The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids

Electrolysis at the Interface Between Two Immiscible Electrolyte Solutions.- Theory.- Experimental Procedures.- Results and Applications.- References.- Problems of a Quantum Theory of Charge Transfer Reactions at the Interface Between Two Immiscible Liquids.- 1. The Franck-Condon Principle and the Physical Mechanism of the Transition.- 2. The Role of a Polar Medium and the Solvent Model.- 3. The Reorganization Energy of the Medium.- 4. The Role of Intramolecular Vibrations and Quantum Degrees of Freedom.- 5. General Regularities in Charge Transfer Processes at the Interface Between Immiscible Liquids.- 6. Electron Transfer at the Interface of Two Immiscible Liquids.- 7. Ion Transfer Through the Interface.- 8. Conclusion.- References.- Hydrodynamics and Mass Exchange at the Phase Boundaries with Regular Dissipative Structures.- 1. Introduction.- 2. General Theoretical Description of Dissipative Structures.- 3. Capillary Instability Due to the Marangoni Effect.- 4. Electro-hydrodynamic Instability.- 5. The Linear Analysis of Marangoni Instability.- 6. The Instability Caused by the Electric Forces Acting at the Surface of an Electrolyte Solution.- 7. Nonlinear Methods of Analyzing the Marangoni Instability.- 8. Models of Systems with Regular Hydrodynamic Dissipative Structures.- 9. Regular Circulation Fluxes Caused by Hydrodynamic Instability and their Role in Interfacial Mass Exchange.- 10. Conclusion.- References.- Galvani and Volta Potentials at the Interface Separating Immiscible Electrolyte Solutions.- Abstract.- 1. Introduction.- 2. Liquid Galvanic Cells - a Historical Survey.- 3. Galvani Potential at the Interface of Immiscible Electrolyte Solutions.- 4. Polarizable Interface of Inamisible Electrolyte Solutions.- 5. Volta Potentials at the Interfaces of ImmiscibleElectrolyte Solutions.- 6. Final Observations.- References.- Electrocapillarity and the Electric Double Layer Structure at Oil/Water Interfaces.- Summary.- Ideal-Polarized and Nonpolarized Oil/Water Interfaces.- Electrocapillary Curves of Ideal-Polarized Oil/Water Interfaces.- Electrocapillary Curves of Nonpolarized Oil/Water Interfaces.- References.- Study of the Electrical Double Layer at the Interface Between Two Immiscible Electrolyte Solutions by Impedance Measurements.- Thermodynamic Background.- AC Impedance Measurements.- Galvanostatic Pulse Technique.- Capacitance Data.- Zero-Charge Potential Difference.- Inner-Layer Potential Difference and Capacitance.- References.- Redox and Photochemical Reactions at the Interface Between Immiscible Liquids.- I. Introduction.- II. Redox Reactions in Monolayers.- III. Redox Processes in the Oil/Water System when Donor and Acceptor are Contained in Different Phases.- IV. Metalcomplexes of Porphyrins - Catalysts of Redox Reactions at the Interface Between Immiscible Liquids.- V. Evidence for the Heterogeneity of Redox Reactions Catalyzed by Metalcomplexes of Porphyrins.- VI. Enzyme Complexes of the Mitochondrial Respiratory Chain in the Oil/Water Interface.- VII. Redox Reactions in the Oil/Water System Accompanied by Protonation of Acceptor in the Nonaqueous Phase.- VIII. Coupling of Reactions at the Interface Between Immiscible Liquids.- References.- Counterions and Adsorption of Ion-Exchange Extractants at the Water/Oil Interface.- Abstract.- The Water/Oil Interface and Extraction Processes.- Adsorption and Extraction Constants.- Counterions and Adsorption of Extractants.- Determination of Activity Coefficients for Extractants in Low-Permittivity Media from Surface Pressure Isotherms.- References.- Kinetics of thePhotochemical Charge Separation in Micellar Solutions.- 1. The Formal Kinetics of Reactions in Micellar Systems.- 2. Charge Separation in Micellar Systems.- 3. Conclusion.- References.