Catalysis by Metals and Alloys

Name: Catalysis by Metals and Alloys
Brand: Elsevier
Price: 54.95 EUR
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V. Bond G. C. Ponec G. C. Bond(Autor*in)

Elsevier (Verlag)

Erschienen am 29. August 1995

745 Seiten

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978-0-08-052865-6 (ISBN)

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Cover
Copyright Page
Contents
PROLOGUE
CHAPTER 1. STRUCTURE AND PROPERTIES OF METALS AND ALLOYS
1.1 A microscopic theory of solids
1.2 Some results of the theory of chemisorption on metals and alloys
1.3 Adsorption of molecules and radicals which are intermediates in catalytic reactions
1.4 Macroscopic thermodynamic theory of alloys
CHAPTER 2. EXPERIMENTAL TECHNIQUES OF SOLID STATE PHYSICS, RELEVANT TO RESEARCH ON ALLOYS
2.1 Photoelectron Spectroscopy (PES)
2.2 Auger spectroscopy
2.3 Other methods
CHAPTER 3. THE ELECTRONIC STRUCTURE OF ALLOYS
EXPERIMENTAL RESULTS
3.1 Magnetic measurements
3.2 The Mössbauer effect
3.3 Photoemission Spectroscopy (PES)
3.4 Soft X-ray emission and absorption
3.5 Conclusions
CHAPTER 4. SURFACE COMPOSITION OF ALLOYS
4.1 General remarks on surfaces of metals
4.2 Binary systems with surface segregation
4.3 Surface segregation in catalytically interesting alloys
CHAPTER 5. PHYSICAL PROPERTIES AND STRUCTURES OF SMALL METAL AND ALLOY PARTICLES
5.1 The electronic structure of small free metal particles
5.2 Equilibrium shape and thermal properties of small metal particles
5.3 Adsorption sites on small metal particles
5.4 Reactivity of small metal particles
5.5 Polarization and charging of small metal particles by a support
CHAPTER 6. THE CATALYTIC CYCLE
6.1 Prelude
6.2 The role of reaction mechanism in catalytic research
6.3 Methods of investigating catalysed reactions
6.4 Kinetics of heterogeneously catalysed reactions
6.5 Structure sensitivity and particle size effects
6.6 Catalytic consequence of metal-support interactions
CHAPTER 7. PREPARATION AND CHARACTERIZATION OF METAL AND ALLOY CATALYSTS
7.1 Macroscopic materials
7.2 Small unsupported metal particles
7.3 Supported metal catalysts
7.4 Characterization of alloy catalysts
CHAPTER 8. ADSORPTION ON ALLOYS
8.1 Ensemble size and composition effects
8.2 Ensemble statistics and the extent of adsorption
8.3 Adsorption as a probe of active sites on alloys
8.4 Adsorption of simple gases on alloys
CHAPTER 9. CATALYSIS BY ALLOYS - GENERAL FEATURES
9.1 Basic problems
9.2 Investigation of electronic structure effects by means of catalytic reactions
9.3 Important side effects of alloying
CHAPTER 10. REACTIONS OF HYDROGEN AND ALKANE-DEUTERIUM EXCHANGE
10.1 Reactions involving only hydrogen and its analogues
10.2 The equilibrium of hydrogen + deuterium and para- hydrogen conversion
10.3 Exchange of alkanes with deuterium
CHAPTER 11. CATALYTIC HYDROGENATION AND DEHYDROGENATION
11.1 Hydrogenation of alkenes
11.2 Hydrogenation of alkynes and alkadienes
11.3 Hydrogenation of aromatic compounds
11.4 Hydrogenation of other unsaturated groups
11.5 Dehydrogenation
11.6 Hydrogenation of diatomic molecules: oxygen and nitrogen
CHAPTER 12. OXIDATION REACTIONS
12.1 Fundamentals - chemisorption of the reactants
12.2 Selected information on simple oxidation reactions on metals
12.3 Oxidations on alloys
12.4 Practical applications of oxidation reactions on metals and alloys
CHAPTER 13. REACTIONS OF ALKANES AND REFORMING OF NAPHTHA
13.1 Fundamentals
13.2 Model reactions of alkanes on alloys
13.3 Fundamental studies on reforming catalysts
13.4 Various combinations containing two transition metals
13.5 Platinum-tin and other related catalysts
13.6 Reforming of naphtha
CHAPTER 14. SYNGAS REACTIONS
14.1 Fundamentals
14.2 Alloys in Fischer-Tropsch synthesis:combinations of active and inactive metals
14.3 Alloys in Fischer-Tropsch synthesis:combinations of two active metals
14.4 Industrial processes with syngas
EPILOGUE
SUBJECT INDEX

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