1 - Science of Synthesis: Knowledge Updates 2012/1 [Seite 1]
1.1 - Title page [Seite 5]
1.2 - Imprint [Seite 7]
1.3 - Preface [Seite 8]
1.4 - Abstracts [Seite 10]
1.5 - Overview [Seite 18]
1.6 - Table of Contents [Seite 20]
1.7 - Volume 2: Compounds of Groups 7-3 (Mn···, Cr···, V···, Ti···, Sc···, La···, Ac···) [Seite 38]
1.7.1 - 2.10 Product Class 10: Organometallic Complexes of Titanium [Seite 38]
1.7.1.1 - 2.10.19 Organometallic Complexes of Titanium (Update 1) [Seite 38]
1.7.1.1.1 - 2.10.19.1 Titanium-Mediated Synthesis of Cyclopropyl Derivatives [Seite 38]
1.7.1.1.1.1 - 2.10.19.1.1 Synthesis of Cyclopropanes without Heteroatom Substitution [Seite 39]
1.7.1.1.1.1.1 - 2.10.19.1.1.1 Method 1: Synthesis from Thioacetals and Thioethers [Seite 39]
1.7.1.1.1.1.2 - 2.10.19.1.1.2 Method 2: Synthesis from 1,1-Dihalides [Seite 44]
1.7.1.1.1.2 - 2.10.19.1.2 Synthesis of Cyclopropanols [Seite 45]
1.7.1.1.1.2.1 - 2.10.19.1.2.1 Synthesis from Carboxylic Acid Esters [Seite 45]
1.7.1.1.1.2.1.1 - 2.10.19.1.2.1.1 Method 1: Use of Grignard Reagents without Ligand Exchange [Seite 45]
1.7.1.1.1.2.1.2 - 2.10.19.1.2.1.2 Method 2: Use of Alkenes and Grignard Reagents [Seite 50]
1.7.1.1.1.2.1.2.1 - 2.10.19.1.2.1.2.1 Variation 1: Bicyclo[n.1.0]alkan-1-ols from Unsaturated Carboxylic Acid Esters [Seite 50]
1.7.1.1.1.2.1.2.2 - 2.10.19.1.2.1.2.2 Variation 2: 2-(Hydroxyalkyl)cyclopropanols from Unsaturated Carboxylic Acid Esters [Seite 53]
1.7.1.1.1.2.1.2.3 - 2.10.19.1.2.1.2.3 Variation 3: Cyclopropanols from Carboxylic Acid Esters and Alkenes [Seite 54]
1.7.1.1.1.2.2 - 2.10.19.1.2.2 Synthesis from Lactones and Other Acid Derivatives [Seite 57]
1.7.1.1.1.2.2.1 - 2.10.19.1.2.2.1 Method 1: Synthesis from Lactones [Seite 57]
1.7.1.1.1.2.2.2 - 2.10.19.1.2.2.2 Method 2: Synthesis from Other Acid Derivatives [Seite 58]
1.7.1.1.1.3 - 2.10.19.1.3 Synthesis of Cyclopropanone Hemiacetals [Seite 59]
1.7.1.1.1.3.1 - 2.10.19.1.3.1 Method 1: Synthesis from Cyclic Carbonates [Seite 59]
1.7.1.1.1.4 - 2.10.19.1.4 Synthesis of Cyclopropylamines [Seite 60]
1.7.1.1.1.4.1 - 2.10.19.1.4.1 Synthesis from Tertiary Amides [Seite 60]
1.7.1.1.1.4.1.1 - 2.10.19.1.4.1.1 Method 1: Use of Grignard Reagents without Ligand Exchange [Seite 61]
1.7.1.1.1.4.1.2 - 2.10.19.1.4.1.2 Method 2: Use of Organozinc Reagents without Ligand Exchange [Seite 65]
1.7.1.1.1.4.1.3 - 2.10.19.1.4.1.3 Method 3: Use of Alkenes and Grignard Reagents [Seite 65]
1.7.1.1.1.4.1.3.1 - 2.10.19.1.4.1.3.1 Variation 1: Bicyclo[n.1.0]alkan-1-amine Derivatives from Unsaturated Carboxylic Amides [Seite 66]
1.7.1.1.1.4.1.3.2 - 2.10.19.1.4.1.3.2 Variation 2: 2-Azabicyclo[n.1.0]alkane Derivatives from Unsaturated Carboxylic Amides [Seite 68]
1.7.1.1.1.4.1.3.3 - 2.10.19.1.4.1.3.3 Variation 3: Cyclopropylamines from Tertiary Amides and Alkenes [Seite 69]
1.7.1.1.1.4.2 - 2.10.19.1.4.2 Synthesis from Nitriles [Seite 72]
1.7.1.1.1.4.2.1 - 2.10.19.1.4.2.1 Method 1: Use of Grignard Reagents without Ligand Exchange [Seite 72]
1.7.1.1.1.4.2.1.1 - 2.10.19.1.4.2.1.1 Variation 1: Alkylcyclopropylamines from Aliphatic Nitriles [Seite 72]
1.7.1.1.1.4.2.1.2 - 2.10.19.1.4.2.1.2 Variation 2: 1-Aryl- and 1-Alkenylcyclopropylamines from Unsaturated Nitriles [Seite 78]
1.7.1.1.1.4.2.2 - 2.10.19.1.4.2.2 Method 2: Use of Alkenes and Grignard Reagents [Seite 80]
1.7.1.1.1.4.2.2.1 - 2.10.19.1.4.2.2.1 Variation 1: Bicyclic Cyclopropylamines from Unsaturated Nitriles [Seite 80]
1.7.1.1.1.4.2.2.2 - 2.10.19.1.4.2.2.2 Variation 2: Cyclopropylamines from Nitriles and Alkenes [Seite 81]
1.7.1.1.1.4.3 - 2.10.19.1.4.3 Synthesis from Imides [Seite 82]
1.7.1.1.1.4.3.1 - 2.10.19.1.4.3.1 Method 1: Synthesis from Formimides or Cyclic Imides [Seite 82]
1.8 - Volume 4: Compounds of Group 15 (As, Sb, Bi) and Silicon Compounds [Seite 88]
1.8.1 - 4.4 Product Class 4: Silicon Compounds [Seite 88]
1.8.1.1 - 4.4.1 Product Subclass 1: Disilenes [Seite 88]
1.8.1.1.1 - Synthesis of Product Subclass 1 [Seite 90]
1.8.1.1.1.1 - 4.4.1.1 Method 1: Synthesis of Acyclic Disilenes [Seite 90]
1.8.1.1.1.1.1 - 4.4.1.1.1 Variation 1: Photolysis of Linear Trisilanes [Seite 90]
1.8.1.1.1.1.2 - 4.4.1.1.2 Variation 2: Photolysis of Cyclotrisilanes [Seite 91]
1.8.1.1.1.1.3 - 4.4.1.1.3 Variation 3: Reductive Dehalogenation of 1,1-Dihalosilanes [Seite 91]
1.8.1.1.1.1.4 - 4.4.1.1.4 Variation 4: Reductive Dehalogenation of 1,2-Dihalodisilanes [Seite 94]
1.8.1.1.1.1.5 - 4.4.1.1.5 Variation 5: Coupling of a 1,1-Dilithiosilane with Dihalosilanes [Seite 94]
1.8.1.1.1.1.6 - 4.4.1.1.6 Variation 6: Coupling of Alkali Metal Disilenides with Electrophiles [Seite 95]
1.8.1.1.1.1.7 - 4.4.1.1.7 Variation 7: Addition to Disilynes [Seite 97]
1.8.1.1.1.1.8 - 4.4.1.1.8 Variation 8: Other Methods [Seite 97]
1.8.1.1.1.2 - 4.4.1.2 Method 2: Synthesis of Tetrasilabutadienes [Seite 99]
1.8.1.1.1.3 - 4.4.1.3 Method 3: Synthesis of Cyclic Disilenes [Seite 100]
1.9 - Volume 8: Compounds of Group 1 (Li···Cs) [Seite 106]
1.9.1 - 8.1 Product Class 1: Lithium Compounds [Seite 106]
1.9.1.1 - 8.1.31 Functionalized Organolithiums by Ring Opening of Heterocycles [Seite 106]
1.9.1.1.1 - 8.1.31.1 Three-Membered Heterocycles [Seite 107]
1.9.1.1.1.1 - 8.1.31.1.1 Method 1: Oxiranes [Seite 107]
1.9.1.1.1.2 - 8.1.31.1.2 Method 2: Aziridines [Seite 112]
1.9.1.1.2 - 8.1.31.2 Four-Membered Heterocycles [Seite 114]
1.9.1.1.2.1 - 8.1.31.2.1 Method 1: Oxetanes [Seite 114]
1.9.1.1.2.2 - 8.1.31.2.2 Method 2: Azetidines [Seite 118]
1.9.1.1.2.3 - 8.1.31.2.3 Method 3: Thietanes [Seite 119]
1.9.1.1.3 - 8.1.31.3 Five-Membered Heterocycles [Seite 119]
1.9.1.1.3.1 - 8.1.31.3.1 Method 1: Oxygen-Containing Compounds [Seite 121]
1.9.1.1.3.1.1 - 8.1.31.3.1.1 Variation 1: Tetrahydrofurans [Seite 121]
1.9.1.1.3.1.2 - 8.1.31.3.1.2 Variation 2: Dioxolanes and Oxazolidines [Seite 122]
1.9.1.1.3.1.3 - 8.1.31.3.1.3 Variation 3: Benzo[b]furans [Seite 126]
1.9.1.1.3.1.4 - 8.1.31.3.1.4 Variation 4: Phthalans [Seite 128]
1.9.1.1.3.2 - 8.1.31.3.2 Method 2: Nitrogen-Containing Compounds: Pyrrolidines [Seite 131]
1.9.1.1.3.3 - 8.1.31.3.3 Method 3: Sulfur-Containing Compounds [Seite 133]
1.9.1.1.4 - 8.1.31.4 Six-Membered Heterocycles [Seite 134]
1.9.1.1.4.1 - 8.1.31.4.1 Method 1: Oxygen-Containing Compounds [Seite 134]
