Coulometry in Analytical Chemistry

Basic References Reproduced in Chapter VIIPreface1 Introduction2 Theoretical Treatment 2.1. Constant-Current Coulometry 2.1.1. Methods of End-Point Determination 2.2. Constant-Potential Coulometry 2.2.1. Measurement of Total Current 2.2.2. Working Electrode Potentials3 Equipment and Technique for Constant-Current Coulometry 3.1. Current Sources 3.2. Measurement of the Quantity of Electricity 3.3. Electrolysis Cells 3.3.1. Cells for the External Generation of Titrants 3.4. Differential Coulometric Titrations4 Equipment for Controlled-Potential Coulometry 4.1. Coulometers for Controlled-Potential Coulometry 4.1.1. Chemical Integration 4.1.2. Electrical and Electromechanical Integration 4.1.3. Electronic Integration 4.2. Controlled-Potential Coulometric Titrators 4.3. High Sensitivity Controlled-Potential Coulometric Titrators 4.4. Differential Controlled-Potential Coulometry 4.5. Cells for Controlled-Potential Coulometry 4.5.1. Cells for Use with Solid-Working Electrodes 4.5.2. Cells for Use with a Stirred-Mercury Electrode5. Applications of Controlled-Potential Coulometry 5.1. Inorganic 5.2. Organic6. Constant-Current Coulometric Titrations 6.1. Redox, Complexometric and Precipitation Titrations for Inorganic Substances 6.2. Redox, Complexometric and Precipitation Titrations for Organic Substances 6.3. Neutralization Titrations in Inorganic and Organic Analysis7. Fundamental Papers in the Development of Coulometry 7.1. Constant-Current Coulometry 7.2. Controlled-Potential Coulometry 7.2.1. Control of Potential 7.2.2. Developments in Integration 7.2.3. Fundamental Principles 7.2.4. Background Corrections in Controlled-Potential Coulometric AnalysisIndex