Advances in Magnetic Resonance, Volume 1, discusses developments in various areas of magnetic resonance. The subject matter ranges from original theoretical contributions through syntheses of points of view toward series of phenomena to critical and painstaking tabulations of experimental data.
The book contains six chapters and begins with a discussion of the theory of relaxation processes. This is followed by separate chapters on the development of magnetic resonance techniques for studying rate processes in chemistry and the application of these techniques to various problems; the geometrical and electronic structures of paramagnetic molecules and complex ions; and various theoretical formulations of spin-spin coupling. Subsequent chapters deal with geminal and vicinal proton-proton coupling constants from values reported in the literature; and electron spin resonance of radical ions.
This serial publication was conceived with the insiders as well as the interested outsiders in mind. The editor hopes that readers who consult this book for a particular article will in some measure profit by being exposed to some of the other contributions.
Sprache
Verlagsort
Verlagsgruppe
Elsevier Science & Techn.
Dateigröße
ISBN-13
978-1-4832-8150-6 (9781483281506)
Schweitzer Klassifikation
ContributorsPrefaceTentative Contents of Future VolumesThe Theory of Relaxation Processes I. Introduction II. Random Perturbation III. Dynamical Interaction with a Thermal Bath IV. Time-Dependent Hamiltonian V. Applications Appendix A Appendix B Chemical Rate Processes and Magnetic Resonance I. Introduction II. Line Shapes and the Motion of Spins III. Slow Passage Line Shapes and the Determination of Reaction Rates IV. Transient Methods for the Measurement of Rates V. ConclusionNuclear Magnetic Resonance of Paramagnetic Molecules I. Introduction II. ApplicationsTheory of Nuclear Spin-Spin Coupling I. Introduction II. Experimental Basis III. Physical Basis-Spin-Spin Coupling Hamiltonian IV. Coupling between Directly Bonded Nuclei V. Molecular Wave Mechanical Formulations VI. Spin-Spin Coupling between Nondirectly Bonded Nuclei VII. General ConclusionsGeminal and Vicinal Proton-Proton Coupling Constants in Organic Compounds I. Introduction II. Geminal Coupling Constants III. Vicinal Coupling Constants across Formal Single Bonds IV. Couplings in Ethylenes and Substituted Ethylenes V. Benzene and Substituted Benzenes VI. Heterocycles Tables ReferencesElectron Spin Resonance of Radical Ions I. Introduction II. Survey of Recent Developments III. Table of Splitting Constants of Hydrocarbon Radical Ions in Solution ReferencesAuthor IndexSubject Index
