Non-covalent Interactions in the Synthesis and Design of New Compounds

Name: Non-covalent Interactions in the Synthesis and Design of New Compounds
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Abel M. Maharramov Kamran T. Mahmudov Maximilian N. Kopylovich Armando J. L. Pombeiro(Herausgeber*in)

Wiley (Verlag)

Erschienen am 3. Mai 2016

480 Seiten

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978-1-119-11385-0 (ISBN)

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Inhalt

Intro
TITLE PAGE
COPYRIGHT PAGE
CONTENTS
NOTES ON EDITORS
LIST OF CONTRIBUTORS
PREFACE
PART I ORGANIC SYNTHESIS
CHAPTER 1 ACTIVATION OF COVALENT BONDS THROUGH NON-COVALENT INTERACTIONS
1.1 INTRODUCTION
1.2 EXAMPLES OF HYDROGEN BOND-ASSISTED ACTIVATIONS
1.3 HALOGEN BOND-ASSISTED ACTIVATIONS
1.4 OTHER TYPES OF NON-COVALENT INTERACTIONS AND PERSPECTIVES
1.5 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 2 BORON-NITROGEN BOND: A USEFUL MOLECULAR CONSTRUCTION TOOL
2.1 INTRODUCTION
2.2 BN AROMATIC HETEROCYCLES
2.3 BN NONAROMATIC HETEROCYCLES
2.4 BN INTERACTION: SUPRAMOLECULAR ARCHITECTURES
2.5 BN INTERACTION: CHEMOSENSING
2.6 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 3 INFLUENCE OF STERIC, ELECTRONIC, AND MOLECULAR PREORGANIZATION EFFECTS IN THE REACTIVITY OF ß-PHENYLETHYLAMINES WITH NONENOLIZABLE ALDEHYDES
3.1 INTRODUCTION
3.2 DOPAMINE REACTION WITH NONENOLIZABLE ALDEHYDES: THE PICTET-SPENGLER REACTION
3.3 TYROSINE DERIVATIVES REACTION WITH NONENOLIZABLE ALDEHYDES
3.4 NON-COVALENT INTERACTIONS REGARDING L-TYROSINE AND ITS TETRABUTYLAMMONIUM SALT
3.5 TYRAMINE AND ß-PHENYLETHYLAMINE REACTION WITH FORMALDEHYDE
3.6 BENZYLAZACYCLOPHANE SYNTHESIS
3.7 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 4 NON-COVALENT INTERACTIONS IN THE SYNTHESIS OF MACROCYCLES
4.1 INTRODUCTION
4.2 ANION-TEMPLATED SYNTHESIS
4.3 CATION-TEMPLATED SYNTHESIS
4.4 HYDROGEN BOND-DIRECTED SYNTHESIS
4.5 OTHER MACROCYCLIZATIONS
4.6 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
PART II INORGANIC, COORDINATION AND ORGANOMETALLIC SYNTHESES
CHAPTER 5 NON-COVALENT INTERACTIONS OF WATER WITH METAL COMPLEXES IN SOLUTION
5.1 INTRODUCTION
5.2 HYDROGEN BONDING AND VAN DER WAALS INTERACTIONS
5.3 NEUTRON AND X-RAY METHODS TO INVESTIGATE STRUCTURAL ASPECTS OF METAL ION AND METAL COMPLEX SOLVATION AND THEIR SOLUTION STRUCTURE
5.4 WATER, METAL IONS, AND METAL COMPLEXES IN SOLUTION
5.5 FINAL COMMENTS
ACKNOWLEDGEMENTS
REFERENCES
CHAPTER 6 P-P INTERACTION DIRECTED APPLICATIONS OF METAL COMPLEXES
6.1 INTRODUCTION
6.2 MODEL AND SOME RULES OF P-P STACKING
6.3 CATALYSIS
6.4 MAGNETISM
6.5 PHOTOPHYSICAL PROPERTIES
6.6 CONCLUSION
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 7 NON-COVALENT STABILIZATION IN TRANSITION METAL COORDINATION AND ORGANOMETALLIC COMPLEXES
7.1 INTRODUCTION
7.2 THEORETICAL CHALLENGES IN ADDRESSING NCIS AND DISPERSION IN TRANSITION METAL COMPLEXES
7.3 INTRAMOLECULAR NCIS AS A STABILIZING FACTOR
7.4 FACE-SELECTIVE METAL COORDINATION TO AROMATIC LIGANDS
