Layered 2D Materials and Their Allied Applications

Name: Layered 2D Materials and Their Allied Applications
Brand: Wiley
Price: 197.99 EUR
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Inamuddin Rajender Boddula Mohd Imran Ahamed Abdullah M. Asiri(Herausgeber*in)

Wiley (Verlag)

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Erschienen am 27. April 2020

400 Seiten

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Beschreibung

Ever since the discovery of graphene, two-dimensional layered materials (2DLMs) have been the central tool of the materials research community. The reason behind their importance is their superlative and unique electronic, optical, physical, chemical and mechanical properties in layered form rather than in bulk form. The 2DLMs have been applied to electronics, catalysis, energy, environment, and biomedical applications.

The following topics are discussed in the book's fifteen chapters:

* The research status of the 2D metal-organic frameworks and the different techniques used to synthesize them.

* 2D black phosphorus (BP) and its practical application in various fields.

* Reviews the synthesis methods of MXenes and provides a detailed discussion of their structural characterization and physical, electrochemical and optical properties, as well as applications in catalysis, energy storage, environmental management, biomedicine, and gas sensing.

* The carbon-based materials and their potential applications via the photocatalytic process using visible light irradiation.

* 2D materials like graphene, TMDCs, few-layer phosphorene, MXene in layered form and their heterostructures.

* The structure and applications of 2D perovskites.

* The physical parameters of pristine layered materials, ZnO, transition metal dichalcogenides, and heterostructures of layered materials are discussed.

* The coupling of graphitic carbon nitride with various metal sulfides and oxides to form efficient heterojunction for water purification.

* The structural features, synthetic methods, properties, and different applications and properties of 2D zeolites.

* The methods for synthesizing 2D hollow nanostructures are featured and their structural aspects and potential in medical and non-medical applications.

* The characteristics and structural aspects of 2D layered double hydroxides (LDHs) and the various synthesis methods and role of LDH in non-medical applications as adsorbent, sensor, catalyst, etc.

* The synthesis of graphene-based 2D layered materials synthesized by using top-down and bottom-up approaches where the main emphasis is on the hot-filament thermal chemical vapor deposition (HFTCVD) method.

* The different properties of 2D h-BN and borophene and the various methods being used for the synthesis of 2D h-BN, along with their growth mechanism and transfer techniques.

* The physical properties and current progress of various transition metal dichalcogenides (TMDC) based on photoactive materials for photoelectrochemical (PEC) hydrogen evolution reaction.

* The state-of-the-art of 2D layered materials and associated devices, such as electronic, biosensing, optoelectronic, and energy storage applications.