1.9.1.1.4.1.1 - 8.1.31.4.1.1 Variation 1: Saturated Oxygen-Containing Heterocycles [Seite 134]
1.9.1.1.4.1.2 - 8.1.31.4.1.2 Variation 2: 1-Benzopyrans [Seite 135]
1.9.1.1.4.1.3 - 8.1.31.4.1.3 Variation 3: 2-Benzopyrans [Seite 137]
1.9.1.1.4.2 - 8.1.31.4.2 Method 2: Nitrogen-Containing Compounds: Tetrahydroisoquinolines [Seite 138]
1.9.1.1.4.3 - 8.1.31.4.3 Method 3: Sulfur-Containing Compounds [Seite 140]
1.9.1.1.5 - 8.1.31.5 Seven-Membered Heterocycles [Seite 141]
1.9.1.1.5.1 - 8.1.31.5.1 Method 1: Dibenzo Oxygen-, Nitrogen-, and Sulfur-Containing Seven-Membered Heterocycles [Seite 141]
1.9.1.1.5.2 - 8.1.31.5.2 Method 2: Dinaphtho Oxygen- and Sulfur-Containing Seven-Membered Heterocycles [Seite 143]
1.9.1.1.6 - 8.1.31.6 Other Heterocycles [Seite 144]
1.9.1.1.6.1 - 8.1.31.6.1 Method 1: Benzodioxins, Benzoxathiins, Dihydrobenzodioxepins, and Dihydronaphthodioxocins [Seite 144]
1.9.1.1.6.2 - 8.1.31.6.2 Method 2: Phenoxathiin, Phenothiazine, and Thianthrene [Seite 147]
1.9.1.2 - 8.1.32 Syntheses Mediated by a-Lithiated Epoxides and Aziridines [Seite 152]
1.9.1.2.1 - 8.1.32.1 Oxiranyllithiums [Seite 152]
1.9.1.2.1.1 - 8.1.32.1.1 2-Alkyl-Substituted Oxiranyllithiums [Seite 153]
1.9.1.2.1.1.1 - 8.1.32.1.1.1 Method 1: Reactions with Electrophiles [Seite 153]
1.9.1.2.1.1.1.1 - 8.1.32.1.1.1.1 Variation 1: Stereospecific Trapping [Seite 153]
1.9.1.2.1.1.1.2 - 8.1.32.1.1.1.2 Variation 2: Asymmetric Lithiation and Trapping of meso-Oxiranes [Seite 154]
1.9.1.2.1.1.1.3 - 8.1.32.1.1.1.3 Variation 3: Coupling with Boronic Esters: Synthesis of Polyoxygenated Compounds [Seite 155]
1.9.1.2.1.1.2 - 8.1.32.1.1.2 Method 2: Enantioselective a-Deprotonation-Rearrangement of meso-Oxiranes [Seite 156]
1.9.1.2.1.1.2.1 - 8.1.32.1.1.2.1 Variation 1: Synthesis of Bicyclic Alcohols by Transannular C--H Insertion [Seite 156]
1.9.1.2.1.1.2.2 - 8.1.32.1.1.2.2 Variation 2: Synthesis of (-)-Xialenon [Seite 157]
1.9.1.2.1.1.2.3 - 8.1.32.1.1.2.3 Variation 3: Effect of Lewis Acids on Transannular C--H Insertion Reactions [Seite 157]
1.9.1.2.1.1.2.4 - 8.1.32.1.1.2.4 Variation 4: Enantioselective Rearrangement of exo-Norbornene Oxide to Nortricyclanol [Seite 158]
1.9.1.2.1.1.2.5 - 8.1.32.1.1.2.5 Variation 5: Transannular C--H Insertion in Lithiated 7-(tert-Butoxycarbonyl)-7-azanorbornene Oxide [Seite 159]
1.9.1.2.1.1.3 - 8.1.32.1.1.3 Method 3: Construction of Nitrogen-Containing Heterocyclic Compounds by Desymmetrization of meso-Epoxides [Seite 160]
1.9.1.2.1.1.4 - 8.1.32.1.1.4 Method 4: Synthesis of Alkenes by Reductive Alkylation [Seite 161]
1.9.1.2.1.1.4.1 - 8.1.32.1.1.4.1 Variation 1: Synthesis of Enantioenriched Unsaturated Diols [Seite 162]
1.9.1.2.1.1.4.2 - 8.1.32.1.1.4.2 Variation 2: Synthesis of Enamines from Terminal Epoxides [Seite 163]
1.9.1.2.1.1.5 - 8.1.32.1.1.5 Method 5: Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides (C==C Insertion) [Seite 164]
1.9.1.2.1.1.5.1 - 8.1.32.1.1.5.1 Variation 1: Stereospecific Synthesis of Bicyclic Alcohols [Seite 164]
1.9.1.2.1.1.5.2 - 8.1.32.1.1.5.2 Variation 2: Synthesis of (-)-Sabina Ketone [Seite 165]
1.9.1.2.1.1.6 - 8.1.32.1.1.6 Method 6: Isomerization of a-Lithiated Epoxides to Ketones: 1,2-Hydrogen Migration [Seite 166]
1.9.1.2.1.2 - 8.1.32.1.2 2-Aryl-Substituted Oxiranyllithiums [Seite 167]
1.9.1.2.1.2.1 - 8.1.32.1.2.1 Method 1: Reactions of 2-Phenyloxiran-2-yllithiums [Seite 167]
1.9.1.2.1.2.1.1 - 8.1.32.1.2.1.1 Variation 1: Stereospecific Trapping with Electrophiles [Seite 167]
1.9.1.2.1.2.1.2 - 8.1.32.1.2.1.2 Variation 2: Stereoselective Synthesis of Antifungal Agents [Seite 168]
1.9.1.2.1.2.2 - 8.1.32.1.2.2 Method 2: Reactions of 3-Substituted 2-Phenyloxiran-2-yllithiums [Seite 169]
1.9.1.2.1.2.2.1 - 8.1.32.1.2.2.1 Variation 1: Of 3-Methyl-2-phenyloxiran-2-yllithiums [Seite 169]
1.9.1.2.1.2.2.2 - 8.1.32.1.2.2.2 Variation 2: Of 2-Lithiated 2,3-Diphenyloxiranes [Seite 169]
1.9.1.2.1.2.3 - 8.1.32.1.2.3 Method 3: Reactions of 2-Aryloxiran-2-yllithiums [Seite 171]
1.9.1.2.1.2.4 - 8.1.32.1.2.4 Method 4: Stereoselective Synthesis of Cyclopropanes [Seite 173]
1.9.1.2.1.2.5 - 8.1.32.1.2.5 Method 5: Stereoselective Synthesis of ß,.-Epoxyhydroxylamines and 4-(Hydroxyalkyl)-1,2-oxazetidines [Seite 174]
1.9.1.2.1.2.6 - 8.1.32.1.2.6 Method 6: Stereocontrolled Synthesis of 1,2-Diols by Homologation of Boronic Esters with Lithiated 2-Phenyloxirane [Seite 175]
1.9.1.2.1.2.7 - 8.1.32.1.2.7 Method 7: Oxiranyl Anion Methodology Using Microflow Systems [Seite 177]
1.9.1.2.1.3 - 8.1.32.1.3 Lithiated Dihydrooxazol-2-yloxiranes [Seite 178]
1.9.1.2.1.3.1 - 8.1.32.1.3.1 Method 1: Reactions of 2-Lithiated 2-(4,5-Dihydrooxazol-2-yl)oxiranes [Seite 178]
1.9.1.2.1.3.1.1 - 8.1.32.1.3.1.1 Variation 1: Configurational Stability of a-Lithiated (4,5-Dihydrooxazol-2-yl)oxiranes: Trapping with Electrophiles [Seite 178]
1.9.1.2.1.3.1.2 - 8.1.32.1.3.1.2 Variation 2: Synthesis of 2-Acyldihydrooxazoles [Seite 179]
1.9.1.2.1.3.1.3 - 8.1.32.1.3.1.3 Variation 3: Synthesis of Cyclopropane-Fused .-Lactones [Seite 180]
1.9.1.2.1.3.1.4 - 8.1.32.1.3.1.4 Variation 4: Synthesis of a-Epoxy-ß-amino Acids [Seite 181]
1.9.1.2.1.3.2 - 8.1.32.1.3.2 Method 2: Reactions of 2-Lithiated 3-(4,5-Dihydrooxazol-2-yl)oxiranes [Seite 184]
1.9.1.2.1.3.2.1 - 8.1.32.1.3.2.1 Variation 1: Configurational Stability of 2-Lithiated 3-(4,5-Dihydrooxazol-2-yl)oxiranes: Trapping with Electrophiles [Seite 184]
1.9.1.2.1.3.2.2 - 8.1.32.1.3.2.2 Variation 2: Synthesis of a,ß-Epoxy-.-butyrolactones [Seite 185]
1.9.1.2.1.3.2.3 - 8.1.32.1.3.2.3 Variation 3: Synthesis of a,ß-Epoxy-.-amino Acids and a,ß-Epoxy-.-butyrolactams [Seite 186]
1.9.1.2.1.3.3 - 8.1.32.1.3.3 Method 3: 2-Lithiation of Terminal 3-(4,5-Dihydrooxazol-2-yl)oxiranes [Seite 189]
1.9.1.2.1.4 - 8.1.32.1.4 2-Trifluoromethyl-Stabilized Oxiranyllithium [Seite 190]
1.9.1.2.1.4.1 - 8.1.32.1.4.1 Method 1: 2-(Trifluoromethyl)oxiranyllithium: Stereospecific Trapping with Electrophiles [Seite 190]
1.9.1.2.1.4.2 - 8.1.32.1.4.2 Method 2: 2-(Trifluoromethyl)oxiranyllithium as Precursor of the Oxiranylzinc [Seite 190]
1.9.1.2.1.5 - 8.1.32.1.5 Lactone-Derived Oxiranyllithiums [Seite 191]
1.9.1.2.1.5.1 - 8.1.32.1.5.1 Method 1: Reactions of Oxiranyllithiums Derived from a,ß-Epoxy-.-butyrolactones [Seite 191]
1.9.1.2.1.6 - 8.1.32.1.6 Silyloxiranyllithiums [Seite 193]
