The Aqueous Chemistry of the Elements

Name: The Aqueous Chemistry of the Elements
Brand: OUP eBook
Price: 120.59 EUR
Availability: OnlineOnly

George K. Schweitzer Lester L. Pesterfield(Autor*in)

OUP eBook (Verlag)

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Erschienen am 14. Januar 2010

447 Seiten

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978-0-19-974219-6 (ISBN)

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Inhalt

Intro
Contents
1 E-pH Diagrams
1. Introduction
2. The Na E-pH Diagram
3. The Al E-pH Diagram
4. The Fe E-pH Diagram
5. The V E-pH Diagram
6. The HOH E-pH Diagram
2 The Construction of E-pH Diagrams
1. Introduction
2. Constructing the Ga E-pH Diagram
3. Constructing the Ga E-pH Diagram with Concentration Variations
4. Constructing the Mn E-pH Diagram
5. E-pH Computer Programs
6. Species Selection and Treatment
3 Reactions and Applications
1. Introduction
2. Reactions with HOH
3. The Mn-Fe-HOH System (Excess Mn Species)
4. The Mn-Fe-HOH System (Excess Fe Species)
5. Combining Redox Reactions
6. The HOH E-pH Diagram Revisited
7. General Conclusions
4 Precipitation and Complexation
1. Introduction
2. Precipitation and E-pH Diagrams
3. Addition of Cl[sup(-)] to the Ag E-pH System
4. Addition of S[sup(-2)] to the Zn E-pH System
5. Review of Complexation and Complex Species
6. Complexation and E-pH Diagrams
7. Addition of Cl[sup(-)] to the Pd E-pH System to Form PdCl[sub(4)][sup(-2)]
8. Multiple Complexes and E-pH Diagrams
5 The Lithium Group
1. Introduction
2. Lithium (Li) 2s[sup(1)]
3. Sodium (Na) 3s[sup(1)]
4. Potassium (K) 4s[sup(1)]
5. Rubidium (Rb) 5s[sup(1)]
6. Cesium (Cs) 6s[sup(1)]
7. Francium (Fr) 7s[sup(1)]
8. The Ammonium Ion (NH[sub(4)][sup(+)]
6 The Beryllium Group
1. Introduction
2. Beryllium (Be) 2s[sup(2)]
3. Magnesium (Mg) 3s[sup(2)]
4. Calcium (Ca) 4s[sup(2)]
5. Strontium (Sr) 5s[sup(2)]
6. Barium (Ba) 6s[sup(2)]
7. Radium (Ra) 7s[sup(2)]
7 The Boron Group
1. Introduction
2. Boron (B) 2s[sup(2)]2p[sup(1)]
3. Aluminum (Al) 3s[sup(2)]3p[sup(1)]
4. Gallium (Ga) 4s[sup(2)]4p[sup(1)]
5. Indium (In) 5s[sup(2)]5p[sup(1)]
6. Thallium (Tl) 6s[sup(2)]6p[sup(1)]
8 The Carbon Group
1. Introduction
2. Carbon (C) 2s[sup(2)]2p[sup(2)]
3. Silicon (Si) 3s[sup(2)]3p[sup(2)]
4. Germanium (Ge) 4s[sup(2)]4p[sup(2)]
5. Tin (Sn) 5s[sup(2)]5p[sup(2)]
6. Lead (Pb) 6s[sup(2)]6p[sup(2)]
9 The Nitrogen Group
1. Introduction
2. Nitrogen (N) 2s[sup(2)]2p[sup(3)]
3. Phosphorus (P) 3s[sup(2)]3p[sup(3)]
4. Arsenic (As) 4s[sup(2)4p[sup(3)]
