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The book provides a detailed examination of the application of nanobioherbicides that come from plants including information on the different metabolites derived from numerous plants that could become bioherbicides.
The book gives attention to weed-plant physiology and chronicles the activities of nanobioherbicides on weeds during preliminary bioassays, pot assays, in-house screenings, and during field trials. Furthermore, deep data is provided on the commercial potential of these nanobioherbicides derived from plants, while toxicity assays are also highlighted.
Other topics covered include: documented patents on nanobioherbicides; the process involved in the registration of these novel products as nanobioherbicides for both conventional and organic farming; relevant information on the application of molecular techniques for improvement of nanobioherbicides, such as genomics, proteomics, informatics, bioinformatics, and chemoinformatics; details about the non-target effect of the nanobioherbicides. Highlighted, too, is information on the biochemical, enzymatic, and ultrastructural effects of these nanobioherbicides, as well as detailed information on the nutritional qualities of agricultural crops after nanobioherbicidal application.
Audience
The book is a useful resource for a diverse audience, including industrialists, food industry professionals, agriculturists, agricultural microbiologists, plant pathologists, botanists, microbiologists, biotechnologists, nanotechnologists, microbial biotechnologists, farmers, policymakers, and extension workers.
Charles Oluwaseun Adetunji, PhD, is a professor in the Department of Microbiology at the Edo University Iyamho, in Edo State, Nigeria. Currently, he is the Director of Intellectual Properties and Technology Transfer and Chairman of the Committee on Research Grants at EUI. He has won several scientific awards and grants from renowned academic bodies such as the Council of Scientific and Industrial Research (CSIR) India. He has published more than 600 papers in peer-reviewed national and international journals as well as more than 50 books, 340 book chapters, and many scientific patents.
Julius Kola Oloke, PhD, is a Professor and Vice Chancellor in the Department of Pure and Applied Biology at the Ladoke Akintola University of Technology, Ogbomoso, Oyo State, Nigeria. He has a PhD in microbiology from Obafemi Awolowo University in 1989. Professor Oloke was conferred with the National Productivity Order of Merit Award by the Federal Government of Nigeria in August 2012, for his work on formulating an immune modulating agent known as Trinity Immuno-booster (Trino IB) which has been used in many countries.
Preface xvii
1 Nanotechnology: History, Trends and Modern Applications 1Charles Oluwaseun Adetunji, Olalekan Akinbo, John Tsado Mathew, Chukwuebuka Egbuna, Abel Inobeme, Olotu Titilayo, Olulope Olufemi Ajayi, Wadazani Dauda, Shakira Ghazanfar, Frank Abimbola Ogundolie, Julinan Bunmi Adetunji, Babatunde Oluwafemi Adetuyi, Shakirat Oloruntoyin Ajenifujah-Solebo and Abdullahi Tunde Aborode
1.1 Introduction 2
1.2 History of Nanotechnology 4
1.3 Recent Trend of Nanotechnology 5
1.4 Application of Nanotechnology Across Industry 6
1.5 Role of Nanotechnology in the Environment 8
1.6 Role of Nanotechnology in Remediation of Polluted Soil 11
1.7 Conclusion 13
2 Mitigating Action of Nanobioherbicides from Natural Products on Agricultural Produce 19Ojo, S.K.S., Otugboyega, J.O., Ayo, I.O., Ojo, A.M. and Oluwole, B.R.
