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This book provides a deep insight into recent achievements in synthesis, investigation, and applications of the low-dimensional chalcohalide nanomaterials. The large number of interesting phenomena occur in these compounds, including ferroelectric, piezoelectric, pyroelectric, electrocaloric, Seebeck, photovoltaic, and ferroelectric-photovoltaic effects. Furthermore, the outstanding photoelectrochemical, photocatalytic, and piezocatalytic properties of the chalcohalide nanomaterials have been revealed. Since many chalcohalide semiconductors possess both photoactive and ferroelectric properties, they are recognized as photoferroelectrics.
It presents an overview of fabrication of chalcohalide nanomaterials using different methods: mechanical milling of bulk crystals, liquid-phase exfoliation, vapor phase growth, hydro/solvothermal methods, synthesis under ultrasonic irradiation, microwave synthesis, laser/heat-induced crystallization, electrospinning, successive ionic layer adsorption and reaction. The strategies of the chalcohalide nanomaterials processing for construction of functional devices are presented.
The book describes solution processing for thin films preparation, spin-coating deposition of polymer composites, solution casting, films deposition via drop-casting, high pressure compression of nanowires into the bulk samples, pressure assisted sintering, and electric field assisted alignment of nanowires. The applications of the chalcohalide nanomaterials for mechanical/thermal energy harvesting and energy storage are presented. Major challenges and emerging trends in fabrication, characterization, and future applications of low-dimensional chalcohalide nanomaterials are discussed.
A wealth of information for scholars, graduate students, and engineers involved in research of nanomaterials.
Krystian Mistewicz was born in 1986. He received MSc in physics with honors at the Mathematics and Physics Faculty at the Silesian University of Technology (Gliwice, Poland) in 2010, and Ph.D. in physics with distinction from the University of Silesia (Katowice, Poland) in 2015. He is currently an assistant professor at Institute of Physics at the Silesian University of Technology. He was a visiting research scholar at the University of Wisconsin-Madison (USA). In 2021, Krystian Mistewicz received IAAM Young Scientist Medal from International Association of Advanced Materials (Sweden). His research interests are focused on nanotechnology, sonochemistry, ferroelectric nanomaterials for gas sensors, photovoltaic devices, pyroelectric and piezoelectric generators.
Introduction.- The Methods of Fabrication of the Chalcohalide Nanostructures.- Strategies for Incorporation of Chalcohalide Nanomaterials into the Functional Devices.- Devices for Energy Harvesting and Storage.- Photovoltaic Devices and Photodetectors.- Gas Nanosensors.- The Catalysts for an Environmental Remediation.- Conclusions and Future Prospects.
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