1.9.1.2.1.6.1 - 8.1.32.1.6.1 Method 1: Lithiation of 3-Vinyloxiran-2-ylsilanes [Seite 193]
1.9.1.2.1.6.2 - 8.1.32.1.6.2 Method 2: Lithiation of 3-Alkyloxiran-2-ylsilanes [Seite 194]
1.9.1.2.1.7 - 8.1.32.1.7 2-Sulfonyloxiranyllithiums [Seite 195]
1.9.1.2.1.7.1 - 8.1.32.1.7.1 Method 1: 2-Sulfonyloxiranyllithiums: Configurational Stability and Trapping with Electrophiles [Seite 195]
1.9.1.2.1.7.2 - 8.1.32.1.7.2 Method 2: Construction of Polycyclic Ethers [Seite 196]
1.9.1.2.1.8 - 8.1.32.1.8 2-Lithiated 2-(Benzotriazol-1-yl)oxiranes [Seite 198]
1.9.1.2.1.8.1 - 8.1.32.1.8.1 Method 1: Synthesis of 2-(Benzotriazol-1-yl)oxiranyllithiums with Subsequent Trapping [Seite 198]
1.9.1.2.1.9 - 8.1.32.1.9 2-Lithiated 2-(Benzothiazol-2-yl)oxiranes [Seite 198]
1.9.1.2.1.9.1 - 8.1.32.1.9.1 Method 1: Synthesis of 2-(Benzothiazol-2-yl)oxiranyllithiums with Subsequent Trapping [Seite 198]
1.9.1.2.1.10 - 8.1.32.1.10 Oxiranyllithiums by Transmetalation [Seite 200]
1.9.1.2.1.10.1 - 8.1.32.1.10.1 Method 1: Lithium-Tin Transmetalation [Seite 200]
1.9.1.2.1.10.2 - 8.1.32.1.10.2 Method 2: Lithium-Aluminum and Lithium-Zirconium Transmetalation [Seite 200]
1.9.1.2.1.10.2.1 - 8.1.32.1.10.2.1 Variation 1: Synthesis of Alkylated (Triphenylsilyl)alkenes: Reaction of a 2-Lithiated 2-(Triphenylsilyl)oxirane with Organoaluminum Reagents [Seite 200]
1.9.1.2.1.10.2.2 - 8.1.32.1.10.2.2 Variation 2: Insertion of Metalated Epoxides into Zirconacycles [Seite 201]
1.9.1.2.1.10.2.3 - 8.1.32.1.10.2.3 Variation 3: Insertion of Metalated Epoxynitriles into Chlorobis(.5-cyclopentadienyl)organozirconium Reagents [Seite 202]
1.9.1.2.1.10.2.4 - 8.1.32.1.10.2.4 Variation 4: Insertion of 2-Lithiated 2-(Phenylsulfonyl)oxiranes into Alkenylchlorobis(.5-cyclopentadienyl)zirconium Reagents [Seite 203]
1.9.1.2.1.11 - 8.1.32.1.11 Remotely Stabilized Lithiated Epoxides [Seite 205]
1.9.1.2.1.11.1 - 8.1.32.1.11.1 Method 1: Remotely Stabilized Lithiated Epoxides: Reactions with Aldehydes [Seite 205]
1.9.1.2.1.11.2 - 8.1.32.1.11.2 Method 2: Synthesis of Xylobovide [Seite 206]
1.9.1.2.2 - 8.1.32.2 a-Lithiated Aziridines [Seite 207]
1.9.1.2.2.1 - 8.1.32.2.1 Lithiation-Trapping Sequence of Aziridines with an Electron-Withdrawing Group at the Carbon Atom [Seite 208]
1.9.1.2.2.1.1 - 8.1.32.2.1.1 Method 1: Synthesis of 1-Alkylaziridine-2-carboxylates [Seite 208]
1.9.1.2.2.1.2 - 8.1.32.2.1.2 Method 2: Synthesis of 1-Alkylaziridine-2-carbothioates [Seite 209]
1.9.1.2.2.1.3 - 8.1.32.2.1.3 Method 3: Reactions of 2-(4,5-Dihydrooxazol-2-yl)-Substituted 1-Phenylaziridines [Seite 210]
1.9.1.2.2.1.4 - 8.1.32.2.1.4 Method 4: Reactions of 2,3-Dihetaryl-Substituted 1-Phenylaziridines [Seite 211]
1.9.1.2.2.1.5 - 8.1.32.2.1.5 Method 5: Reactions of 2-(4,5-Dihydrooxazol-2-yl)-Substituted 1-Tritylaziridines [Seite 213]
1.9.1.2.2.1.5.1 - 8.1.32.2.1.5.1 Variation 1: Synthesis of N-Tritylepimino-.-butyrolactones [Seite 214]
1.9.1.2.2.1.6 - 8.1.32.2.1.6 Method 6: Reactions of 2-(4,5-Dihydrooxazol-2-yl)-Substituted 1-Benzylaziridines [Seite 215]
1.9.1.2.2.1.7 - 8.1.32.2.1.7 Method 7: Reactions of 2-(4,5-Dihydrooxazol-2-yl)-Substituted 1-(1-Phenylethyl)aziridines [Seite 216]
1.9.1.2.2.1.8 - 8.1.32.2.1.8 Method 8: Synthesis of C-Substituted 1-Phenyl-2-sulfonylaziridines [Seite 218]
1.9.1.2.2.2 - 8.1.32.2.2 Lithiation of Aziridines with an Electron-Withdrawing Group at Nitrogen [Seite 219]
1.9.1.2.2.2.1 - 8.1.32.2.2.1 Method 1: C-Alkylation of 1-(tert-Butylsulfonyl)-2-phenylaziridine [Seite 219]
1.9.1.2.2.2.1.1 - 8.1.32.2.2.1.1 Variation 1: Synthesis of 2-Substituted 1-(tert-Butylsulfonyl)-2-phenylaziridines Using Microreactor Technology [Seite 220]
1.9.1.2.2.2.1.2 - 8.1.32.2.2.1.2 Variation 2: Synthesis of (tert-Butylsulfonyl)amino Alcohols [Seite 221]
1.9.1.2.2.2.2 - 8.1.32.2.2.2 Method 2: Synthesis of 2-Alkyl-Substituted 1-(tert-Butylsulfonyl)-3-(trimethylsilyl)aziridines [Seite 222]
1.9.1.2.2.2.3 - 8.1.32.2.2.3 Method 3: Synthesis of 2-Substituted 1-(tert-Butylsulfonyl)aziridines [Seite 223]
1.9.1.2.2.2.3.1 - 8.1.32.2.2.3.1 Variation 1: Synthesis of 2-Substituted 1-(tert-Butylsulfonyl)aziridines Using Microreactor Technology [Seite 224]
1.9.1.2.2.2.4 - 8.1.32.2.2.4 Method 4: Synthesis of trans-2,3-Disubstituted 1-(tert-Butylsulfonyl)aziridines [Seite 225]
1.9.1.2.2.2.5 - 8.1.32.2.2.5 Method 5: Synthesis of C-Substituted 1-(2,4,6-Triisopropylphenylsulfonyl)aziridines [Seite 226]
1.9.1.2.2.2.6 - 8.1.32.2.2.6 Method 6: Reductive Alkylation (or Alkylative Ring Opening) of 1-Sulfonylaziridinyllithiums [Seite 228]
1.9.1.2.2.2.6.1 - 8.1.32.2.2.6.1 Variation 1: Synthesis of Allylic Sulfonamides [Seite 228]
1.9.1.2.2.2.6.2 - 8.1.32.2.2.6.2 Variation 2: Synthesis of Alkynylamines [Seite 230]
1.9.1.2.2.2.6.3 - 8.1.32.2.2.6.3 Variation 3: Allylic Amino Alcohols and Amino Ethers by Organolithium-Induced Alkylative Ring Opening of 1-Sulfonyl-Protected Aziridinyl Ethers [Seite 232]
1.9.1.2.2.2.6.4 - 8.1.32.2.2.6.4 Variation 4: Allylic Amino Alcohols and Amino Ethers by Organolithium-Induced Alkylative Ring Opening of 1,4-Dimethoxybut-2-ene-Derived Aziridines [Seite 233]
1.9.1.2.2.2.7 - 8.1.32.2.2.7 Method 7: Eliminative Dimerization of Lithiated 1-(tert-Butylsulfonyl)-aziridines [Seite 234]
1.9.1.2.2.2.7.1 - 8.1.32.2.2.7.1 Variation 1: Synthesis of 2-Ene-1,4-diamines [Seite 234]
1.9.1.2.2.2.8 - 8.1.32.2.2.8 Method 8: Intramolecular Cyclopropanation of Lithiated 1-(tert-Butylsulfonyl)aziridines [Seite 235]
1.9.1.2.2.2.8.1 - 8.1.32.2.2.8.1 Variation 1: Synthesis of 2-Aminobicyclo[3.1.0]hexanes [Seite 235]
1.9.1.2.2.2.9 - 8.1.32.2.2.9 Method 9: Lithiation of 1-(tert-Butoxycarbonyl)aziridines [Seite 237]
1.9.1.2.2.2.9.1 - 8.1.32.2.2.9.1 Variation 1: Synthesis of 2-Silylaziridines [Seite 237]
1.9.1.2.2.2.9.2 - 8.1.32.2.2.9.2 Variation 2: Synthesis of trans-Configured Aziridine-2-carboxylates [Seite 237]
1.9.1.2.2.2.9.3 - 8.1.32.2.2.9.3 Variation 3: Synthesis of trans-Configured Aziridin-2-ylphosphonates [Seite 239]
1.9.1.2.2.2.9.4 - 8.1.32.2.2.9.4 Variation 4: Synthesis of N-tert-Butoxycarbonyl 1,2-Amino Alcohols [Seite 239]
1.9.1.2.2.3 - 8.1.32.2.3 Lithiation of Aziridines with an Electron-Donating Group on Nitrogen [Seite 241]
1.9.1.2.2.3.1 - 8.1.32.2.3.1 Method 1: Synthesis of cis- and trans-Configured C-Substituted 1-Alkyl-2,3-diphenylaziridines [Seite 241]