2.1 Introduction 20
2.2 Bioherbicides/Bioherbicide Formulations 21
2.3 Bioherbicides Sourced From Plants 23
2.4 Bioherbicides Sourced From Natural By-Products 24
2.5 Overview of the Benefits of Bioherbicides 25
2.6 Bioherbicides, Sources, and Effects on Target Weeds 26
2.7 Description of Nanoherbicides and Nanotechnology 29
2.8 Polymeric Nanoparticles 30
2.9 Application of Nanoparticles as Nanocarriers 33
2.10 Mode of Action of Nanobioherbicides 34
2.11 Nanobioherbicides and Their Mechanisms of Action 34
2.12 Conclusion 38
3 Beneficial and Natural Metabolites Derived From Plants 45Saheed Ibrahim Musa, Josiah Eseoghene Ifie, Francis Aibuedefe Igiebor, Praisel Nnekauso Dike, Mimololuwa Adejumo, Daniel Igbinigun, Bartholomew Usunobun and Beckley Ikhajiagbe
3.1 Introduction 46
3.2 Types of Plant Metabolites 46
3.3 Relevance/Uses of Secondary Metabolites 56
3.4 Conclusion 56
4 Nanobioherbicides and Nutrient Uptakes 63Kehinde Abraham Odelade, Babatunde Oluwafemi Adetuyi, Jacob Oluwadamilare Ibrahim, Victor Kayode Adeoye, Grace Gift Adewale, Oluwakemi Semiloore Omowumi and Charles Oluwaseun Adetunji
4.1 Introduction 64
4.2 Bioherbicides 66
4.3 Various Assumptions to Bioherbicides Approaches 67
4.4 Different Opportunities to the Bioherbicide Methodology 72
4.5 Examination of Bioherbicides With a Wide Range of Host 73
4.6 The Improvement of Bioherbicide 73
4.7 Roles of Various Microbial Products With Herbicidal Properties 77
4.8 The Capability of Nanotechnology in the Improvement of Bioherbicides 78
4.9 Roles of Phytotoxic Nanoparticles in Bioherbicides Enhancement 85
4.10 Conclusion 87
5 Nanobioherbicide and Photosynthetic Pigment Synthesis 97Gloria Omorowa Omoregie, Francis Aibuedefe Igiebor, Barka Peter Mshelmbula, Saheed Ibrahim Musa, Precious Osagie, Moteniola Adebiyi, Cynthia Etinosa Igbinosun and Beckley Ikhajiagbe
5.1 Introduction 98
5.2 Herbicides 99
5.3 Categories of Herbicides 99
5.4 Classes of Herbicides 102
5.5 Nanobiotechnology 105
5.6 Photosynthesis 106
5.7 Photosynthetic Pigments 108
5.8 Chloroplasts 110
5.9 Nanoherbicide and Agriculture 112
5.10 Future of Nanotechnology 115
5.11 Nanoparticle-Plant Interaction 117
5.12 Conclusion 119
6 Nanobioherbicides and Plant Growth Hormone Synthesis and Stress-Mediated Hormones 125Franics Aibuedefe Igiebor, Edokpolor Osazee Ohanmu, Gloria Omorowa Omoregie, Ojo Otokiti Jennifer, Musa, S.I., Denzel Ejale, Nathaniel Okojie, Richard Afe, Stanley Ivbobie and Beckley Ikhajiagbe
6.1 Introduction 126
6.2 History of Nanotechnology 126
6.3 Types of Nanoparticles 127
6.4 Application of Nanotechnology 130
6.5 Nanobioherbicides 132
6.6 Agroindustrial Waste-Based Nanoparticles 134
6.7 Bioherbicides 135
6.8 Impact of Nanoherbicides on Plant Growth Hormones 138
6.9 Plant Growth Hormones 140
6.10 Synthesis of Plant Growth Hormones 140
6.11 Types of Plant Growth Hormones 141
6.12 Conclusion 143
7 Relevance of Nanobiofungicides in the Prevention of Abiotic Stress 151Gloria Omorowa Omoregie, Edokpolor Osazee Ohanmu, Francis Aibuedefe Igiebor, Yvonne Dike, Chima James Rufus, Esther Eniola, Saheed Ibrahim Musa, Emmanuel Ochoche Shaibu and Beckley Ikhajiagbe
7.1 Introduction 152
7.2 Environment Stress and Fungal Effects 156
7.3 Fungicides 156
7.4 Biofungicides 162
7.5 Limiting Factors in the Use of Microbial Biofungicides 167
7.6 Challenges in the Use of Biofungicides 167
7.7 Nanoparticles as Applied to Biofungicides 167
7.8 Conclusion 175
8 The Influence of Nanobioherbicides on the Social Economy and Its Bioeconomy Perspectives in Attaining Sustainable Development Goals 179Abere Benjamin Olusola and Charles Oluwaseun Adetunji
8.1 Introduction 180
8.2 Literature Review 182
8.3 The Role of Nanobioherbicides in the Creation of Sustainable Development Goals 184