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Inhalt

Cover
Title Page
Copyright Page
Contents
Preface
Chapter 1 2D Metal-Organic Frameworks
1.1 Introduction
1.2 Synthesis Approaches
1.2.1 Selection of Synthetic Raw Materials
1.2.2 Solvent Volatility Method
1.2.3 Diffusion Method
1.2.3.1 Gas Phase Diffusion
1.2.3.2 Liquid Phase Diffusion
1.2.4 Sol-Gel Method
1.2.5 Hydrothermal/Solvothermal Synthesis Method
1.2.6 Stripping Method
1.2.7 Microwave Synthesis Method
1.2.8 Self-Assembly
1.2.9 Special Interface Synthesis Method
1.2.10 Surfactant-Assisted Synthesis Method
1.2.11 Ultrasonic Synthesis
1.3 Structures, Properties, and Applications
1.3.1 Structure and Properties of MOFs
1.3.2 Application in Biomedicine
1.3.3 Application in Gas Storage
1.3.4 Application in Sensors
1.3.5 Application in Chemical Separation
1.3.6 Application in Catalysis
1.3.7 Application in Gas Adsorption
1.4 Summary and Outlook
Acknowledgements
References
Chapter 2 2D Black Phosphorus
2.1 Introduction
2.2 The Research on Black Phosphorus
2.2.1 The Structure and Properties
2.2.1.1 The Structure of Black Phosphorus
2.2.1.2 The Properties of Black Phosphorus
2.2.2 Preparation Methods
2.2.2.1 Mechanical Exfoliation
2.2.2.2 Liquid-Phase Exfoliation
2.2.3 Antioxidant
2.2.3.1 Degradation Mechanism
2.2.3.2 Adding Protective Layer
2.2.3.3 Chemical Modification
2.2.3.4 Doping
2.3 Applications of Black Phosphorus
2.3.1 Electronic and Optoelectronic
2.3.1.1 Field-Effect Transistors
2.3.1.2 Photodetector
2.3.2 Energy Storage and Conversion
2.3.2.1 Catalysis
2.3.2.2 Batteries
2.3.2.3 Supercapacitor
2.3.3 Biomedical
2.4 Conclusion and Outlook
Acknowledgements
References
Chapter 3 2D Metal Carbides
3.1 Introduction
3.2 Synthesis Approaches
3.2.1 Ti3C2 Synthesis
3.2.2 V2C Synthesis
3.2.3 Ti2C Synthesis
3.2.4 Mo2C Synthesis
3.3 Structures, Properties, and Applications
3.3.1 Structures and Properties of 2D Metal Carbides
3.3.1.1 Structures and Properties of Ti3C2
3.3.1.2 Structural Properties of Ti2C
3.3.1.3 Structural Properties of Mo2C
3.3.1.4 Structural Properties of V2C
3.3.2 Carbide Materials in Energy Storage Applications
3.3.2.1 Ti3C2
3.3.2.2 Ti2C
3.3.2.3 V2C
3.3.2.4 Mo2C
3.3.3 Metal Carbide Materials in Catalysis Applications
3.3.3.1 Ti3C2
3.3.3.2 V2C
3.3.3.3 Mo2C
3.3.4 Metal Carbide Materials in Environmental Management Applications
3.3.4.1 Ti3C2 in Environmental Management Applications
3.3.4.2 Ti2C in Environmental Management Applications
3.3.4.3 V2C in Environmental Management Applications
3.3.4.4 Mo2C in Environmental Management Applications
3.3.5 Carbide Materials in Biomedicine Applications
3.3.5.1 Ti3C2 in Biomedicine Applications
3.3.5.2 Ti2C in Biomedicine Applications
3.3.5.3 V2C in Biomedicine Applications
3.3.5.4 Mo2C in Biomedicine Applications
3.3.6 Carbide Materials in Gas Sensing Applications
3.3.6.1 Ti3C2 in Gas Sensing Applications
3.3.6.2 Ti2C in Gas Sensing Applications
3.3.6.3 V2C in Gas Sensing Applications
3.3.6.4 Mo2C in Gas Sensing Applications
3.4 Summary and Outlook
Acknowledgements
References
Chapter 4 2D Carbon Materials as Photocatalysts
4.1 Introduction
4.2 Carbon Nanostructured-Based Materials
4.2.1 Forms of Carbon
4.2.2 Synthesis of Carbon Nanostructured-Based Materials
4.3 Photo-Degradation of Organic Pollutants
4.3.1 Graphene, Graphene Oxide, Graphene Nitride (g-C3N4)
4.3.1.1 Graphene-Based Materials
4.3.1.2 Graphene Nitride (g-C3N4)
4.3.2 Carbon Dots (CDs)
4.3.3 Carbon Spheres (CSs)
