Advances in Magnetic Resonance, Volume 3, describes a number of important developments which are finding increasing application by chemists. The book contains five chapters and begins with a discussion of how the properties of random molecular rotations reflect themselves in NMR and how they show up, often differently, in other kinds of experiments. This is followed by separate chapters on the Kubo method, showing its equivalence to the Redfield approach in the cases of most general interest; the current state of dynamic nuclear polarization measurements in solutions and what they tell us about the interactions of molecules and about the frequency spectra of molecular motions; and insights into the structures of ferroelectric crystals and the nature of the transition to the ferroelectric state. The final chapter discusses spin temperatures and related matters.
Sprache
Verlagsort
Verlagsgruppe
Elsevier Science & Techn.
Dateigröße
ISBN-13
978-1-4832-8152-0 (9781483281520)
Schweitzer Klassifikation
ContributorsPrefaceContents of Previous VolumesTentative Contents of Future VolumesCorrelation Functions for Molecular Motion I. Introduction II. Correlation Functions in Spectroscopy III. Calculations of Correlation Functions in Molecular GasesTime Correlation Functions in Nuclear Magnetic Relaxation I. Introduction II. Outline of the Development III. The Macroscopic Transport Equations IV. Linear Relaxation Theory from the Point of View of Brownian Motion V. Correlation Functions and Onsager's Assumption VI. The Linear Response Theory VII. The Time Correlation Function Formulas VIII. Application Appendix. The Behavior of Correlation Functions on the Macroscopic Time ScaleDynamic Nuclear Polarization in Liquids I. Introduction II. Theory III. Experimental Technique IV. Experimental ResultsMagnetic Resonance in Hydrogen-Bonded Ferroelectrics I. Introduction II. Deuteron Magnetic Resonance (DMR) III. Proton Magnetic Resonance IV. Deuteron and Proton Resonance of Ferroelectric Ammonium Salts V. Resonance of Nuclei Other than H or D VI. Electron Paramagnetic Resonance in H-Bonded Ferroelectrics Appendix. Some Ferroelectric and Antiferroelectric Compounds Investigated by NMRThermodynamics of Spin Systems in Solids I. Introduction II. Spin Hamiltonians, Energy Levels III. Spin Systems in Quasi-Equilibrium IV. Spin-Lattice Relaxation V. The Effects of a Weak RF Irradiation (Large Single Spin Hamiltonians) VI. "Adiabatic" Processes. Cross-Relaxation VII. "Sudden" Processes. Pulse TechniquesAuthor IndexSubject Index