8.4 Conclusion 185
9 Nutritional Qualities of Agricultural Crops After Application of Nanobioherbicides 189John Tsado Mathew, Charles Oluwaseun Adetunji, Abel Inobeme, Musah Monday, Yakubu Azeh, Abdulfatai Aideye Otori and Amos Mamman
9.1 Introduction 190
9.2 Significant Importance of Nanobioherbicides on Nutritional Qualities of Agricultural Crops 192
9.3 Effects of Nanobioherbicides on Nutritional Qualities of Agricultural Crops 194
9.4 Prospect of Nanobioherbicides on Nutritional Qualities of Agricultural Crops 195
9.5 Recent Reports on Nanobioherbicides on Nutritional Qualities of Agricultural Crops 198
9.6 Conclusion 199
10 Application of Plant-Based Nanobiopesticides for Mitigation of Several Abiotic Stress 205Babatunde Oluwafemi Adetuyi and Oluwakemi Semiloore Omowumi
10.1 Introduction 206
10.2 Stress Speculations 208
10.3 Stress Patterns 208
10.4 Natural Stress 210
10.5 Organic Stress 210
10.6 Abiotic Stress 211
10.7 Thermodynamic Pressure 213
10.8 Stress on Heavy Metals 215
10.9 Plant Response to Abiotic Stress 215
10.10 Plant Abiotic Stress Tolerance Mechanisms 217
10.11 Biotechnical Techniques to Reduce Plant Abiotic Stress 223
10.12 Methods in Genetic Engineering to Resist Abiotic Stress 225
10.13 Metabolite Engineering to Increase Resistance to Abiotic Stress 226
10.14 Stress-Responsive Qualities and Record Variables Can Be Hereditarily Adjusted 227
10.15 Devices for Gene Editing to Increase Plant Stress Resistance 229
10.15.1 Zinc Finger Nucleases (ZFNs) 229
10.16 An Approach For Future Applications of Nanomaterials In Combating Plant Stress 231
10.17 Take-Up, Translocation, and Biological Impacts of Plants 233
10.18 Nanobiopesticides 234
10.19 Conclusion 238
11 Nanobioherbicide Applications: Current Trends 253Temitope Fasunloye Ajani, Omotayo Opemipo Oyedara, Bukola Christianah Adebayo-Tayo, Sunday Babatunde Akinde and Charles Oluwaseun Adetunji
11.1 Introduction 254
11.2 Nanoparticles for Agrochemicals 256
11.3 Key Features Nanobioherbicides 259
11.4 Approaches for Application of Nanobioherbicides 259
11.5 Mechanisms of Actions of Nanobioherbicides 264
11.6 Factors Affecting the Efficacy of Nanobioherbicides 267
11.7 Toxicity of Nanobioherbicides 268
11.8 Safety Tests for Nanobioherbicides 269
11.9 Nanoinformatic-Enhanced Weed Control 270
11.10 Challenges and Future Perspectives of Nanobioherbicides 274
11.11 Conclusion and Contribution to Knowledge 277
12 Preliminary Testing and Bioassays of Nanobioherbicides 291Temitope Fasunloye Ajani and Charles Oluwaseun Adetunji
12.1 Introduction 292
12.2 Pot Assay 293
12.3 Field Trial 295
12.4 Sampling of Raw Agricultural Commodity 295
12.5 Information/Raw Data on Individual Field Trials (Test Substance: Nanobioherbicide) 297
12.6 In-House Screening: Confirming Exposure and Maintaining Test Concentration 297
12.7 Test Media Characterization 298
12.8 Measuring Uptake in Soil Organisms 299
12.9 Nanobioherbicide Soil Sorption Assay 299
12.10 Allium cepa Chromosome Aberration Assay 299
13 Nontarget Effects of Nanobioherbicides 303Temitope Fasunloye Ajani, Sunday Babatunde Akinde and Charles Oluwaseun Adetunji
13.1 Introduction 304
13.2 Effects of Nanobioherbicide Formulations 304
13.3 Nontarget Effects of Nanobioherbicide Formulations 305
13.4 Nanoatrazine: Effectiveness and Side Effects 306
13.5 Toxicity of Nanobioherbicides With Nontarget Organisms in Agroecosystem 310
14 Host Range Tests of Nanobioherbicides 317Temitope Fasunloye Ajani, Charles Oluwaseun Adetunji and Bukola Christianah Adebayo-Tayo
14.1 Introduction 317
14.2 Conclusion and Contribution to Knowledge 348
References 348
Index 357