1.9.1.2.2.3.2 - 8.1.32.2.3.2 Method 2: Synthesis of C-Substituted 1-Alkyl-2-methyleneaziridines [Seite 242]
1.9.1.2.2.3.2.1 - 8.1.32.2.3.2.1 Variation 1: Synthesis of Chiral Nonracemic C-Substituted 1-Alkyl-2-methyleneaziridines [Seite 243]
1.9.1.2.2.3.3 - 8.1.32.2.3.3 Method 3: Synthesis of C-Substituted Aziridine-Borane Complexes [Seite 244]
1.9.1.2.2.3.3.1 - 8.1.32.2.3.3.1 Variation 1: Of 1-[2-(tert-Butyldimethylsiloxy)ethyl]aziridine-Borane Complexes [Seite 244]
1.9.1.2.2.3.3.2 - 8.1.32.2.3.3.2 Variation 2: Of 1-Alkyl-2-phenylaziridine-Borane Complexes [Seite 246]
1.9.1.3 - 8.1.33 Transition-Metal-Catalyzed Carbon--Carbon Bond Formation with Organolithiums [Seite 252]
1.9.1.3.1 - 8.1.33.1 Copper-Catalyzed Reactions [Seite 252]
1.9.1.3.1.1 - 8.1.33.1.1 Method 1: Copper-Catalyzed Conjugate Addition [Seite 253]
1.9.1.3.1.2 - 8.1.33.1.2 Method 2: Copper-Catalyzed Alkylation [Seite 254]
1.9.1.3.1.2.1 - 8.1.33.1.2.1 Variation 1: Copper-Catalyzed Asymmetric Allylation [Seite 254]
1.9.1.3.1.3 - 8.1.33.1.3 Method 3: Copper-Catalyzed Coupling of Organolithium Reagents with a-Lithiated Cyclic Enol Ethers [Seite 256]
1.9.1.3.2 - 8.1.33.2 Palladium-Catalyzed Reactions [Seite 256]
1.9.1.3.2.1 - 8.1.33.2.1 Method 1: Palladium-Catalyzed Cross-Coupling Reactions with Aryl and Vinyl Halides [Seite 257]
1.9.1.3.2.2 - 8.1.33.2.2 Method 2: Palladium-Catalyzed Coupling Reaction of Aryllithium Reagents with 1-Bromo-2-methylbut-3-en-2-ol [Seite 258]
1.9.1.3.3 - 8.1.33.3 Iron-Catalyzed Reactions [Seite 259]
1.9.1.3.3.1 - 8.1.33.3.1 Method 1: Iron-Catalyzed Cross-Coupling Reactions [Seite 259]
1.9.1.3.3.2 - 8.1.33.3.2 Method 2: Iron-Catalyzed Carbolithiation of Alkynes [Seite 260]
1.10 - Volume 16: Six-Membered Hetarenes with Two Identical Heteroatoms [Seite 264]
1.10.1 - 16.2 Product Class 2: 1,4-Dioxins and Benzo- and Dibenzo-Fused Derivatives [Seite 264]
1.10.1.1 - 16.2.4 1,4-Dioxins and Benzo- and Dibenzo-Fused Derivatives [Seite 264]
1.10.1.1.1 - 16.2.4.1 Synthesis by Ring-Closure Reactions [Seite 264]
1.10.1.1.1.1 - 16.2.4.1.1 By Formation of Two O--C Bonds [Seite 264]
1.10.1.1.1.1.1 - 16.2.4.1.1.1 Fragments O--C--C--O and C--C [Seite 264]
1.10.1.1.1.1.1.1 - 16.2.4.1.1.1.1 Method 1: Dibenzo[b,e][1,4]dioxins by Base-Induced Coupling of Benzene-1,2-diols with Activated Fluorobenzenes [Seite 264]
1.10.1.1.1.1.2 - 16.2.4.1.1.2 Fragments O--C--C and O--C--C [Seite 266]
1.10.1.1.1.1.2.1 - 16.2.4.1.1.2.1 Method 1: Substituted 1,4-Dioxins by Reaction of Methyl 3-Chloro-2-oxo-3-phenylpropanoate with Potassium Phthalimide or Sodium Imidazolide [Seite 266]
1.10.1.1.1.2 - 16.2.4.1.2 By Formation of One C--C Bond [Seite 267]
1.10.1.1.1.2.1 - 16.2.4.1.2.1 Fragment C--O--C--C--O--C [Seite 267]
1.10.1.1.1.2.1.1 - 16.2.4.1.2.1.1 Method 1: 1,4-Benzodioxins by Ring-Closing Metathesis of Divinyl Ethers [Seite 267]
1.10.1.1.2 - 16.2.4.2 Aromatization [Seite 268]
1.10.1.1.2.1 - 16.2.4.2.1 Method 1: 1,4-Benzodioxins by Isomerization of Exocyclic Alkenes [Seite 268]
1.10.1.1.2.2 - 16.2.4.2.2 Method 2: Dibenzo[b,e][1,4]dioxins from the Diels-Alder Reactions of 1,4-Benzodioxin and Benzo[b]furo[3,4-e][1,4]dioxins [Seite 269]
1.10.1.1.3 - 16.2.4.3 Synthesis by Substituent Modification [Seite 272]
1.10.1.1.3.1 - 16.2.4.3.1 Substitution of Existing Substituents [Seite 272]
1.10.1.1.3.1.1 - 16.2.4.3.1.1 Of Hydrogen [Seite 272]
1.10.1.1.3.1.1.1 - 16.2.4.3.1.1.1 Method 1: Vilsmeier Reaction of 2-Phenyl-1,4-benzodioxin [Seite 272]
1.10.1.1.3.1.1.2 - 16.2.4.3.1.1.2 Method 2: Diels-Alder Reaction of 2,2'-Bi-1,4-benzodioxin [Seite 272]
1.10.1.1.3.1.2 - 16.2.4.3.1.2 Of Metals [Seite 273]
1.10.1.1.3.1.2.1 - 16.2.4.3.1.2.1 Method 1: Stille Coupling of 2-(Trimethylstannyl)-1,4-benzodioxin with a Bromoalkene [Seite 273]
1.10.1.1.3.1.3 - 16.2.4.3.1.3 Of Halogens [Seite 275]
1.10.1.1.3.1.3.1 - 16.2.4.3.1.3.1 Method 1: Alkylation of 2-Bromo-1,4-benzodioxin by Lithium-Halogen Exchange [Seite 275]
1.10.1.1.3.2 - 16.2.4.3.2 Modification of Substituents [Seite 275]
1.10.1.1.3.2.1 - 16.2.4.3.2.1 Method 1: Alkylation of 1,4-Benzodioxin-6,7-dicarbaldehyde [Seite 275]
1.10.2 - 16.3 Product Class 3: 1,2-Dithiins [Seite 278]
1.10.2.1 - 16.3.5 1,2-Dithiins [Seite 278]
1.10.2.1.1 - 16.3.5.1 Synthesis by Ring-Closure Reactions [Seite 281]
1.10.2.1.1.1 - 16.3.5.1.1 By Formation of One S--S and Two S--C Bonds [Seite 281]
1.10.2.1.1.1.1 - 16.3.5.1.1.1 Fragment C--C--C--C and Two S Fragments [Seite 281]
1.10.2.1.1.1.1.1 - 16.3.5.1.1.1.1 Method 1: Addition of Sulfur to 6-Nitroperylo[1,12-bcd]thiophene [Seite 281]
1.10.2.1.1.1.1.2 - 16.3.5.1.1.1.2 Method 2: Addition of Sulfur to 2-(Trimethylsiloxy)buta-1,3-diene [Seite 281]
1.10.2.1.1.2 - 16.3.5.1.2 By Formation of One S--S and One S--C Bond [Seite 282]
1.10.2.1.1.2.1 - 16.3.5.1.2.1 Fragments S--C--C--C--C and S [Seite 282]
1.10.2.1.1.2.1.1 - 16.3.5.1.2.1.1 Method 1: Reaction of 2-(2-Phenylvinyl)-3-vinylthiirane Promoted by Acetonitrile(pentacarbonyl)tungsten(0) [Seite 282]
1.10.2.1.1.3 - 16.3.5.1.3 By Formation of One S--S and One C--C Bond [Seite 282]
1.10.2.1.1.3.1 - 16.3.5.1.3.1 Fragments S--C--C--C and S--C [Seite 282]
1.10.2.1.1.3.1.1 - 16.3.5.1.3.1.1 Method 1: Thermal Dimerization of a,ß-Unsaturated ß-Arylsulfanyl Thioketones [Seite 282]
1.10.2.1.1.3.1.2 - 16.3.5.1.3.1.2 Method 2: Cobalt(II)-Mediated Dimerization of a,ß-Unsaturated Thioacylsilanes [Seite 283]
1.10.2.1.1.3.1.3 - 16.3.5.1.3.1.3 Method 3: Dimerization via Diels-Alder Reaction of Thioaldehydes [Seite 283]
1.10.2.1.1.3.2 - 16.3.5.1.3.2 Fragments S--C--C and S--C--C [Seite 284]
1.10.2.1.1.3.2.1 - 16.3.5.1.3.2.1 Method 1: Thionation-Dimerization of 1,3-Dihydro-2H-indol-2-one [Seite 284]
1.10.2.1.1.3.2.2 - 16.3.5.1.3.2.2 Method 2: Manganese(IV) Oxide Promoted Oxidative Dimerization [Seite 285]
1.10.2.1.1.4 - 16.3.5.1.4 By Formation of One S--S Bond [Seite 285]
1.10.2.1.1.4.1 - 16.3.5.1.4.1 Fragment S--C--C--C--C--S [Seite 285]
1.10.2.1.1.4.1.1 - 16.3.5.1.4.1.1 Method 1: Polycyclization of Diynes [Seite 285]
1.10.2.1.1.4.1.2 - 16.3.5.1.4.1.2 Method 2: N-Bromosuccinimide-Induced Ring Formation [Seite 286]
1.10.2.1.1.4.1.3 - 16.3.5.1.4.1.3 Method 3: Cyclization of Dibromides Promoted by Phase-Transfer Catalysts [Seite 287]