7.5 INTERMOLECULAR NCIS IN METAL-METAL DA COMPLEXES AND OTHER AGGREGATES
7.6 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 8 HALOGEN BONDING IN THE SYNTHESIS AND DESIGN OF COORDINATION AND ORGANOMETALLIC COMPOUNDS
8.1 INTRODUCTION
8.2 HALOGEN-HALOGEN BONDING
8.3 HALOGEN-NITROGEN INTERACTIONS
8.4 HALOGEN-CHALCOGEN BONDING
8.5 HALOGEN BONDING IN ORGANOMETALLIC COMPOUNDS
8.6 FINAL REMARKS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 9 THE INFLUENCE OF NON-COVALENT INTERACTIONS IN THE STRUCTURE AND DIMENSIONALITY OF HYBRID COMPOUNDS AND COORDINATION POLYMERS
9.1 INTRODUCTION
9.2 NON-COVALENT INTERACTIONS IN LAYERED AND 3D OPEN FRAMEWORK ZIRCONIUM AMINOPHOSPHONATES
9.3 THE ROLE OF P.P STACKING IN THE ASSEMBLY, DIMENSIONALITY, AND STABILITY OF CPS
9.4 SUPRAMOLECULAR INTERACTIONS AFFECTING THE METAL COORDINATION
9.5 THE RELATIONSHIP BETWEEN NETWORK DIMENSIONALITY AND CATION SIZE
9.6 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
PART III CRYSTAL DESIGN AND HOST-GUEST COMPOUNDS
CHAPTER 10 DIHALOGENS AS HALOGEN BOND DONORS
10.1 INTRODUCTION
10.2 TYPICAL HALOGEN BOND DONORS
10.3 TYPICAL HALOGEN BOND ACCEPTORS
10.4 BASIC FEATURES OF DIHALOGENS
10.5 CHARGE TRANSFER AND DIHALOGENS
10.6 CASE STUDIES
10.7 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 11 CONSTRUCTION OF SUPRAMOLECULAR ASSEMBLIES BASED ON ANION-P INTERACTIONS
11.1 INTRODUCTION
11.2 PHYSICAL NATURE
11.3 EXAMPLES OF SUPRAMOLECULAR ASSEMBLIES
11.4 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 12 ASYMMETRIC AZAMACROCYCLES AS CHIRAL SOLVATING AGENTS
12.1 INTRODUCTION
12.2 BINOL-BASED CHIRAL MACROCYCLIC AMINES
12.3 CHIRAL MACROCYCLIC AMIDES
12.4 CHIRAL MACROCYCLIC AMINES
12.5 CHIRAL AZA-CROWN MACROCYCLES
12.6 FINAL COMMENTS
REFERENCES
CHAPTER 13 NEW STRATEGIES FOR THE DESIGN OF INCLUSION COMPOUNDS WITH CUCURBITURIL HOSTS
13.1 INTRODUCTION
13.2 PROMINENT FEATURES OF CBN FOR HOST-GUEST CHEMISTRY
13.3 STIMULI-RESPONSIVE SUPRAMOLECULAR NANOSTRUCTURES
13.4 CONCLUDING REMARKS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 14 PARALLEL INTERACTIONS OF AROMATIC MOLECULES AT LARGE HORIZONTAL DISPLACEMENTS
14.1 INTRODUCTION
14.2 PARALLEL WATER-AROMATIC INTERACTIONS AT LARGE HORIZONTAL DISPLACEMENTS
14.3 PARALLEL INTERACTIONS BETWEEN AROMATIC RINGS AT LARGE HORIZONTAL DISPLACEMENTS
14.4 CONCLUSIONS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 15 SELECTIVE MOLECULAR BINDING AND NANOSUPRAMOLECULAR ASSEMBLY OF P-SULFONATOCALIX[N]ARENES
15.1 INTRODUCTION
15.2 SELECTIVE MOLECULAR BINDING
15.3 NANOSUPRAMOLECULAR ASSEMBLY
15.4 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 16 SYNTHESIS, DESIGN, CHARACTERIZATION, AND APPLICATION OF METALLO-SUPRAMOLECULAR POLYMERS
16.1 INTRODUCTION
16.2 SYNTHESIS OF MSPS
16.3 DESIGN OF MSPS
16.4 APPLICATIONS OF MSPS
16.5 CONCLUSIONS
ACKNOWLEDGMENTS
REFERENCES
PART IV CATALYSIS
CHAPTER 17 CATALYTIC APPLICATIONS OF METAL COMPLEXES IMMOBILIZED BY NON-COVALENT INTERACTIONS ONTO CHEMICALLY DERIVED GRAPHENES AND RELATED MATERIALS
17.1 INTRODUCTION
