Polyarenes I

Name: Polyarenes I
Brand: Springer
Price: 213.99 EUR
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Jay S. Siegel Yao-Ting Wu(Herausgeber*in)

Springer (Verlag)

Erschienen am 13. November 2014

IX, 294 Seiten

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978-3-662-43379-9 (ISBN)

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Inhalt

Intro
Preface
References
Contents
Beyond Pentacenes: Synthesis and Properties of Higher Acenes
1 Introduction
2 Hexacenes
2.1 Parent Hexacene
2.2 Substituted Hexacenes
2.2.1 Silylethynyl Substitution
3 Heptacenes
3.1 Parent Heptacene
3.2 Substituted Heptacenes
3.2.1 Silylethynyl Substituted Heptacenes
3.2.2 Aryl Substituted Heptacenes
3.2.3 Thioaryl Substituted Heptacenes
4 Octacene and Nonacene
4.1 Parent Octacene and Nonacene
4.2 Silylethynyl Substituted Nonacenes
4.3 Thioaryl Substituted Nonacenes
5 Conclusions and Outlook
References
Twisted Arenes
1 Introduction
2 Twisted Phenanthrenes and Related Compounds
2.1 4,5-Dialkylphenanthrenes
2.2 4,5-Diarylphenanthrenes
2.3 4,5-Dihalophenanthrenes
2.4 1,10-Disubstituted 4,7-Phenanthrolines
2.5 1,10-Phenanthroline 1,10-Dioxides
3 Twisted Benzo[c]phenanthrenes and Related Compounds
3.1 1,12-Dialkylbenzo[c]phenanthrenes
3.2 1,12-Diarylbenzo[c]phenanthrenes
4 Twisted Dibenzo[c,g]phenanthrenes and Related Compounds
4.1 1,14-Dialkyldibenzo[c,g]phenanthrenes
4.2 1,14-Diaryldibenzo[c,g]phenanthrenes
4.3 1,14-Dimethoxydibenzo[c,g]phenanthrene and Related Compounds
5 Twisted Naphthalenes, Anthracenes, and Higher Acenes
5.1 Highly Substituted Naphthalenes
5.2 Highly Substituted Anthracenes
5.3 Highly Substituted Higher Acenes
6 Conclusions and Outlook
References
Synthesis, Structures, and Physical Properties of Aromatic Molecular-Bowl Hydrocarbons
1 Introduction
2 Corannulene and Its Derivatives
2.1 Corannulene and Simple Corannulene Derivatives
2.1.1 Pioneering Syntheses
2.1.2 Structure and Properties of Simple Corannulene Derivatives
2.2 Highly Substituted Corannulenes
2.2.1 Synthesis
2.2.2 Structures and Properties of Highly Substituted Corannulenes
2.3 Cyclopentacorannulene, Acecorannulene and Annelated Corannulenes
2.3.1 Synthesis
2.3.2 Structures and Properties of Annulated Corannulenes
2.4 Benzocorannulene Family
2.4.1 Synthesis
2.4.2 Structures and Properties
2.5 Indenocorannulene Family
2.5.1 Synthesis
2.5.2 Structures and Properties
2.6 Other Corannulene Derivatives
2.6.1 Corannulene Cyclophane
2.6.2 Acenaphtho[1,2,3-bcd]corannulene
2.6.3 Semibuckminsterfullerene
2.6.4 Corannulene Clip
2.7 The Correlations Between Structures and Bowl-to-Bowl Inversion Barriers
3 Sumanene
3.1 Sumanene and Simple Sumanene Derivatives
3.1.1 Synthesis
3.1.2 Structures and Properties
3.2 Naphthosumanenes
3.3 Hemifullerene
4 Mixed Type Buckybowls
4.1 Acenaphtho[3,2,1,8-ijlkm]diindeno[4,3,2,1-cdef:1,2,3,4-pqra]triphenylene
4.2 Acenaphth[3,2,1,8-fghij]-as-indaceno[3,2,1,8,7,6-pqrstuv]picene
4.3 Circumtrindene
5 Other Bulkybowls
5.1 as-Indaceno[3,2,1,8,7,6-pqrstuv]picenes
5.2 Tetrabenzopyracylene
5.3 Tetraindenopyrene
5.4 Highly Curved Fragment of C70 and Higher Fullerenes