1.10.2.1.1.4.1.4 - 16.3.5.1.4.1.4 Method 4: Cyclization of Dichlorides by Tandem Michael-Nucleophilic Substitution Processes [Seite 288]
1.10.2.1.1.5 - 16.3.5.1.5 By Formation of One C--C Bond [Seite 289]
1.10.2.1.1.5.1 - 16.3.5.1.5.1 Fragment C--C--S--S--C--C [Seite 289]
1.10.2.1.1.5.1.1 - 16.3.5.1.5.1.1 Method 1: Cyclization via Ring-Closing Metathesis of Alkenes [Seite 289]
1.10.2.1.2 - 16.3.5.2 Synthesis by Ring Transformation [Seite 289]
1.10.2.1.2.1 - 16.3.5.2.1 Method 1: Ring Contraction Promoted by Photolysis [Seite 289]
1.10.2.1.3 - 16.3.5.3 Synthesis by Other Methods [Seite 290]
1.10.2.1.3.1 - 16.3.5.3.1 Method 1: Rearrangement Promoted by Photolysis [Seite 290]
1.10.2.1.4 - 16.3.5.4 Applications of 1,2-Dithiins in Organic Synthesis [Seite 290]
1.10.2.1.4.1 - 16.3.5.4.1 Reaction with Transition Metals [Seite 291]
1.10.2.1.4.1.1 - 16.3.5.4.1.1 Method 1: Reaction with Organometallic Complexes [Seite 291]
1.10.2.1.4.1.2 - 16.3.5.4.1.2 Method 2: Reaction with Copper Metal [Seite 292]
1.10.2.1.4.2 - 16.3.5.4.2 Reaction with Lewis Acids [Seite 292]
1.10.2.1.4.2.1 - 16.3.5.4.2.1 Method 1: Reaction Promoted by Aluminum Trichloride [Seite 292]
1.10.2.1.4.2.2 - 16.3.5.4.2.2 Method 2: Reaction Promoted by Boron Trifluoride [Seite 293]
1.10.2.1.4.3 - 16.3.5.4.3 Reaction with Diazo Compounds [Seite 294]
1.10.2.1.4.3.1 - 16.3.5.4.3.1 Method 1: Reaction Promoted by Rhodium(II) Acetate [Seite 294]
1.10.2.1.4.3.2 - 16.3.5.4.3.2 Method 2: Reaction Promoted by Copper(I) Chloride [Seite 295]
1.10.2.1.4.4 - 16.3.5.4.4 Reaction with Alkynes [Seite 296]
1.10.2.1.4.4.1 - 16.3.5.4.4.1 Method 1: Reaction Promoted by Bis(acetylacetonato)nickel(II) [Seite 296]
1.10.2.1.4.5 - 16.3.5.4.5 Reaction with Enzymes [Seite 297]
1.10.2.1.4.5.1 - 16.3.5.4.5.1 Method 1: Reaction with a Toluene Dioxygenase [Seite 297]
1.11 - Volume 17: Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles [Seite 300]
1.11.1 - 17.4 Product Class 4: Seven-Membered Hetarenes with One Heteroatom [Seite 300]
1.11.1.1 - 17.4.1.5 Oxepins [Seite 300]
1.11.1.1.1 - 17.4.1.5.1 Synthesis by Ring-Closure Reactions [Seite 300]
1.11.1.1.1.1 - 17.4.1.5.1.1 By Formation of One O--C and One C--C Bond [Seite 300]
1.11.1.1.1.1.1 - 17.4.1.5.1.1.1 Method 1: From a 3-(Dimethylamino)-1-phenylprop-2-en-1-one and Arylidenemalononitriles [Seite 300]
1.11.1.1.2 - 17.4.1.5.2 Synthesis by Ring Transformation [Seite 300]
1.11.1.1.2.1 - 17.4.1.5.2.1 Method 1: By Valence Isomerization of 3-Oxaquadricyclanes [Seite 300]
1.11.1.1.2.2 - 17.4.1.5.2.2 Method 2: By Valence Isomerization of 7-Oxanorbornadienes [Seite 301]
1.11.1.1.2.3 - 17.4.1.5.2.3 Method 3: By Ring Enlargement of Furans with Diethyl Acetylenedicarboxylate [Seite 302]
1.11.1.1.2.4 - 17.4.1.5.2.4 Method 4: By Valence Isomerization of Benzene Oxide [Seite 302]
1.11.1.1.2.5 - 17.4.1.5.2.5 Method 5: By Ring Enlargement of a 2-[(Prop-2-ynyloxy)methyl]furan [Seite 303]
1.11.1.1.2.6 - 17.4.1.5.2.6 Method 6: By Ring Enlargement of a Cyclohexa-2,5-diene-1,4-diol via SN2' Reaction [Seite 304]
1.11.1.1.3 - 17.4.1.5.3 Aromatization [Seite 304]
1.11.1.1.3.1 - 17.4.1.5.3.1 Method 1: By Dehydrogenation [Seite 304]
1.11.1.2 - 17.4.2.5 Benzoxepins [Seite 308]
1.11.1.2.1 - 17.4.2.5.1 Synthesis by Ring-Closure Reactions [Seite 308]
1.11.1.2.1.1 - 17.4.2.5.1.1 By Formation of One O--C and Two C--C Bonds [Seite 308]
1.11.1.2.1.1.1 - 17.4.2.5.1.1.1 Method 1: From a Betaine and Diethyl Acetylenedicarboxylate [Seite 308]
1.11.1.2.1.2 - 17.4.2.5.1.2 By Formation of One O--C and One C--C Bond [Seite 308]
1.11.1.2.1.2.1 - 17.4.2.5.1.2.1 Method 1: From Dinitrotoluenes and Salicylaldehydes [Seite 308]
1.11.1.2.1.3 - 17.4.2.5.1.3 By Formation of Two C--C Bonds [Seite 310]
1.11.1.2.1.3.1 - 17.4.2.5.1.3.1 Method 1: By Annulation of a Boronic Acid with Dimethyl Acetylenedicarboxylate [Seite 310]
1.11.1.2.1.4 - 17.4.2.5.1.4 By Formation of One O--C Bond [Seite 311]
1.11.1.2.1.4.1 - 17.4.2.5.1.4.1 Method 1: From 2-Alkyl-3-[2-(iodoethynyl)phenyl]oxiranes [Seite 311]
1.11.1.2.1.4.2 - 17.4.2.5.1.4.2 Method 2: By Cyclization of 2-[2-(2-Bromophenyl)vinyl]phenols and Related Compounds [Seite 312]
1.11.1.2.1.5 - 17.4.2.5.1.5 By Formation of One C--C Bond [Seite 314]
1.11.1.2.1.5.1 - 17.4.2.5.1.5.1 Method 1: By Base-Catalyzed Cyclocondensation of Methyl (2E)-4-(2-Formylphenoxy)but-2-enoate [Seite 314]
1.11.1.2.2 - 17.4.2.5.2 Synthesis by Ring Transformation [Seite 315]
1.11.1.2.2.1 - 17.4.2.5.2.1 By Ring Enlargement [Seite 315]
1.11.1.2.2.1.1 - 17.4.2.5.2.1.1 Method 1: Of a Benzofuran with 1-Phenyl-2-tosylacetylene [Seite 315]
1.11.1.2.2.1.2 - 17.4.2.5.2.1.2 Method 2: Of Xanthenes by Dehydration [Seite 315]
1.11.1.2.2.1.3 - 17.4.2.5.2.1.3 Method 3: Of 2-Diazo-3',6'-bis(diethylamino)spiro[indene-1,9'-xanthen]-3(2H)-one (Rhodamine BBN) [Seite 317]
1.11.1.2.2.1.4 - 17.4.2.5.2.1.4 Method 4: Of a Dihydrofuran by Rearrangement [Seite 318]
1.11.1.2.2.1.5 - 17.4.2.5.2.1.5 Method 5: Of Tetrahydrobenzo[b]cyclopropa[e]pyran-1-carboxylates [Seite 319]
1.11.1.2.3 - 17.4.2.5.3 Synthesis by Substituent Modification [Seite 320]
1.11.1.2.3.1 - 17.4.2.5.3.1 Substitution of Existing Substituents [Seite 320]
1.11.1.2.3.1.1 - 17.4.2.5.3.1.1 Method 1: Condensation of Dibenz[b,f]oxepin-10(11H)-one with 3-Methylbut-2-enal [Seite 320]
1.11.1.2.3.1.2 - 17.4.2.5.3.1.2 Method 2: Vilsmeier-Type Chloroformylation of Dibenz[b,f]oxepin-10(11H)-ones [Seite 320]
1.11.1.2.3.1.3 - 17.4.2.5.3.1.3 Method 3: Reaction of Dibenz[b,f]oxepin-10(11H)-one with Base and Carbon Disulfide/Iodomethane or Dimethyl Trithiocarbonate [Seite 321]
1.11.1.2.3.1.4 - 17.4.2.5.3.1.4 Method 4: 1H-Dibenz[2,3:6,7]oxepino[4,5-b]pyrroles by Annulation of 11-(Hydrazonoethylidene)dibenz[b,f]oxepin-10-ones [Seite 327]
1.11.1.2.3.1.5 - 17.4.2.5.3.1.5 Method 5: 1H-Dibenz[2,3:6,7]oxepino[4,5-d]imidazoles by Oxidation/Annulation of Dibenz[b,f]oxepin-10(11H)-ones [Seite 328]
1.11.1.3 - 17.4.5.5 Azepines, Cyclopentazepines, and Phosphorus Analogues [Seite 332]
1.11.1.3.1 - 17.4.5.5.1 Synthesis by Ring-Closure Reactions [Seite 332]
1.11.1.3.1.1 - 17.4.5.5.1.1 By Formation of One C--C Bond [Seite 332]
1.11.1.3.1.1.1 - 17.4.5.5.1.1.1 Method 1: Azepine Formation via Copper-Mediated Cyclization of 2-Azahepta-2,4-dien-6-ynyl Anions [Seite 332]
1.11.1.3.1.1.2 - 17.4.5.5.1.1.2 Method 2: 3H-Azepines via Deprotonation of 2-Aza-1,3,5-trienes [Seite 333]
