International Series of Monographs in Analytical Chemistry, Volume 50: N-Benzoylphenylhydroxylamine and its Analogues covers the analytical applications of the organic hydroxylamine derivatives.
This book is composed of seven chapters, and starts with a brief historical account of the uses of organic reagents in inorganic analysis. The next chapter discusses some basic physico-chemical factors associated with the constitution of a good reagent, including some fundamental ideas about the type and nature of the principal reactive and other groupings in the ligand. A chapter deals with the inclusion of the methods of preparation and properties of N-benzoylphenylhydroxylamine (BPHA) and its analogues and derivatives, and their reactions with different metal ions. These topics are followed by descriptions of the various types of analytical applications of BPHA and its analogues, such as gravimetry, spectrophotometry, and solvent extraction, as well as their applications in titrimetry and paper chromatography.
This book is of value to analytical and organic chemists.
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978-1-4832-7863-6 (9781483278636)
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Preface 1. Introduction Organic Reagents in Inorganic Analysis References 2. The Effect of Atomic Groupings and Substituents on Reagents Cupferrons Hydroxytriazenes Hydroxamic Acids Hydroxylamines References 3. Preparation and Properties of N-Benzoylphenylhydroxylamine and its Analogues 30 N-Benzoylphenylhydroxy lamine {BPHA) N-Substituted Phenylhydroxylamines N-Acetylphenylhydroxylamine N-2-Thiophenecarbonyl-p-tolylhydroxylamine Spectral Characteristics of p-TTHA and PTHA N-Benzoyl-o-tolylhydroxylamine H-Benzoyl-p-tolylhydroxylamine and N-benzoyl-m-tolylhydroxylamine N-Cinnamoylphenylhydroxylamine N-Phenylacetylphenylhydroxylamine N-Benzoyl-p-chlorophenylhydroxylamine N-Salicylphenylhydroxylamine N-Acetylsalicylphenylhydroxylamine N-Benzoylmethylhydroxylamine N-Substituted Arylhydroxylamines N-Thiobenzoylphenylhydroxylamine (TBPHA) References4. Gravimetric Determination of the Elements with N-Benzoylphenylhydroxylamine and its Analogues 1. Applications of N-Benzoylphenylhydroxylamine 2. Applications of N-Cinnamoylphenylhydroxylamine 3. Applications of N-Benzoyl-o-tolylhydroxylamine 4. Application of N-Salicylphenylhydroxylamine 5. Application of N-Acetylsalicylphenylhydroxylamine 6. Applications of Thiobenzoylphenylhydroxylamine References 5. Spectrophotometric Determination of the Elements with N-Benzoylphenylhydroxylamine and its Analogues 1. N-Benzoylphenylhydroxyfamine as a Spectrophotometric Reagent 2. N-Acetylphenylhydrïxyfamine as a Spectrophotometric Reagent 3. N-Benzoylmethylhydroxylamine as a Spectrophotometric Reagent 4. N-2-Thiophenecarbonyl-p-tolylhydroxylamine and N-2-thiophenecarbonylphenylhydroxylamine as Spectrophotometric Reagents 5. N-Cinnamoylphenylhydroxylamine as a Spectrophotometric Reagent 6. N-Benzoyl-p-tolylhydroxylamine as a Spectrophotometric Reagent 7. N-Benzoyl-o-tolylhydroxylamine as a Spectrophotometric Reagent 8. N-Benzoyl-p-chlorophenylhydroxyfamine as a Spectrophotometric Reagent 9. N-Benzoyl-o-tolylhydroxy famine and Other Aromatic Hydroxylamines as Spectrophotometric Reagents 10. N-Furoylphenylhydroxylamine as a Spectrophotometric Reagent 11. N-Acetylsalicylphenylhydroxyfamine as a Spectrophotometric Reagent 12. N-Arylhydroxyfamines as Spectrophotometric Reagents References 6.
