Schweitzer Fachinformationen
Wenn es um professionelles Wissen geht, ist Schweitzer Fachinformationen wegweisend. Kunden aus Recht und Beratung sowie Unternehmen, öffentliche Verwaltungen und Bibliotheken erhalten komplette Lösungen zum Beschaffen, Verwalten und Nutzen von digitalen und gedruckten Medien.
Jay Siegel, Emeritus Professor of Forensic Science, Michigan State University Jay Siegel is Director of the Forensic and Investigative Sciences Program at Indiana University Purdue University, Indianapolis and Chair of the Department of Chemistry and Chemical Biology. He holds a Ph.D. in Analytical Chemistry from George Washington University. He worked for 3 years at the Virginia Bureau of Forensic Sciences, analyzing drugs, fire residues and trace evidence. From 1980 to 2004 he was professor of forensic chemistry and Director of the forensic science program at Michigan State University in the School of Criminal Justice. He is Editor in Chief of the Encyclopedia of Forensic Sciences, author of Forensic Science: A Beginner's Guide and Fundamentals of Forensic Science and has over 30 publications in forensic science journals. Dr. Siegel was awarded the 2005 Paul Kirk Award for lifetime achievement in forensic science. In February 2009, he was named Distinguished Fellow by the American Academy of Forensic Sciences. In April 2009 he was named the Distinguished Alumni Scholar Award by his alma mater, George Washington University.
About the editor, xii
Contributors, xiii
Series preface, xv
Preface, xvi
1 Drugs of abuse, 1Niamh Nic Daéid
1.1 Introduction, 1
1.2 Law and legislation, 2
1.3 Sampling, 4
1.3.1 Random sampling and representative sampling, 6
1.3.2 Arbitrary sampling, 7
1.3.3 Statistical sampling methods, 8
1.4 Specific drug types, 9
1.4.1 Cannabis, 9
1.4.2 Heroin, 14
1.4.3 Cocaine, 22
1.4.4 Amphetamine?]type stimulants, 27
1.4.5 New psychoactive substances, 33
1.5 Conclusions, 36
Acknowledgements, 36
References, 36
2 Textiles, 40Max Houck
2.1 Introduction, 40
2.2 A science of reconstruction, 40
2.2.1 Classification, 41
2.2.2 Comparison, 42
2.2.3 Transfer and persistence, 43
2.3 Textiles, 43
2.3.1 Information, 44
2.3.2 Morphology, 45
2.4 Natural fibers, 48
2.4.1 Animal fibers, 48
2.4.2 Plant fibers, 51
2.5 Manufactured fibers, 52
2.6 Yarns and fabrics, 55
2.6.1 Fabric construction, 56
2.6.2 Finishes, 59
2.7 Fiber types, 59
2.7.1 Acetate, 59
2.7.2 Acrylic, 59
2.7.3 Aramids, 60
2.7.4 Modacrylic, 60
2.7.5 Nylon, 61
2.7.6 Olefins (polypropylene and polyethylene), 61
2.7.7 Polyester, 62
2.7.8 Rayon, 62
2.7.9 Spandex, 65
2.7.10 Triacetate, 66
2.7.11 Bicomponent fibers, 66
2.8 Chemistry, 67
2.8.1 General analysis, 67
2.8.2 Instrumental analysis, 68
2.8.3 Color, 69
2.8.4 Raman spectroscopy, 70
2.8.5 Interpretation, 71
2.9 The future, 72
References, 72
3 Paint and coatings examination, 75Paul Kirkbride
3.1 Introduction, 75
3.2 Paint chemistry, 76
3.2.1 Binders, 76
3.2.2 Dyes and pigments, 86
3.2.3 Additives, 89
3.3 Automotive paint application, 91
3.4 Forensic examination of paint, 92
3.4.1 General considerations, 92
3.4.2 Microscopy, 95
3.4.3 Vibrational spectrometry, 96
3.4.4 SEM?]EDX and XRF, 106
3.4.5 Pyrolytic techniques, 111
3.4.6 Color analysis, 116
3.5 Paint evidence evaluation and expert opinion, 120
References, 128
Contents vii
4 Forensic fire debris analysis, 135Reta Newman
4.1 Introduction, 135
4.2 Process overview, 135
4.3 Sample collection, 136
4.4 Ignitable liquid classification, 137
4.5 Petroleum?]based ignitable liquids, 144
4.6 Non?]petroleum?]based ignitable liquids, 160