1.11.1.3.2 - 17.4.5.5.2 Synthesis by Ring Transformation [Seite 334]
1.11.1.3.2.1 - 17.4.5.5.2.1 By Ring Enlargement [Seite 334]
1.11.1.3.2.1.1 - 17.4.5.5.2.1.1 Of Five-Membered Heterocycles [Seite 334]
1.11.1.3.2.1.1.1 - 17.4.5.5.2.1.1.1 Method 1: Thermal Isomerization of 3-Azaquadricyclanes [Seite 334]
1.11.1.3.2.1.1.1.1 - 17.4.5.5.2.1.1.1.1 Variation 1: Thermal Isomerization of a Cyclobutane 3-Azaquadricyclane [Seite 334]
1.11.1.3.2.1.2 - 17.4.5.5.2.1.2 Of Six-Membered Arenes [Seite 335]
1.11.1.3.2.1.2.1 - 17.4.5.5.2.1.2.1 Method 1: Intramolecular Insertion of Arylnitrenes [Seite 335]
1.11.1.3.2.1.2.1.1 - 17.4.5.5.2.1.2.1.1 Variation 1: Photolytic Decomposition of Aryl Azides [Seite 335]
1.11.1.3.2.1.2.1.2 - 17.4.5.5.2.1.2.1.2 Variation 2: Rearrangement of Nitroarenes [Seite 337]
1.11.1.3.3 - 17.4.5.5.3 Synthesis by Substituent Modification [Seite 338]
1.11.1.3.3.1 - 17.4.5.5.3.1 Substitution of Existing Substituents [Seite 338]
1.11.1.3.3.1.1 - 17.4.5.5.3.1.1 Of Hydrogen [Seite 338]
1.11.1.3.3.1.1.1 - 17.4.5.5.3.1.1.1 Method 1: Tautomerization [Seite 338]
1.11.1.3.3.1.1.1.1 - 17.4.5.5.3.1.1.1.1 Variation 1: Rearrangement of 2H- to 3H-Azepines [Seite 338]
1.11.1.3.3.1.1.2 - 17.4.5.5.3.1.1.2 Method 2: C-Halogenation [Seite 339]
1.11.1.3.3.1.1.2.1 - 17.4.5.5.3.1.1.2.1 Variation 1: C-Halogenation with N-Bromosuccinimide [Seite 339]
1.11.1.3.3.1.1.3 - 17.4.5.5.3.1.1.3 Method 3: C-Alkylsulfanylation [Seite 339]
1.11.1.3.3.1.1.4 - 17.4.5.5.3.1.1.4 Method 4: C-Amination [Seite 340]
1.11.1.3.3.1.1.5 - 17.4.5.5.3.1.1.5 Method 5: C-Alkoxylation [Seite 341]
1.11.1.3.3.1.2 - 17.4.5.5.3.1.2 Of Heteroatoms [Seite 342]
1.11.1.3.3.1.2.1 - 17.4.5.5.3.1.2.1 Method 1: Of Alkoxy Groups [Seite 342]
1.11.1.3.3.1.2.1.1 - 17.4.5.5.3.1.2.1.1 Variation 1: Of Activated Organooxy Groups [Seite 344]
1.11.1.4 - 17.4.6.10 Benzazepines and Their Group 15 Analogues [Seite 348]
1.11.1.4.1 - 17.4.6.10.1 1H-1-Benzazepines [Seite 349]
1.11.1.4.1.1 - 17.4.6.10.1.1 Synthesis by Ring-Closure Reactions [Seite 349]
1.11.1.4.1.1.1 - 17.4.6.10.1.1.1 By Formation of Two C--C Bonds and One C--N Bond [Seite 349]
1.11.1.4.1.1.1.1 - 17.4.6.10.1.1.1.1 Method 1: By Condensation between 2-Fluoroaniline and Aryl Methyl Ketones [Seite 349]
1.11.1.4.1.1.2 - 17.4.6.10.1.1.2 By Formation of One N--C and One C--C Bond [Seite 349]
1.11.1.4.1.1.2.1 - 17.4.6.10.1.1.2.1 Method 1: From 5-[(E)-(2-Dimethylamino)vinyl]-2,1,3-benzoselenadiazol-4-amine [Seite 349]
1.11.1.4.1.1.3 - 17.4.6.10.1.1.3 By Formation of Two C--C Bonds [Seite 350]
1.11.1.4.1.1.3.1 - 17.4.6.10.1.1.3.1 Method 1: By Thermal Cycloaddition of Dimethyl Acetylenedicarboxylate with Methylindoles [Seite 350]
1.11.1.4.1.1.3.2 - 17.4.6.10.1.1.3.2 Method 2: From the Reaction of Phosphonium Ylides [Seite 351]
1.11.1.4.1.1.4 - 17.4.6.10.1.1.4 By Formation of One C--N Bond [Seite 353]
1.11.1.4.1.1.4.1 - 17.4.6.10.1.1.4.1 Method 1: By Intramolecular Addition of Anilines [Seite 353]
1.11.1.4.1.2 - 17.4.6.10.1.2 Synthesis by Ring Transformation [Seite 355]
1.11.1.4.1.2.1 - 17.4.6.10.1.2.1 By Ring Enlargement [Seite 355]
1.11.1.4.1.2.1.1 - 17.4.6.10.1.2.1.1 Method 1: By Ring Expansion of Activated Quinolines [Seite 355]
1.11.1.4.2 - 17.4.6.10.2 2-Benzazepines [Seite 356]
1.11.1.4.2.1 - 17.4.6.10.2.1 Synthesis by Ring-Closure Reactions [Seite 356]
1.11.1.4.2.1.1 - 17.4.6.10.2.1.1 By Formation of One N--C and One C--C Bond [Seite 356]
1.11.1.4.2.1.1.1 - 17.4.6.10.2.1.1.1 Method 1: By a Tandem Ritter/Houben-Hoesch Process [Seite 356]
1.11.1.4.2.1.1.2 - 17.4.6.10.2.1.1.2 Method 2: By Reaction of 4-Chloro-2-oxo-2H-1-benzopyran-3-carbaldehyde with Benzylamines [Seite 357]
1.11.1.4.2.1.2 - 17.4.6.10.2.1.2 By Formation of One C--C Bond [Seite 359]
1.11.1.4.2.1.2.1 - 17.4.6.10.2.1.2.1 Method 1: By Cyclization of 2-Azahepta-2,4-dien-6-ynyls [Seite 359]
1.11.1.4.3 - 17.4.6.10.3 5H-Dibenz[b,d]azepines [Seite 360]
1.11.1.4.3.1 - 17.4.6.10.3.1 Synthesis by Substituent Modification [Seite 360]
1.11.1.4.3.1.1 - 17.4.6.10.3.1.1 Method 1: By Rhodium-Catalyzed Decarbonylative Cycloaddition [Seite 360]
1.11.1.4.4 - 17.4.6.10.4 11H-Dibenz[b,e]azepines [Seite 361]
1.11.1.4.4.1 - 17.4.6.10.4.1 Synthesis by Ring-Closure Reactions [Seite 361]
1.11.1.4.4.1.1 - 17.4.6.10.4.1.1 By Formation of One N--C and One C--C Bond [Seite 361]
1.11.1.4.4.1.1.1 - 17.4.6.10.4.1.1.1 Method 1: By Condensation of 2,6-Dimethylaniline with Phenanthrene-9,10-dione [Seite 361]
1.11.1.4.4.1.2 - 17.4.6.10.4.1.2 By Formation of One C--C Bond [Seite 361]
1.11.1.4.4.1.2.1 - 17.4.6.10.4.1.2.1 Method 1: By Bischler-Napieralski Cyclodehydration of N-(2-Benzylphenyl)-2-chloroacetamide [Seite 361]
1.11.1.4.4.1.2.2 - 17.4.6.10.4.1.2.2 Method 2: By Friedel-Crafts Cyclization of 2-Allyl-N-benzylanilines [Seite 362]
1.11.1.4.4.1.2.3 - 17.4.6.10.4.1.2.3 Method 3: By Acid-Mediated Cyclization of Benzylic Alcohols [Seite 363]
1.11.1.4.5 - 17.4.6.10.5 5H-Dibenz[c,e]azepines [Seite 365]
1.11.1.4.5.1 - 17.4.6.10.5.1 Synthesis by Ring-Closure Reactions [Seite 365]
1.11.1.4.5.1.1 - 17.4.6.10.5.1.1 By Formation of Two N--C Bonds [Seite 365]
1.11.1.4.5.1.1.1 - 17.4.6.10.5.1.1.1 Method 1: Ring Closure of 2,2'-Difunctionalized Biaryls with Chiral Amines under Acidic Conditions [Seite 365]
1.11.1.4.6 - 17.4.6.10.6 5H-Dibenz[b,f]azepines [Seite 370]
1.11.1.4.6.1 - 17.4.6.10.6.1 Synthesis by Ring-Closure Reactions [Seite 370]
1.11.1.4.6.1.1 - 17.4.6.10.6.1.1 By Formation of One C--C and One C--N Bond [Seite 370]
1.11.1.4.6.1.1.1 - 17.4.6.10.6.1.1.1 Method 1: By a Palladium-Catalyzed Tandem Process [Seite 370]
1.11.1.4.6.1.2 - 17.4.6.10.6.1.2 By Formation of One C--C Bond [Seite 371]
1.11.1.4.6.1.2.1 - 17.4.6.10.6.1.2.1 Method 1: By Palladium-Catalyzed Intramolecular Amination [Seite 371]
1.11.1.4.6.1.2.2 - 17.4.6.10.6.1.2.2 Method 2: Friedel-Crafts Acylation [Seite 372]
1.11.1.4.6.2 - 17.4.6.10.6.2 Synthesis by Ring Transformation [Seite 373]
1.11.1.4.6.2.1 - 17.4.6.10.6.2.1 By Ring Enlargement [Seite 373]
1.11.1.4.6.2.1.1 - 17.4.6.10.6.2.1.1 Method 1: From 1-Arylindoles [Seite 373]
1.11.1.4.6.2.1.1.1 - 17.4.6.10.6.2.1.1.1 Variation 1: Ring Expansion of 6-Methoxy-1-phenylindole [Seite 373]
1.11.1.4.6.3 - 17.4.6.10.6.3 Aromatization [Seite 373]
