This is a Solutions Manual to Accompany with solutions to the exercises in the main volume of Principles of Physical Chemistry, Third Edition.
This book provides a unique approach to introduce undergraduate students to the concepts and methods of physical chemistry, which are the foundational principles of Chemistry. The book introduces the student to the principles underlying the essential sub-fields of quantum mechanics, atomic and molecular structure, atomic and molecular spectroscopy, statistical thermodynamics, classical thermodynamics, solutions and equilibria, electrochemistry, kinetics and reaction dynamics, macromolecules, and organized molecular assemblies. Importantly, the book develops and applies these principles to supramolecular assemblies and supramolecular machines, with many examples from biology and nanoscience. In this way, the book helps the student to see the frontier of modern physical chemistry developments.
The book begins with a discussion of wave-particle duality and proceeds systematically to more complex chemical systems in order to relate the story of physical chemistry in an intellectually coherent manner. The topics are organized to correspond with those typically given in each of a two course semester sequence. The first 13 chapters present quantum mechanics and spectroscopy to describe and predict the structure of matter: atoms, molecules, and solids. Chapters 14 to 29 present statistical thermodynamics and kinetics and applies their principles to understanding equilibria, chemical transformations, macromolecular properties and supramolecular machines. Each chapter of the book begins with a simplified view of a topic and evolves to more rigorous description, in order to provide the student (and instructor) flexibility to choose the level of rigor and detail that suits them best. The textbook treats important new directions in physical chemistry research, including chapters on macromolecules, principles of interfaces and films for organizing matter, and supramolecular machines -- as well as including discussions of modern nanoscience, spectroscopy, and reaction dynamics throughout the text.
Auflage
Sprache
Produkt-Hinweis
Dateigröße
ISBN-13
978-1-119-85292-6 (9781119852926)
Schweitzer Klassifikation
1 - Cover [Seite 1]
2 - Title Page [Seite 5]
3 - Copyright [Seite 6]
4 - Contents [Seite 7]
5 - Preface Third Edition [Seite 11]
6 - Acknowledgment [Seite 13]
7 - Chapter 1 Wave-Particle Duality [Seite 15]
7.1 - 1.1 Exercises [Seite 15]
7.2 - 1.2 Problems [Seite 21]
8 - Chapter 2 Essential Aspects of Structure and Bonding [Seite 27]
8.1 - 2.1 Exercises [Seite 27]
8.2 - 2.2 Problems [Seite 34]
9 - Chapter 3 Schrödinger Equation [Seite 42]
9.1 - 3.1 Exercises [Seite 42]
9.2 - 3.2 Problems [Seite 54]
10 - Chapter 4 Hydrogen Atom [Seite 72]
10.1 - 4.1 Exercises [Seite 72]
10.2 - 4.2 Problems [Seite 84]
11 - Chapter 5 Atoms and Variational Principle [Seite 104]
11.1 - 5.1 Exercises [Seite 104]
11.2 - 5.2 Problems [Seite 117]
12 - Chapter 6 A Quantitative View of Chemical Bonding [Seite 138]
12.1 - 6.1 Exercises [Seite 138]
12.2 - 6.2 Problems [Seite 146]
13 - Chapter 7 Bonding Described by Electron Pairs and Molecular Orbitals [Seite 158]
13.1 - 7.1 Exercises [Seite 158]
13.2 - 7.2 Problems [Seite 170]
14 - Chapter 8 Molecules with PI?Electron Systems [Seite 182]
14.1 - 8.1 Exercises [Seite 182]
14.2 - 8.2 Problems [Seite 197]
15 - Chapter 9 Absorption of Light [Seite 214]
15.1 - 9.1 Exercises [Seite 214]
15.2 - 9.2 Problems [Seite 227]
16 - Chapter 10 Emission of Light [Seite 253]
16.1 - 10.1 Exercises [Seite 253]
16.2 - 10.2 Problems [Seite 259]
17 - Chapter 11 Nuclei: Particle and Wave Properties [Seite 264]
17.1 - 11.1 Exercises [Seite 264]
17.2 - 11.2 Problems [Seite 283]
18 - Chapter 12 Nuclear Spin [Seite 303]
18.1 - 12.1 Exercises [Seite 303]
18.2 - 12.2 Problems [Seite 307]
19 - Chapter 13 Solids and Intermolecular Forces [Seite 309]
19.1 - 13.1 Exercises [Seite 309]
19.2 - 13.2 Problems [Seite 324]
20 - Chapter 14 Thermal Motion of Molecules [Seite 338]
20.1 - 14.1 Exercises [Seite 338]
20.2 - 14.2 Problems [Seite 347]
21 - Chapter 15 Energy Distribution in Molecular Assemblies [Seite 356]
21.1 - 15.1 Exercises [Seite 356]
21.2 - 15.2 Problems [Seite 376]
22 - Chapter 16 Work w, Heat q, and Internal Energy U [Seite 395]
22.1 - 16.1 Exercises [Seite 395]
22.2 - 16.2 Problems [Seite 407]
23 - Chapter 17 Reversible Work wrev, Reversible Heat qrev, and Entropy S [Seite 418]
23.1 - 17.1 Exercises [Seite 418]
23.2 - 17.2 Problems [Seite 432]
24 - Chapter 18 General Conditions for Spontaneity and its Application to Equilibria of Ideal Gases and Dilute Solutions [Seite 449]
24.1 - 18.1 Exercises [Seite 449]
24.2 - 18.2 Problems [Seite 467]
25 - Chapter 19 Formal Thermodynamics and Its Application to Phase Equilibria [Seite 483]
25.1 - 19.1 Exercises [Seite 483]
25.2 - 19.2 Problems [Seite 495]
26 - Chapter 20 Real Gases [Seite 511]
26.1 - 20.1 Exercises [Seite 511]
26.2 - 20.2 Problems [Seite 527]
27 - Chapter 21 Real Solutions [Seite 541]
27.1 - 21.1 Exercises [Seite 541]
27.2 - 21.2 Problems [Seite 554]
28 - Chapter 22 Reaction Equilibria in Aqueous Solutions and Biosystems [Seite 564]
28.1 - 22.1 Exercises [Seite 564]
28.2 - 22.2 Problems [Seite 577]
29 - Chapter 23 Chemical Reactions in Electrochemical Cells [Seite 589]
29.1 - 23.1 Exercises [Seite 589]
29.2 - 23.2 Problems [Seite 600]
30 - Chapter 24 Chemical Kinetics [Seite 612]
30.1 - 24.1 Exercises [Seite 612]
30.2 - 24.2 Problems [Seite 627]
31 - Chapter 25 Transition States and Chemical Reactions [Seite 640]
31.1 - 25.1 Exercises [Seite 640]
31.2 - 25.2 Problems [Seite 655]
32 - Chapter 26 Macromolecules [Seite 669]
32.1 - 26.1 Exercises [Seite 669]
32.2 - 26.2 Problems [Seite 681]
33 - Chapter 27 Organized Molecular Assemblies [Seite 694]
33.1 - 27.1 Exercises [Seite 694]
33.2 - 27.2 Problems [Seite 706]
34 - Chapter 28 Supramolecular Machines [Seite 714]
34.1 - 28.1 Exercises [Seite 714]
34.2 - 28.2 Problems [Seite 725]
35 - Chapter 29 Origin of Life. Matter Carrying Information [Seite 731]
35.1 - 29.1 Exercises [Seite 731]
35.2 - 29.2 Problems [Seite 732]
36 - EULA [Seite 736]