4.7 Sample preparation, 161
4.8 Sample analysis and data interpretation, 166
4.9 Summary, 172
References, 173
5 Explosives, 175John Goodpaster
5.1 The nature of an explosion, 175
5.1.1 Types of explosions, 175
5.1.2 Explosive effects, 176
5.2 Physical and chemical properties of explosives, 180
5.2.1 Low explosives, 181
5.2.2 High explosives, 186
5.3 Protocols for the forensic examination of explosives and explosive devices, 192
5.3.1 Recognition of evidence, 192
5.3.2 Portable technology and on?]scene analysis, 193
5.3.3 In the laboratory, 194
5.4 Chemical analysis of explosives, 200
5.4.1 Consensus standards (TWGFEX), 201
5.4.2 Chemical tests, 203
5.4.3 X?]ray techniques, 204
5.4.4 Spectroscopy, 207
5.4.5 Separations, 212
5.4.6 Gas chromatography, 213
5.4.7 Mass spectrometry, 215
5.4.8 Provenance and attribution determinations, 219
5.5 Ongoing research, 221
Acknowledgements, 222
References, 222
Further reading, 226
6 Analysis of glass evidence, 228Jose Almirall and Tatiana Trejos
6.1 Introduction to glass examinations and comparisons, 228
6.2 Glass, the material, 231
6.2.1 Physical and chemical properties, 231
6.2.2 Manufacturing, 233
6.2.3 Fractures and their significance, 236
6.2.4 Forensic considerations: Transfer and persistence of glass, 238
6.3 A brief history of glass examinations, 241
6.4 Glass examinations and comparison, standard laboratory practices, 242
6.4.1 Physical measurements, 243
6.4.2 Optical measurements, 244
6.4.3 Chemical measurements: elemental analysis, 247
6.5 Interpretation of glass evidence examinations and comparisons, 256
6.5.1 Defining the match criteria, 256
6.5.2 Descriptive statistics, 256
6.5.3 Match criteria for refractive index measurements, 257
6.5.4 Informing power of analytical methods, forming the opinion, 260
6.5.5 Report writing and testimony, 262
6.6 Case examples, 263
6.6.1 Case 1: Hit?]and?]run case, 263
6.6.2 Case 2: Multiple transfer of glass in breaking?]and?]entry case, 264
6.7 Conclusions, 265
References, 266
7 The forensic comparison of soil and geologic microtraces, 273Richard E. Bisbing
7.1 Soil and geologic microtraces as trace evidence, 273
7.2 Comparison process, 274
7.3 Developing expertise, 278
7.4 Genesis of soil, 279
7.5 Genesis of geologic microtraces, 284
7.6 Collecting questioned samples of unknown origin, 287
7.7 Collecting soil samples of known origin, 288
7.8 Initial comparisons, 290
7.9 Color comparison, 290
7.10 Texture comparison, 293
7.11 Mineral comparison, 297
7.12 Modal analysis, 301
7.13 Automated instrumental modal analysis, 308
7.14 Ecological constituents, 310
7.15 Anthropogenic constituents, 312
7.16 Reporting comparison results, 312
7.17 Future directions and research, 314
Acknowledgments, 314
References, 315
Further reading, 316
8 Chemical analysis for the scientific examination of questioned documents, 318Gerald M. LaPorte
8.1 Static approach, 320
8.2 Dynamic approach, 324
8.3 Ink composition, 324
8.4 Examinations, 328
8.4.1 Physical examinations, 329
8.4.2 Optical examinations, 332
8.4.3 Chemical examinations, 333
8.4.4 Paper examinations, 339
8.5 Questioned documents, crime scenes and evidential considerations, 342
8.5.1 How was the questioned document produced?, 342
8.5.2 What evidence can be used to associate a questioned document with the crime scene and/or victim?, 343
8.5.3 Are there other forensic examinations that can be performed?, 345
8.5.4 Demonstrating that a suspect altered a document, 346
8.6 Interpreting results and rendering conclusions, 347
References, 350