1.11.1.4.6.3.1 - 17.4.6.10.6.3.1 Method 1: Bromination-Dehydrobromination [Seite 373]
1.11.1.4.6.3.1.1 - 17.4.6.10.6.3.1.1 Variation 1: Dehalogenation of 5-Acetyl-10,11-dibromo-10,11-dihydro-5H-dibenz[b,f]azepine with 1,2-Diphenylethane-1,2-diyldisodium [Seite 373]
1.11.1.4.6.4 - 17.4.6.10.6.4 Synthesis by Substituent Modification [Seite 374]
1.11.1.4.6.4.1 - 17.4.6.10.6.4.1 Substitution of Hydrogen [Seite 374]
1.11.1.4.6.4.1.1 - 17.4.6.10.6.4.1.1 Method 1: N-Alkylation of 5H-Dibenz[b,f]azepines [Seite 374]
1.11.1.4.6.4.1.1.1 - 17.4.6.10.6.4.1.1.1 Variation 1: By Phase-Transfer Catalysis [Seite 375]
1.11.1.4.6.4.1.2 - 17.4.6.10.6.4.1.2 Method 2: N-Acylation of 5H-Dibenz[b,f]azepines [Seite 376]
1.11.1.4.6.4.1.2.1 - 17.4.6.10.6.4.1.2.1 Variation 1: By Reaction with Acid Chlorides [Seite 376]
1.11.1.4.6.4.1.2.2 - 17.4.6.10.6.4.1.2.2 Variation 2: By Reaction with Dimethyl Carbonate [Seite 377]
1.11.1.4.6.4.1.2.3 - 17.4.6.10.6.4.1.2.3 Variation 3: By Palladium-Mediated Carbonylative Benzoylation of 5H-Dibenz[b,f]azepine [Seite 377]
1.11.1.4.6.4.1.2.4 - 17.4.6.10.6.4.1.2.4 Variation 4: By Reaction with Trifluoroacetic Anhydride [Seite 378]
1.11.1.4.6.4.1.2.5 - 17.4.6.10.6.4.1.2.5 Variation 5: N-Formylation of 5H-Dibenz[b,f]azepine [Seite 378]
1.11.1.4.6.4.1.3 - 17.4.6.10.6.4.1.3 Method 3: Chlorocarbonylation of 5H-Dibenz[b,f]azepines with Phosgene Equivalents [Seite 379]
1.11.1.4.6.4.1.3.1 - 17.4.6.10.6.4.1.3.1 Variation 1: N-Acylation of 5H-Dibenz[b,f]azepines Followed by Amination [Seite 379]
1.11.1.4.6.4.1.4 - 17.4.6.10.6.4.1.4 Method 4: Formation of N--P Bonds [Seite 379]
1.11.1.4.6.4.1.5 - 17.4.6.10.6.4.1.5 Method 5: By a Methoxy Group [Seite 381]
1.11.1.4.6.4.1.6 - 17.4.6.10.6.4.1.6 Method 6: Palladium-Catalyzed N-Arylation [Seite 382]
1.11.1.4.6.4.2 - 17.4.6.10.6.4.2 Substitution of Heteroatoms [Seite 383]
1.11.1.4.6.4.2.1 - 17.4.6.10.6.4.2.1 Method 1: Substitution of Bromine [Seite 383]
1.11.1.4.6.4.3 - 17.4.6.10.6.4.3 Addition Reactions [Seite 384]
1.11.1.4.6.4.3.1 - 17.4.6.10.6.4.3.1 Method 1: Formation of Epoxides by Oxidation [Seite 384]
1.11.1.4.6.4.3.2 - 17.4.6.10.6.4.3.2 Method 2: Formation of Diols by Oxidation [Seite 384]
1.11.1.4.6.4.3.3 - 17.4.6.10.6.4.3.3 Method 3: [2 + 2] Photodimerization of 5-Acetyl-5H-dibenz[b,f]azepine [Seite 385]
1.11.1.4.6.4.3.3.1 - 17.4.6.10.6.4.3.3.1 Variation 1: [2 + 2] Photodimerization of 5H-Dibenz[b,f]azepine Derivatives [Seite 385]
1.11.1.4.7 - 17.4.6.10.7 9H-Tribenz[b,d,f]azepines [Seite 386]
1.11.1.4.7.1 - 17.4.6.10.7.1 Synthesis by Ring-Closure Reactions [Seite 386]
1.11.1.4.7.1.1 - 17.4.6.10.7.1.1 By Formation of One N--C Bond [Seite 386]
1.11.1.4.7.1.1.1 - 17.4.6.10.7.1.1.1 Method 1: From N-(2-Bromophenyl)biphenyl-2-amine [Seite 386]
1.11.1.4.8 - 17.4.6.10.8 Other Group 15 Benzoheterepins [Seite 387]
1.11.1.4.8.1 - 17.4.6.10.8.1 3-Benzoheterepins [Seite 387]
1.11.1.4.8.1.1 - 17.4.6.10.8.1.1 Synthesis by Ring-Closure Reactions [Seite 387]
1.11.1.4.8.1.1.1 - 17.4.6.10.8.1.1.1 By Formation of Two Heteroatom--Carbon Bonds [Seite 387]
1.11.1.4.8.1.1.1.1 - 17.4.6.10.8.1.1.1.1 Method 1: Potassium Hydroxide Catalyzed Addition of Metal Complexed Phosphines to 1,2-Diethynylbenzene [Seite 387]
1.11.1.4.8.1.1.1.2 - 17.4.6.10.8.1.1.1.2 Method 2: From 1,2-Bis[(Z)-2-bromovinyl]benzenes and Metal Halides [Seite 388]
1.12 - Volume 19: Three Carbon--Heteroatom Bonds: Nitriles, Isocyanides, and Derivatives [Seite 392]
1.12.1 - 19.5 Product Class 5: Nitriles [Seite 392]
1.12.1.1 - 19.5.17 Synthesis of Nitriles Using Cross-Coupling Reactions [Seite 392]
1.12.1.1.1 - 19.5.17.1 Preparation of Aryl Cyanides [Seite 392]
1.12.1.1.1.1 - 19.5.17.1.1 Method 1: Use of Alkali Metal Cyanides [Seite 392]
1.12.1.1.1.1.1 - 19.5.17.1.1.1 Variation 1: Palladium-Catalyzed Approaches [Seite 393]
1.12.1.1.1.1.2 - 19.5.17.1.1.2 Variation 2: Copper-Catalyzed Approaches [Seite 395]
1.12.1.1.1.1.3 - 19.5.17.1.1.3 Variation 3: Dual Palladium- and Copper-Catalyzed Approaches [Seite 396]
1.12.1.1.1.1.4 - 19.5.17.1.1.4 Variation 4: Nickel-Catalyzed Approaches [Seite 397]
1.12.1.1.1.2 - 19.5.17.1.2 Method 2: Use of Zinc(II) Cyanide [Seite 398]
1.12.1.1.1.2.1 - 19.5.17.1.2.1 Variation 1: Palladium-Catalyzed Approaches: Homogeneous Catalysis [Seite 398]
1.12.1.1.1.2.2 - 19.5.17.1.2.2 Variation 2: Palladium-Catalyzed Approaches: Heterogeneous Catalysis [Seite 406]
1.12.1.1.1.2.3 - 19.5.17.1.2.3 Variation 3: Copper-Mediated Approaches [Seite 408]
1.12.1.1.1.3 - 19.5.17.1.3 Method 3: Use of Nickel(II) Cyanide as the Cyanide Source [Seite 409]
1.12.1.1.1.4 - 19.5.17.1.4 Method 4: Use of Copper(I) Cyanide as the Cyanide Source [Seite 410]
1.12.1.1.1.5 - 19.5.17.1.5 Method 5: Use of Potassium Hexacyanoferrate(II) as the Cyanide Source [Seite 411]
1.12.1.1.1.5.1 - 19.5.17.1.5.1 Variation 1: Palladium-Catalyzed Approaches: Homogeneous Catalysis [Seite 411]
1.12.1.1.1.5.2 - 19.5.17.1.5.2 Variation 2: Palladium-Catalyzed Approaches: Heterogeneous Catalysis [Seite 418]
1.12.1.1.1.5.3 - 19.5.17.1.5.3 Variation 3: Copper-Catalyzed Approaches [Seite 421]
1.12.1.1.1.5.4 - 19.5.17.1.5.4 Variation 4: Dual Palladium- and Copper-Catalyzed Approaches [Seite 424]
1.12.1.1.1.6 - 19.5.17.1.6 Method 6: Use of Organic Cyanide Sources [Seite 425]
1.12.1.1.1.6.1 - 19.5.17.1.6.1 Variation 1: Use of Cyanohydrins [Seite 425]
1.12.1.1.1.6.2 - 19.5.17.1.6.2 Variation 2: Use of Trimethylsilyl Cyanide [Seite 429]
1.12.1.1.1.6.3 - 19.5.17.1.6.3 Variation 3: Use of N-Cyano-N-phenyl-4-toluenesulfonamide [Seite 431]
1.12.1.1.1.7 - 19.5.17.1.7 Method 7: In Situ Generation of Cyanide from Non-Cyanide-Containing Precursors [Seite 431]
1.12.1.1.2 - 19.5.17.2 Preparation of Hetaryl Cyanides [Seite 433]
1.12.1.1.2.1 - 19.5.17.2.1 Method 1: Palladium-Catalyzed Coupling Reactions [Seite 437]
1.12.1.1.2.2 - 19.5.17.2.2 Method 2: Copper-Catalyzed Coupling Reactions [Seite 440]
1.12.1.1.2.3 - 19.5.17.2.3 Method 3: Dual Palladium- and Copper-Catalyzed Approaches [Seite 443]
1.12.1.1.3 - 19.5.17.3 Preparation of Vinyl Cyanides [Seite 446]
1.12.1.1.3.1 - 19.5.17.3.1 Method 1: Cyanation of Vinyl Halides and Vinylboronic Acids [Seite 446]
1.13 - Volume 27: Heteroatom Analogues of Aldehydes and Ketones [Seite 454]
1.13.1 - 27.25 Product Class 25: N-Sulfanyl-, N-Selanyl-, and N-Tellanylimines, and Their Oxidation Derivatives [Seite 454]
