Electrospray Ionization and Collision Induced Dissociation Mass Spectrometric Quantitative Conjunctions with the Experimental Intensity of the Analyte Ions of Metal-Organics- Stochastic Dynamics

Research Paper (postgraduate) from the year 2019 in the subject Chemistry - Analytical Chemistry, University of Dortmund (Institute of Environmental Research, Department of Analytical Chemistry), language: English, abstract: Throughout the chapters in this book we argue that the temporal behaviour of the experimental mass spectrometric intensity of analyte ions obeys a certain and universal law based on a stochastic dynamic approach. The content of the book evidences convincingly through a selected series of examples to molecular systems of metal-organic complexes of transition metal ions with electronic configuration d10, for instance, AgI- and ZnII-ions, the validity of our model equation reported, more recently. It needs to be underlined that, the comprehensive study that is provided, herein, is published, for first time in the literature. The book, therefore, represents monograph containing results from our research work, detailing correlatively experimental and theoretical mass spectrometric analyses of metal-organics using ultrahigh accuracy electrospray ionization and collision induced dissociation mass spectrometry. An enormous amount of effort is concentrated on a quantitative description of the relationships between experimental measurable parameter "intensity" and diffusion or kinetic parameters of analyte ions.