9 Chemical methods for the detection of latent fingermarks, 354Amanda A. Frick, Patrick Fritz, and Simon W. Lewis
9.1 Introduction, 354
9.2 Sources of latent fingermark residue, 355
9.2.1 Aqueous components, 356
9.2.2 Lipid components, 357
9.2.3 Sources of compositional variation, 359
9.3 Chemical processing of latent fingermarks, 361
9.3.1 Amino acid sensitive reagents, 361
9.3.2 Reagents based on colloidal metals, 370
9.3.3 Lipid?]sensitive reagents, 377
9.3.4 Other techniques, 383
9.4 Experimental considerations for latent fingermark chemistry research, 384
9.5 Conclusions and future directions, 387
Acknowledgements, 388
References, 388
Further reading, 398
10 Chemical methods in firearms analysis, 400Walter F. Rowe
10.1 Introduction, 400
10.2 Basic firearms examination, 400
10.2.1 Cleaning bullets and cartridges, 402
10.2.2 Analysis of bullet lead, 404
10.2.3 Serial number restoration, 406
10.3 Shooting incident reconstruction, 408
10.3.1 Muzzle?]to?]target determinations, 411
10.3.2 Firearm primers, 416
10.3.3 Collection of gunshot residue, 425
10.4 Conclusion, 433
References, 433
11 Forensic microscopy, 439Christopher S. Palenik
11.1 The microscope as a tool, 439
11.2 Motivation, 440
11.2.1 Intimidation, 442
11.2.2 Limitations, 442
11.3 Scale, 442
11.3.1 Scale and magnification, 443
11.3.2 Noting scale, 443
11.3.3 Analytical volume and limits of detection, 443
11.4 Finding, 445
11.4.1 Spatial resolution, 445
11.4.2 Recovery resolution, 447
11.4.3 Stereomicroscope, 447
11.5 Preparing, 448
11.5.1 Preservation and documentation, 448
11.5.2 Isolation, 450
11.5.3 Mounting, 451
11.6 Looking, 455
11.6.1 Light microscopy, 456
11.6.2 Scanning electron microscopy, 457
11.7 Analyzing, 458
11.7.1 Polarized light microscopy, 458
11.7.2 Energy dispersive X?]ray spectroscopy, 462
11.7.3 FTIR and Raman spectroscopy, 464
11.7.4 Other methods, 465
11.8 Thinking, 465
11.9 Thanking, 467
References, 467
12 Chemometrics, 469Ruth Smith
12.1 Introduction, 469
12.2 Chromatograms and spectra as multivariate data, 470
12.3 Data preprocessing, 470
12.3.1 Baseline correction, 471
12.3.2 Smoothing, 473
12.3.3 Retention?]time alignment, 473
12.3.4 Normalization and scaling, 475
12.4 Unsupervised pattern recognition, 477
12.4.1 Hierarchical cluster analysis, 478
12.4.2 Principal components analysis, 480
12.5 Supervised pattern recognition procedures, 485
12.5.1 k?]Nearest neighbors, 486
12.5.2 Discriminant analysis, 487
12.5.3 Soft independent modeling of class analogy, 492
12.5.4 Model validation, 493
12.6 Applications of chemometric procedures in forensic science, 494
12.6.1 Fire debris and explosives, 495
12.6.2 Controlled substances and counterfeit medicines, 496
12.6.3 Trace evidence, 497
12.6.4 Impression evidence, 499
12.7 Conclusions, 499
Acknowledgements, 500
References, 500
Index, 504
Dateiformat: ePUBKopierschutz: Adobe-DRM (Digital Rights Management)
Systemvoraussetzungen:
Das Dateiformat ePUB ist sehr gut für Romane und Sachbücher geeignet – also für „fließenden” Text ohne komplexes Layout. Bei E-Readern oder Smartphones passt sich der Zeilen- und Seitenumbruch automatisch den kleinen Displays an. Mit Adobe-DRM wird hier ein „harter” Kopierschutz verwendet. Wenn die notwendigen Voraussetzungen nicht vorliegen, können Sie das E-Book leider nicht öffnen. Daher müssen Sie bereits vor dem Download Ihre Lese-Hardware vorbereiten.Bitte beachten Sie: Wir empfehlen Ihnen unbedingt nach Installation der Lese-Software diese mit Ihrer persönlichen Adobe-ID zu autorisieren!
Weitere Informationen finden Sie in unserer E-Book Hilfe.