5.5 Hexabenzocoronene-Based Buckybowl
6 The Smallest Carbon Nanotube
7 A Warped Nanographene
8 Molecular Packing of Bowls in the Solid State
9 Conclusion and Outlooks
References
Strategies in Organic Synthesis for Condensed Arenes, Coronene, and Graphene
1 Introduction
2 Synthetic Methods to Assemble Graphene-Type Structures
2.1 Pioneering Synthesis of PAHs
2.2 Syntheses via the Diels-Alder Reaction
2.3 Cyclotrimerization
2.4 Aryl-Aryl-Coupling Reactions
2.4.1 Cross-Coupling Reactions
2.4.2 Cross-Coupling Reactions Involving C-H Bond Activation
2.4.3 Oxidative/Reductive Coupling Reactions
2.5 Annulation Reactions
2.5.1 Photocyclizations
2.5.2 Transition Metal Mediated Cyclizations
2.6 Ring Closing Metathesis
3 Synthetic Methods for the Extension of Graphene-Type Structures
3.1 Polymerization Reactions
3.2 Postfunctionalization of PAHs for the Extension to Graphene
3.3 Direct Extension of PAHs by Diels-Alder Reaction
4 Surface Assisted Methods for the Synthesis of Graphene-Type Structures
5 Summary, Conclusions, and Outlook
References
Indenofluorenes and Derivatives: Syntheses and Emerging Materials Applications
1 Introduction
1.1 Background
1.2 Early Research
2 Indeno[1,2-a]fluorenes
2.1 Indeno[1,2-a]fluorene-7,12-diones
2.2 Other Indeno[1,2-a]fluorenes
3 Indeno[1,2-b]fluorenes
3.1 Indeno[1,2-b]fluorene-6,12-diones
3.2 Indeno[1,2-b]fluorene-6,12-olefins
3.3 Fully-Conjugated Indeno[1,2-b]fluorene
3.4 Other Indeno[1,2-b]fluorenes
4 Indeno[2,1-a]fluorenes
4.1 Indeno[2,1-a]fluorene-11,12-diones
4.2 Fully-Conjugated Indeno[2,1-a]fluorenes
5 Indeno[2,1-b]fluorenes
5.1 Indeno[2,1-b]fluorene-10,12-diones
5.2 Fully-Conjugated Indeno[2,1-b]fluorenes
5.3 Other Indeno[2,1-b]fluorenes
6 Indeno[2,1-c]fluorenes
6.1 Indeno[2,1-c]fluorene-5,8-diones
6.2 Fully-Conjugated Indeno[2,1-c]fluorenes
6.3 Other Indeno[2,1-c]fluorenes
7 Conclusions
References
Closed-Shell and Open-Shell 2D Nanographenes
1 Introduction
2 2D Nanographenes with Only Zigzag Edges
2.1 Phenalenyl-Based Open-Shell Systems
2.1.1 Phenalenyl-Based Monoradicals
2.1.2 Extended Systems Based on Bis- and Trisphenalenyls
2.2 Triangulene-Based Triplet Biradicals
3 2D Nanographenes with Both Zigzag Edges and Armchair Edges
3.1 Rylenes
3.2 Anthenes and Periacenes
4 2D Nanographenes with Only Armchair Edges
4.1 Hexa-Peri-Hexabenzocoronene
4.2 All-Benzenoid PAHs Larger than HBC
5 Conclusion and Outlook
References
Molecular Belts
1 Radially Oriented pi-Systems
2 Hydrocarbon ``Picotube´´
3 Cycloparaphenyleneacetylenes
3.1 First Synthesis by Kawase
3.2 CPPAs as Novel Host Molecules
3.3 Synthesis of More Reactive CPPAs
4 Cycloparaphenylenes
4.1 Early Attempts Towards Cycloparaphenylenes
4.2 First Synthesis of Cycloparaphenylene
4.3 Subsequent Syntheses: A New Field Emerges
4.4 Better Synthetic Control and New CPP Sizes
4.5 Host-Guest Behavior of [10]CPPC60, a Fullerene Peapod
4.6 Functionalized Cycloparaphenylenes
5 ``Top-Down´´ Synthesis of [10]Cyclophenacene
6 Cyclacenes
6.1 Towards the Synthesis of [6]12Cyclacene
6.2 Towards the Synthesis of [6]8Cyclacene
6.3 [6.8]Cyclacene
6.4 Buckybelts
References
Index

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