Charles Oluwaseun Adetunji1*, Olalekan Akinbo1, John Tsado Mathew2, Chukwuebuka Egbuna3, Abel Inobeme4, Olotu Titilayo5, Olulope Olufemi Ajayi6, Wadazani Dauda7, Shakira Ghazanfar8, Frank Abimbola Ogundolie9, Julinan Bunmi Adetunji10, Babatunde Oluwafemi Adetuyi11, Shakirat Oloruntoyin Ajenifujah-Solebo12 and Abdullahi Tunde Aborode13
1Applied Microbiology, Biotechnology and Nanotechnology Laboratory, Department of Microbiology, Edo University Iyamho, Auchi, Edo State, Nigeria
2Department of Chemistry, Ibrahim Badamasi Babangida University Lapai, Niger State, Nigeria
3Department of Biochemistry, Faculty of Natural Sciences, Chukwuemeka Odumegwu Ojukwu University, Uli Campus, Anambra State, Nigeria. Nutritional Biochemistry and Toxicology Unit, World Bank Africa Centre of Excellence, Centre for Public Health and Toxicological Research (PUTOR), University of Port-Harcourt, Rivers State, Nigeria
4Department of Chemistry, Edo University Iyamho, Edo State, Nigeria
5Department of Microbiology, Adeleke University, Ede, Osun State, Nigeria
6Department of Biochemistry, Edo University Iyamho, Edo State, Nigeria
7Department of Crop Protection, Federal University Gasua, Zamfara State, Nigeria
8Functional Genomics and Bioinformatics, National Agricultural Research Centre, Islamabad, Pakistan
9Department of Biotechnology, Baze University Abuja, Abuja, Nigeria
10Laboratory for Reproductive Biology and Developmental Programming, Department of Physiology, Edo University Iyamho, Edo State, Nigeria
11Department of Natural Sciences, Biochemistry Unit, Faculty of Pure and Applied Sciences, Precious Cornerstone University, Ibadan, Oyo State, Nigeria
12Department of Biochemistry, Osogbo, Osun State University, Osun State, Nigeria
13Healthy Africans Platform, Research and Development, Ibadan, Nigeria
Nanoscience and nanotechnology are expanding fields of research that include tools and platforms with new characteristics and roles owing to the organization of molecules nanoscale. Nanotechnology contributes extensively to numerous fields of science, like physics, chemistry, biology, materials science, computer science, physiology, anatomy, and technology. Although lack of information and the potential for negative influences on human health and the environment, continues to be of concern, the possible roles in many fields like coatings and paints, apparel and textiles, cosmetics, catalysis, food technology, and more have offered new opportunities to improve measurement, monitoring, and control methods. This chapter describes an overview of the advances and basic principles of nanotechnology and presents both premodern and modern eras of detections and innovative milestones in their areas of application.
Keywords: Nanotechnology, applications, human health, safety, sustainability
Virtually, several fields of technology, science, physiology, and engineering in the area of nanoscience are making life easier. Nanotechnology is a growing field of study that include structures, tools, and platforms possessing new characteristics and roles owing to the organization of atoms in the nanoscale [1]. This field was a topic of budding public consciousness and debate in the early 2000s, resulting in the commercial applications of nanotechnology.
Nanotechnology contributes to several fields of science, like physics, chemistry, materials science, biology, engineering, and computer science. In recent few decades, nanotechnology has been utilized in human health with encouraging results, particularly in the area of cancer management [2]. To appreciate the advancement in nanotechnology, it is useful to consider the chronology of detections that have led to the recent development in the field. This overview describes the advances and basic ethics of nanotechnology presented in both premodern and modern eras of findings and advances in their areas of application.