1.13.1.1 - 27.25.1 Product Subclass 1: N-Sulfanylimines [Seite 454]
1.13.1.1.1 - 27.25.1.1 Synthesis of Product Subclass 1 [Seite 454]
1.13.1.1.1.1 - 27.25.1.1.1 Method 1: Synthesis from Aldehydes or Ketones [Seite 454]
1.13.1.1.1.1.1 - 27.25.1.1.1.1 Variation 1: From Ammonia and a Thiol [Seite 454]
1.13.1.1.1.1.2 - 27.25.1.1.1.2 Variation 2: From Ammonia and a Disulfide [Seite 455]
1.13.1.1.1.1.3 - 27.25.1.1.1.3 Variation 3: From N,N-Bis(trimethylsilyl)sulfenamides [Seite 456]
1.13.1.1.1.1.4 - 27.25.1.1.1.4 Variation 4: From Sulfenamides [Seite 458]
1.13.1.1.1.2 - 27.25.1.1.2 Method 2: Synthesis from Imines and Imine Derivatives [Seite 461]
1.13.1.1.1.2.1 - 27.25.1.1.2.1 Variation 1: From N-Unsubstituted Imines [Seite 461]
1.13.1.1.1.2.2 - 27.25.1.1.2.2 Variation 2: From Oximes [Seite 462]
1.13.1.1.1.2.3 - 27.25.1.1.2.3 Variation 3: From Oxime Thiocarbamates [Seite 463]
1.13.1.1.1.2.4 - 27.25.1.1.2.4 Variation 4: From O-Tosyloximes [Seite 464]
1.13.1.1.1.2.5 - 27.25.1.1.2.5 Variation 5: From N-Chloroimines [Seite 465]
1.13.1.1.1.3 - 27.25.1.1.3 Method 3: Synthesis from a-Aminoalkanoates [Seite 467]
1.13.1.1.1.4 - 27.25.1.1.4 Method 4: Synthesis from Sulfinamides [Seite 468]
1.13.1.1.1.5 - 27.25.1.1.5 Method 5: Synthesis from Nitro Compounds [Seite 468]
1.13.1.2 - 27.25.2 Product Subclass 2: N-Sulfinylimines [Seite 469]
1.13.1.2.1 - 27.25.2.1 Synthesis of Product Subclass 2 [Seite 469]
1.13.1.2.1.1 - 27.25.2.1.1 Method 1: Synthesis by Oxidation of N-Sulfanylimines [Seite 469]
1.13.1.2.1.2 - 27.25.2.1.2 Method 2: Synthesis from N-Metalated Imines [Seite 473]
1.13.1.2.1.2.1 - 27.25.2.1.2.1 Variation 1: From Sulfinate Esters [Seite 473]
1.13.1.2.1.2.2 - 27.25.2.1.2.2 Variation 2: From a Cyclic Sulfinamide [Seite 475]
1.13.1.2.1.3 - 27.25.2.1.3 Method 3: Synthesis from Ortho Esters [Seite 476]
1.13.1.2.1.4 - 27.25.2.1.4 Method 4: Synthesis from an Aldehyde Hydrate [Seite 477]
1.13.1.2.1.5 - 27.25.2.1.5 Method 5: Synthesis from Carbonyl Derivatives [Seite 477]
1.13.1.2.1.5.1 - 27.25.2.1.5.1 Variation 1: From 1,2,3-Oxathiazolidine 2-Oxides [Seite 477]
1.13.1.2.1.5.2 - 27.25.2.1.5.2 Variation 2: From Sulfinate Esters [Seite 479]
1.13.1.2.1.5.3 - 27.25.2.1.5.3 Variation 3: From an N-Sulfinylbornane-10,2-sultam [Seite 481]
1.13.1.2.1.5.4 - 27.25.2.1.5.4 Variation 4: From Sulfinamides [Seite 482]
1.13.1.2.1.5.5 - 27.25.2.1.5.5 Variation 5: From a Phosphazene [Seite 485]
1.13.1.2.1.6 - 27.25.2.1.6 Method 6: Synthesis from Sulfoximides [Seite 486]
1.13.1.2.1.7 - 27.25.2.1.7 Method 7: Synthesis from Other N-Sulfinylimines [Seite 487]
1.13.1.2.2 - 27.25.2.2 Applications of Product Subclass 2 in Organic Synthesis [Seite 488]
1.13.1.3 - 27.25.3 Product Subclass 3: N-Sulfonylimines [Seite 490]
1.13.1.3.1 - 27.25.3.1 Synthesis of Products of Subclass 3 [Seite 490]
1.13.1.3.1.1 - 27.25.3.1.1 Method 1: Synthesis from Acetals [Seite 490]
1.13.1.3.1.1.1 - 27.25.3.1.1.1 Variation 1: From O,O-Acetals and Sulfonamides [Seite 490]
1.13.1.3.1.1.2 - 27.25.3.1.1.2 Variation 2: From N-[(Arylsulfonyl)methyl]arenesulfonamides [Seite 491]
1.13.1.3.1.2 - 27.25.3.1.2 Method 2: Synthesis from Alkenes and Allenes [Seite 492]
1.13.1.3.1.2.1 - 27.25.3.1.2.1 Variation 1: By Oxidative Amination [Seite 492]
1.13.1.3.1.2.2 - 27.25.3.1.2.2 Variation 2: From N,N-Dihalosulfonamides [Seite 493]
1.13.1.3.1.2.3 - 27.25.3.1.2.3 Variation 3: From Sulfonyl Azides [Seite 493]
1.13.1.3.1.2.4 - 27.25.3.1.2.4 Variation 4: From Oxazolidinones [Seite 495]
1.13.1.3.1.3 - 27.25.3.1.3 Method 3: Synthesis from Alkynes [Seite 496]
1.13.1.3.1.3.1 - 27.25.3.1.3.1 Variation 1: By a Hydroamination Reaction [Seite 496]
1.13.1.3.1.3.2 - 27.25.3.1.3.2 Variation 2: From Sulfonyl Azides [Seite 498]
1.13.1.3.1.3.3 - 27.25.3.1.3.3 Variation 3: Through Iminobismuthane Addition [Seite 499]
1.13.1.3.1.4 - 27.25.3.1.4 Method 4: Synthesis from Aziridines [Seite 500]
1.13.1.3.1.5 - 27.25.3.1.5 Method 5: Synthesis from Carbonyl Compounds [Seite 501]
1.13.1.3.1.5.1 - 27.25.3.1.5.1 Variation 1: From Sulfonamides [Seite 501]
1.13.1.3.1.5.2 - 27.25.3.1.5.2 Variation 2: From Isocyanates [Seite 506]
1.13.1.3.1.5.3 - 27.25.3.1.5.3 Variation 3: From N-Sulfinylsulfonamides [Seite 507]
1.13.1.3.1.5.4 - 27.25.3.1.5.4 Variation 4: From Chloramine-T [Seite 508]
1.13.1.3.1.6 - 27.25.3.1.6 Method 6: Synthesis from Other Imines [Seite 510]
1.13.1.3.1.6.1 - 27.25.3.1.6.1 Variation 1: From Oximes [Seite 510]
1.13.1.3.1.6.2 - 27.25.3.1.6.2 Variation 2: From N-(Trimethylsilyl)imines [Seite 512]
1.13.1.3.1.6.3 - 27.25.3.1.6.3 Variation 3: From N-Sulfanylimines [Seite 512]
1.13.1.3.1.6.4 - 27.25.3.1.6.4 Variation 4: From N-Sulfinylimines [Seite 513]
1.13.1.3.1.6.5 - 27.25.3.1.6.5 Variation 5: From Imidoyl Chlorides [Seite 514]
1.13.1.3.1.7 - 27.25.3.1.7 Method 7: Synthesis from Sulfimides [Seite 515]
1.13.1.3.1.8 - 27.25.3.1.8 Method 8: Synthesis by Oxidation of N-Sulfonylanilines [Seite 517]
1.13.1.3.1.9 - 27.25.3.1.9 Method 9: Synthesis from N-Sulfonylamides [Seite 524]
1.13.1.3.2 - 27.25.3.2 Applications of Product Subclass 3 in Organic Synthesis [Seite 524]
1.13.1.4 - 27.25.4 Product Subclass 4: N-Selanylimines [Seite 525]
1.13.1.4.1 - 27.25.4.1 Synthesis of Product Subclass 4 [Seite 525]
1.13.1.4.1.1 - 27.25.4.1.1 Method 1: Synthesis from N-Unsubstituted Imines [Seite 525]
1.13.1.4.1.2 - 27.25.4.1.2 Method 2: Synthesis by Oxidation of Phenols [Seite 525]
1.13.1.4.1.3 - 27.25.4.1.3 Method 3: Synthesis from N-Selenamides [Seite 527]
1.13.1.5 - 27.25.5 Product Subclass 5: N-Seleninylimines and Related Compounds [Seite 527]
1.13.1.5.1 - 27.25.5.1 Synthesis of Product Subclass 5 [Seite 527]
1.13.1.5.1.1 - 27.25.5.1.1 Method 1: Synthesis from Imines and Imine Derivatives [Seite 527]
1.13.1.5.1.1.1 - 27.25.5.1.1.1 Variation 1: From Imines [Seite 528]
1.13.1.5.1.1.2 - 27.25.5.1.1.2 Variation 2: From N-Chloroimines [Seite 528]
1.13.1.6 - 27.25.6 Product Subclass 6: N-Tellanylimines [Seite 528]
1.13.1.6.1 - 27.25.6.1 Synthesis of Product Subclass 6 [Seite 528]
1.13.1.6.1.1 - 27.25.6.1.1 Method 1: From N-Metalloimines [Seite 528]
1.13.1.6.1.2 - 27.25.6.1.2 Method 2: From Pentafluorotellurium Isocyanate [Seite 529]
1.14 - Author Index [Seite 538]
1.15 - Abbreviations [Seite 560]
1.16 - List of All Volumes [Seite 566]