Fullerenes and Other Carbon-Rich Nanostructures

Name: Fullerenes and Other Carbon-Rich Nanostructures
Brand: Springer
Price: 213.99 EUR
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Jean-François Nierengarten(Herausgeber*in)

Springer (Verlag)

Erschienen am 16. Mai 2014

VII, 259 Seiten

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978-3-642-54854-3 (ISBN)

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Inhalt

Intro
Preface
Contents
Exotic Self-Organized Fullerene Materials Based on Uncommon Hydrophobic-Amphiphilic Approach
1 Introduction
2 Self-Assemblies of Pristine C60
2.1 Controlled Assembly of C60
2.2 Supramolecular Coassembly
3 Exotic Assemblies of Uncommon Hydrophobic C60 Amphiphiles
3.1 Morphology Control
3.2 Morphology-Related Functions
3.3 Supramolecular Composites
4 Soft to Hard: Plasticization and Metallization
5 Exotic Fluid Materials
5.1 Liquid Crystalline Assemblies
5.2 Room Temperature Liquid Fullerenes
6 Conclusion
References
C60 Fullerene Amphiphiles as Supramolecular Building Blocks for Organized and Well-Defined Nanoscale Objects
1 Introduction
2 Molecular Packing of Amphiphiles
3 Nano-Aggregates Assembled by C60 Amphiphiles Bearing Chain-Like Polar Appendages
4 Nano-Aggregates Assembled by C60 Amphiphiles Bearing Branched or Dendritic Polar Appendages
5 Nano-Aggregates Assembled by Amphiphilic Hexakis Adducts of C60
6 Summary and Outlook
References
Multilayer Assembly for Solar Energy Conversion
1 Introduction
2 Historical Background
2.1 Langmuir/Langmuir Blodgett
2.2 Layer-by-Layer
3 Fundamental Concepts and Mechanisms of Multilayer Formation
3.1 Deposition of Langmuir-Blodgett Films
3.2 Layer-by-Layer Assembly
4 Thin Films of Carbon Nanotubes and Fullerenes
4.1 Langmuir-Blodgett Films
4.1.1 Fullerenes
4.1.2 Carbon Nanotubes
4.2 Layer-by-Layer Films
5 Applications of Multilayer Assemblies in Photovoltaic Devices
5.1 Langmuir-Blodgett and Langmuir-Schaefer Film-Based Solar Cells
5.1.1 Fullerenes
5.1.2 Carbon Nanotubes
5.2 Layer-by-Layer Film-Based Solar Cells
5.2.1 Fullerenes
5.2.2 Carbon Nanotubes
6 Summary and Outlook
References
Self- or Induced Organization of [60]Fullerene Hexakisadducts
1 Introduction
2 Thin Films as Induced Organization of [60]Fullerene Hexakisadducts
2.1 [5:1] Hexakisadducts
2.1.1 Dendritic Structure
With Ester Link
With Amide Link
2.1.2 Linear Structure
2.1.3 Steroid-Based
2.2 [3:3] Hexakisadducts
3 Thermotropic Liquid-Crystalline Hexakisadducts
3.1 Enantiotropic Smectic A Phase
3.2 Nematic Phase
3.2.1 Transient Phase
3.2.2 Chiral
3.2.3 Constrained
4 Self-organization Through Micelles, Nanospheres
4.1 [6:0] Hexakisadduct
4.1.1 As Unimolecular Micelles
4.1.2 Lipofullerenes
4.1.3 Polymerized Lipofullerenes
4.2 Dendritic [5:1] hexakisadduct
4.3 Dendritic [3:3] Hexakisadduct
5 Conclusions
References
Dual Role of Phthalocyanines in Carbon Nanostructure-Based Organic Photovoltaics
1 Introduction
2 Basic Principles of Organic Solar Cells
3 Phthalocyanines as Electron-Donor Photoactive Materials
4 Carbon Nanostructures as Electron-Acceptor Materials
5 (Sub)Phthalocyanine/Fullerene Donor/Acceptor Systems
5.1 Covalent (Sub)Phthalocyanine-Fullerene Ensembles
5.2 Self-Assembly and Supramolecular Organization of (Sub)Phthalocyanine-Fullerene Ensembles
5.3 (Sub)Phthalocyanine/Fullerene-Based Organic Solar Cells
5.3.1 PHJ Devices
5.3.2 Co-evaporated Devices
5.3.3 Small-Molecule Bulk Heterojunction Devices
5.3.4 Polymer-Based BHJ Devices
6 Phthalocyanine/Carbon Nanotube Donor/Acceptor Systems
6.1 Covalent Attachment of Pcs to Carbon Nanotubes
6.2 Non-Covalent Interactions Between Pcs and Carbon Nanotubes
7 (Sub)Phthalocyanines as Electron-Acceptor Photoactive Materials
8 Conclusions
References
Supramolecular Chemistry of Carbon Nanotubes at Interfaces: Toward Applications
1 Introduction
2 Supramolecular Chemistry of Carbon Nanotubes at the Interfaces
2.1 Carbon Nanotubes at the Solid/Liquid Interface
2.2 Carbon Nanotubes at the Liquid/Liquid Interface
2.3 Carbon Nanotubes at the Gas/Solid Interface
2.4 Carbon Nanotubes at the Biological Interface
3 Conclusions
References
Oligomers from sp-Hybridized Carbon: Cumulenes and Polyynes
1 Introduction
2 Synthesis
2.1 Cumulene Synthesis
2.1.1 Synthesis of Aryl-Substituted Series of [n]cumulenes
2.1.2 Synthesis of an Alkyl-Substituted Series of [n]cumulenes
2.2 Polyyne Synthesis
3 Structure and Bonding
3.1 Vibrational Spectroscopy
3.1.1 Cumulenes
3.1.2 Polyynes
3.2 13C NMR Spectroscopy
3.2.1 Cumulenes
3.2.2 Polyynes
3.3 UV/Vis Spectroscopy
3.3.1 Cumulenes
3.3.2 Polyynes
3.4 X-ray Crystallography
3.4.1 Cumulenes
3.4.2 Polyynes
4 Conclusions
References
Index

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