The preface "nano" is a Greek word meaning "dwarf" or very little, which stands for thousandths of a meter. Nanotechnology and nanoscience must be distinguished or separated. Nanoscience is the study of nanometer-scale molecules or structures in the range of one to hundred nm, and the tools that apply them to hands-on uses like tools is called nanotechnology [3]. For comparison, it should be understood that the thickness of one human hair is 60,000 nm, and the radius of DNA double helix structure is 1 nm [4].
Advances in nanoscience can be traced to the era of the Democritus and Greeks in the 5th century BC. At the time, researchers viewed the question of whether the matter is continuous and can be divided into infinitely lesser parts, or whether it consists of indivisible, small, imperishable matter and particle [4].
Nanotechnology is one of the most advanced tools of the 21st century with the capability to transform nanoscience theories into valuable uses by measuring, analyzing, manipulating, manipulating, assembling, and creating materials on the nanoscale [5].
This definition assumes two settings for nanotechnology; the first is a matter of scale. Nanotechnology uses structures to control size and shape at the nanoscale. More so, the second problem is the novelty since nanoscale nanotechnology has to do with small molecules by taking advantage of certain characteristics [6, 7].
Nanotechnology is the utilization of scientific techniques to control and manipulate molecules at the nanoscale to exploit size, shape, and arrangement-dependent characteristics and spectacles as opposed to those involving single molecules or wholesale materials [8]. This field presents new opportunities to develop FMCG products with improved efficiency, lowered manufacturing costs, and reduced raw material usage. Nanotechnology, closely aligned with European Union's agenda for sustainable, smart, and accountable growth, is possibly a major social change confronting the region, like health requirements of an ageing population, better utilization of available resources, and the development of renewable energy sources. It will help to solve the problem to meet the increased requirements [9].
However, questions remain that the role of nanoparticles, mostly due to the inadequate level of information on their characteristics and usefulness, as well as concerns about the adverse effects nanotechnology, may have on health and the environment. This chapter provides a brief overview of nanoparticles utilized in key industries.
Nanotechnology has advanced growth and innovation in many industries. Nanotechnology is considered a major tool for a diverse range of utilizations in healthcare, electronics, chemistry, cosmetics, material science, energy, and more. Uses fewer raw materials. Despite advances in nanotechnology, several challenges are still encountered by scientists in providing adequate outstanding and role of nanotechnology in several industrial sectors. Inadequate information and the potential for negative influences on human health, environment, sustainability, and safety continue to be of concern [10-15].
Nanoscience and nanotechnology must be distinguished. Nanoscience is a combination of materials science, physics, biology, and technology that involves the manipulation of matter at the molecular level. Nanotechnology is also the ability to observe, quantify, manipulate, collect, control, analyze, and create matter on the nanometer scale [16]. Some reports show the account of nanoscience but there are no reports that summarize nanoscience and technology as a progressive event from the beginning of nanoscience to that era. It is therefore essential to recap the major advances in nanoscience and technology to fully appreciate advances in this field.
American Nobel laureate and physicist Richard Feynman introduced the idea of nanotechnology in 1959 [17]. At the American Physical Society meeting, Feynman gave a public lecture (California Institute of Technology) entitled "There's a lot of space on the floor." Feynman hypothesized, "Why can't we write all 24 volumes of the Encyclopedia Britannica on Pinhead?" And he defined an idea of utilizing technologies to make machines small to molecular level [18]. This new idea showed that Feynman's hypothesis was accurate, and for this reason, he is given the father of contemporary nanotechnology.
About 15 years later, Japanese scientist Norio Taniguchi first used and defined the term "nanotechnology" [19]. After Feynman revealed this novel area of study that has attracted the attention of numerous researchers, two methods have been established to explain the diverse potentials of nanostructure production. These industrial methods fall into two classes: bottom-up and top-down, which vary in speed, cost particles, and quality. This can be attained utilizing innovative methods like lithography and precision tools [9, 20, 21].
Bottom-up approaches use the controlled manipulation of atomic self-assembly to represent the growth of nanoparticles under molecule-to-molecular through chemical and physical approaches in the nanoscale range (1 nm to 100 nm) and Molecular [22]. Chemical production is a method of generating coarse materials which can be utilized in...
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