For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century.
The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
Rezensionen / Stimmen
From the reviews:
"'This book is a remarkably useful contribution to the literature of organosilicon chemistry and silicon-based polymers. . I do highly recommend this book to researchers concerned with this area. For research libraries, it represents a very timely and thorough compilation of the literature . .' For those of us working in organosilicon chemistry, this is a useful compendium of the recent developments in hydrosilylation reactions. . I am happy to recommend this book to individuals and institutions with research interests in silicon chemistry." (Stephen J. Clarson, Silicon, Vol. 1, 2009)
Reihe
Sprache
Verlagsort
Verlagsgruppe
Illustrationen
Dateigröße
ISBN-13
978-1-4020-8172-9 (9781402081729)
DOI
10.1007/978-1-4020-8172-9
Schweitzer Klassifikation
Hydrosilylation of Carbon-Carbon Multiple Bonds in Synthesis of Molecular Organosilicon Compounds.- Hydrosilylation of Alkenes and Their Derivatives.- Hydrosilylation of Alkynes and Their Derivatives.- Hydrosilylation of Carbon-Carbon Multiple Bonds in Organic Synthesis.- Asymmetric Hydrosilylation of Prochiral Alkenes and Their Derivatives.- Hydrosilylation of Carbon-Carbon Multiple Bonds in Polymer Chemistry and Materials Science.- Functionalisation and Cross-Linking of Organosilicon Polymers.- Hydrosilylation Polymerisation.- Functionalised (Poly)silsesquioxanes and Silicon-Containing Dendrimers.- Organosilicon - Organic Hybrid Polymers and Materials.- Chemo- and Enantio-Selective Hydrosilylation of Unsaturated Carbon-Heteroatom Bonds.- Hydrosilylation of Unsaturated Carbon-Heteroatom Bonds.- Asymmetric Hydrosilylation of Unsaturated Carbon-Heteroatom Bonds.