5. Antimony (Sb) 5s[sup(2)]5p[sup(3)]
6. Bismuth (Bi) 6s[sup(2)]6p[sup(3)]
10 The Oxygen Group
1. Introduction
2. Oxygen (O) 2s[sup(2)]2p[sup(4)]
3. Sulfur (S) 3s[sup(2)]3p[sup(4)]
4. Selenium (Se) 4s[sup(2)]4p[sup(4)]
5. Tellurium (Te) 5s[sup(2)]5p[sup(4)]
6. Polonium (Po) 6s[sup(2)]6p[sup(4)]
11 The Fluorine Group
1. Introduction
2. Fluorine (F) 2s[sup(2)]2p[sup(5)]
3. Chlorine (Cl) 3s[sup(2)]3p[sup(5)]
4. Bromine (Br) 4s[sup(2)]4p[sup(5)]
5. Iodine (I) 5s[sup(2)]5p[sup(5)]
6. Astatine (At) 6s[sup(2)]6p[sup(5)]
12 The Scandium Group
1. Introduction
2. Occurrences
3. Discoveries
4. Scandium (Sc) 4s[sup(2)]3d[sup(1)]
5. The Lanthanoids (La-Lu) 6s[sup(2)]5d[sup(0-1)]4f[sup(n)], Including Y, 5s[sup(2)]4d[sup(1)] (All Referred to as Ln)
6. Actinium (Ac) 6s[sup(2)]5d[sup(1)]
13 The Ti Group and the 5B, 6B, 7B and 8B Heavy Elements
1. General Introduction
2. Introduction to the Insoluble-oxide Elements: Ti, Zr, Hf, Nb, Ta
3. Titanium (Ti) 4s[sup(2)]3d[sup(2)]
4. Zirconium (Zr) 5s[sup(2)]4d[sup(2)] and Hafnium (Hf) 6s[sup(2)]5d[sup(2)]
5. Niobium (Nb) 5s[sup(2)]4d[sup(3)]
6. Tantalum (Ta) 6s[sup(2)]5d[sup(3)]
7. Introduction to the High Oxidation State Oxyanion Elements: Mo, W, Tc, Re
8. Molybdenum (Mo) 5s[sup(1)]4d[sup(5)]
9. Tungsten (W) 6s[sup(1)]5d[sup(5)]
10. Rhenium (Re) 6s[sup(2)]5d[sup(5)]
11. Technetium (Tc) 5s[sup(2)]4d[sup(5)]
12. Introduction to the Noble Metal Elements: Ru, Rh, Pd, Os, Ir, Pt
13. Ruthenium (Ru) 5s[sup(1)]4d[sup(7)]
14. Osmium (Os) 6s[sup(2)]5d[sup(6)]
15. Rhodium (Rh) 5s[sup(1)]4d[sup(8)]
16. Iridium (Ir) 6s[sup(2)]5d[sup(7)]
17. Palladium (Pd) 5s[sup(0)]4d[sup(10)]
18. Platinum (Pt) 6s[sup(1)]5d[sup(9)]
14 The V-Cr-Mn Group
1. Introduction
2. Vanadium (V) 4s[sup(2)]3d[sup(3)]
3. Chromium (Cr) 4s[sup(1)]3d[sup(5)]
4. Manganese (Mn) 4s[sup(2)]3d[sup(5)]
15 The Fe-Co-Ni Group
1. Introduction
2. Iron (Fe) 4s[sup(2)]3d[sup(6)]
3. Cobalt (Co) 4s[sup(2)]3d[sup(7)]
4. Nickel (Ni) 4s[sup(2)]3d[sup(8)]
16 The Cu Group
1. Introduction
2. Copper (Cu) 4s[sup(1)]3d[sup(10)]
3. Silver (Ag) 5s[sup(1)]4d[sup(10)]
4. Gold (Au) 6s[sup(1)]5d[sup(10)]
17 The Zn Group
1. Introduction
2. Zinc (Zn) 4s[sup(2)]3d[sup(10)]
3. Cadmium (Cd) 5s[sup(2)]4d[sup(10)]
4. Mercury (Hg) 6s[sup(2)]5d[sup(10)]
18 The Actinoid Metals
1. Introduction
2. Availabilities of the Elements
3. Discoveries and Extractions
4. Elements and Compounds
5. E-pH Diagrams
6. Complexes
7. Trans-lawrencium Elements
References
Index
A
B
C
D
E
F
G
H
I
L
M
N
O
P
R
S
T
U
V
W
Y
Z

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