Organometallic Chemistry of Titanium, Zirconium, and Hafnium

Preface Chapter I. Introduction A. The Cyclopentadienyl Compounds B. Spectroscopic Properties of Cyclopentadienyl Groups Chapter II. Alkyl- and Aryltitanium(IV) Compounds A. Alkyltitanium Halides B. Adducts of Alkyltitanium Trihalides C. Phenyltitanium Trichloride D. Alkyl- and Aryltitanium Alkoxides E. Alkyl- and Aryltitanium Amides F. Tetraalkyl- and Tetraaryltitanium Compounds Chapter III. p-Bonded Derivatives of Titanium(IV) A. Mono(cyclopentadienyl)titanium(IV) Derivatives B. Bis(cyclopentadienyl)titanium(IV) Derivatives C. Tris(cyclopentadienyl)titanium(IV) Chloride D. Tetracyclopentadienyltitanium(IV) E. Bis(cyclooctatetraene)titanium F. p-Pyrrolyl Compounds Chapter IV. Organometallic Compounds of Zirconium(IV) and Hafnium(IV) A. Alkylzirconium(IV) and Alkylhafnium(IV) Compounds B. Cyclopentadienyl Compounds C. Miscellaneous p Derivatives of Zirconium(lV) and Hafnium(IV) Chapter V. Complexes of Titanium and Aluminum (Including Related Systems) A. µ-Halo Complexes B. µ-Alkoxo Complexes C. µ-Hydrido Complexes D. Reactions of Alkylaluminum Derivatives with Zirconium Compounds E. The Role of Organotitanium in Olefin Polymerization (Ziegler-Natta Catalysis) Chapter VI. Organometallic Compounds of Titanium(III) and Zirconium(III) A. Alkyl-, Aryl-, and Arenetitanium(III) Compounds (Excluding Cyclopentadienyl) B. Mono(cyclopentadienyl)titanium(III) Compounds C. Bis(cyclopentadienyl)titanium(III) Derivatives D. Tris(cyclopentadienyl)titanium(III) E. Compounds of Zirconium(III) 2Chapter VII. Organometallic Compounds of Titanium(II), Zirconium(II), and Hafnium(II) A. Titanocene B. Bis(pentamethylcyclopentadienyl)titanium (or Decamethyltitanocene) C. Carbonyl Compounds D. Zirconocene and Hafnocene E. 2,2'-Bipyridyl Adducts of Titanocene and Zirconocene F. Cyclopentadienylphenyltitanium G. Cyclopentadienylcycloheptatrienyltitanium H. Cycloheptatrienylcycloheptadienyltitanium I. Cyclooctatetraene(tetraphenylcyclobutadiene)titanium J. Bis(phenyl)titanium K. Arene Complexes Chapter VIII. The Reactions of Dinitrogen with Titanium (and Zirconium) Compounds A. Absorption of Nitrogen by Reduced Titanium Species B. Reactions of Individual Organotitanium Compounds with Dinitrogen C. Nitrogen Incorporation into Organic Molecules Bibliography Appendix Subject Index