17.2 PREPARATION OF CDGS
17.3 FUNCTIONALIZATION BY NON-COVALENT INTERACTIONS
17.4 CATALYTIC APPLICATIONS
17.5 PERSPECTIVES
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 18 COOPERATION OF NON-COVALENT INTERACTIONS AND COORDINATION IN CATALYSIS
18.1 INTRODUCTION
18.2 HYDROGEN BONDING COOPERATION WITH COORDINATION
18.3 HALOGEN BONDING COOPERATION WITH COORDINATION OR HYDROGEN BONDING
18.4 COOPERATION OF COORDINATION WITH OTHER TYPES OF NON-COVALENT INTERACTIONS
18.5 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 19 HYBRID ORDERED MESOPOROUS MATERIALS AS SUPPORTS FOR PERMANENT ENZYME IMMOBILIZATION THROUGH NON-COVALENT INTERACTIONS
19.1 INTRODUCTION
19.2 NON-COVALENT METHODS OF ENZYME IMMOBILIZATION
19.3 ORDERED MESOPOROUS MATERIALS
19.4 NON-COVALENT IMMOBILIZATION OF ENZYMES ON ORDERED MESOPOROUS MATERIALS
19.5 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
PART V BIORELEVANT SYNTHESES
CHAPTER 20 MODULATION OF BIORELEVANT RADICAL REACTIONS BY NON-COVALENT INTERACTIONS
20.1 INTRODUCTION
20.2 SOLVENT EFFECTS IN RADICAL REACTIONS
20.3 QUANTITATIVE TREATMENT OF H-BOND STRENGTH IN SOLUTION: ABRAHAM'S SOLVATOCHROMIC PARAMETERS
20.4 EFFECT OF NON-COVALENT INTERACTIONS ON REACTIONS OF PHENOLIC ANTIOXIDANTS WITH PEROXYL RADICALS
20.5 EFFECTS OF NON-COVALENT INTERACTIONS ON THE REACTIVITY OF PHENOXYL RADICALS
20.6 EFFECTS OF NON-COVALENT INTERACTIONS ON THE REACTIONS OF ALKOXYL RADICALS WITH AMINES OR AMIDES
20.7 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 21 CURRENT UNDERSTANDING OF P-P INTERACTIONS AND THE APPLICATIONS IN PROTEIN DESIGN
21.1 INTRODUCTION
21.2 SIGNIFICANCE OF P-P INTERACTIONS IN PROTEIN FOLDING
21.3 P-P INTERACTIONS IN PEPTIDE ASSEMBLY
21.4 P-P INTERACTIONS IN PEPTIDE THERAPEUTICS
21.5 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
CHAPTER 22 NON-COVALENT INTERACTIONS FOR THE PREPARATION OF PSEUDOPEPTIDIC SYNTHETIC COMPOUNDS AND MATERIALS
22.1 INTRODUCTION
22.2 NON-COVALENT INTERACTIONS IN THE PREPARATION OF CYCLIC PSEUDOPEPTIDES
22.3 PSEUDOPEPTIDES IN DYNAMIC COVALENT CHEMISTRY
22.4 NON-COVALENT INTERACTIONS IN PEPTIDE-LIKE FOLDAMERS
22.5 SELF-ASSEMBLED PSEUDOPEPTIDES FOR THE PREPARATION OF NANOSTRUCTURES
22.6 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
PART VI MATERIAL CHEMISTRY
CHAPTER 23 NON-COVALENT EXFOLIATION OF GRAPHITE TO PRODUCE GRAPHENE
23.1 INTRODUCTION
23.2 SOLID-PHASE EXFOLIATION
23.3 LIQUID-PHASE EXFOLIATION
23.4 CONCLUSIONS AND OUTLOOK
ACKNOWLEDGEMENTS
REFERENCES
CHAPTER 24 ELECTROSTATIC INTERACTIONS IN THE DESIGN OF POLYMERIC PRODUCTS
24.1 INTRODUCTION
24.2 SYNTHETIC STRATEGIES
24.3 PROPERTIES OF IONOMERS
24.4 PERSPECTIVE IN FUTURE RESEARCH
REFERENCES
CHAPTER 25 SUPRAMOLECULAR STERIC HINDRANCE AT BULKY ORGANIC/POLYMER SEMICONDUCTORS AND DEVICES
25.1 INTRODUCTION
25.2 FOUR-ELEMENT DESIGN PRINCIPLE
25.3 SSH IN ORGANIC SEMICONDUCTORS
25.4 EXTENSION OF SSH CONCEPT TO POLYMER SEMICONDUCTORS
25.5 FINAL COMMENTS
ACKNOWLEDGMENTS
REFERENCES
INDEX
EULA

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