4.4 Carbon-Based Materials for Hydrogen Production
4.5 Carbon-Based Materials for CO2 Reduction
References
Chapter 5 Sensitivity Analysis of Surface Plasmon Resonance Biosensor Based on Heterostructure of 2D BlueP/MoS2 and MXene
5.1 Introduction
5.2 Proposed SPR Sensor, Design Considerations, and Modeling
5.2.1 SPR Sensor and Its Sensing Principle
5.2.2 Design Consideration
5.2.2.1 Layer 1: Prism for Light Coupling
5.2.2.2 Layer 2: Metal Layer
5.2.2.3 Layer 3: BlueP/MoS2 Layer
5.2.2.4 Layer 4: MXene (Ti3C2Tx) Layer as BRE for Biosensing
5.2.2.5 Layer 5: Sensing Medium (RI-1.33-1.335)
5.2.3 Proposed Sensor Modeling
5.3 Results Discussion
5.3.1 Role of Monolayer BlueP/MoS2 and MXene (Ti3C2Tx) and Its Comparison With Conventional SPR
5.3.2 Influence of Varying Heterostructure Layers for Proposed Design
5.3.3 Effect of Changing Prism Material and Metal on Performance of Proposed Design
5.4 Conclusion
References
Chapter 6 2D Perovskite Materials and Their Device Applications
6.1 Introduction
6.2 Structure
6.2.1 Crystal Structure
6.2.2 Electronic Structure of 2D Perovskites
6.2.3 Structure of Photovoltaic Cell
6.3 Discussion and Applications
6.4 Conclusion
References
Chapter 7 Introduction and Significant Parameters for Layered Materials
7.1 Graphene
7.2 Phosphorene
orthorhombic rhombohedral Simple cubic
semiconductor semimetal metal
7.3 Silicene
7.4 ZnO
7.5 Transition Metal Dichalcogenides (TMDCs)
7.6 Germanene and Stanene
7.7 Heterostructures
References
Chapter 8 Increment in Photocatalytic Activity of g-C3N4 Coupled Sulphides and Oxides for Environmental Remediation
8.1 Introduction
8.2 GCN Coupled Metal Sulphide Heterojunctions for Environment Remediation
8.2.1 GCN and MoS2-Based Photocatalysts
8.2.2 GCN and CdS-Based Heterojunctions
8.2.3 Some Other GCN Coupled Metal Sulphide Photocatalysts
8.3 GCN Coupled Metal Oxide Heterojunctions for Environment Remediation
8.3.1 GCN and MoO3-Based Heterojunctions
8.3.2 GCN and Fe2O3-Based Heterojunctions
8.3.3 Some Other GCN Coupled Metal Oxide Photocatalysts
8.4 Conclusions and Outlook
References
Chapter 9 2D Zeolites
9.1 Introduction
9.1.1 What is 2D Zeolite?
9.1.2 Advancement in Zeolites to 2D Zeolite
9.2 Synthetic Method
9.2.1 Bottom-Up Method
9.2.2 Top-Down Method
9.2.3 Support-Assisted Method
9.2.4 Post-Synthesis Modification of 2D Zeolites
9.3 Properties
9.4 Applications
9.4.1 Petro-Chemistry
9.4.2 Biomass Conversion
9.4.2.1 Pyrolysis of Solid Biomass
9.4.2.2 Condensation Reactions
9.4.2.3 Isomerization
9.4.2.4 Dehydration Reactions
9.4.3 Oxidation Reactions
9.4.4 Fine Chemical Synthesis
9.4.5 Organometallics
9.5 Conclusion
References
Chapter 10 2D Hollow Nanomaterials
10.1 Introduction
10.2 Structural Aspects of HNMs
10.3 Synthetic Approaches
10.3.1 Template-Based Strategies
10.3.1.1 Hard Templating
10.3.1.2 Soft Templating
10.3.2 Self-Templating Strategies
10.3.2.1 Surface Protected Etching
10.3.2.2 Ostwald Ripening
10.3.2.3 Kirkendall Effect
10.3.2.4 Galvanic Replacement
10.4 Medical Applications of HNMs
10.4.1 Imaging and Diagnosis Applications
10.4.2 Applications of Nanotube Arrays
10.4.2.1 Pharmacy and Medicine
10.4.2.2 Cancer Therapy
10.4.2.3 Immuno and Hyperthermia Therapy
10.4.2.4 Infection Therapy and Gene Therapy
10.4.3 Hollow Nanomaterials in Diagnostics and Therapeutics
10.4.4 Applications in Regenerative Medicine
10.4.5 Anti-Neurodegenerative Applications
10.4.6 Photothermal Therapy
10.4.7 Biosensors
10.5 Non-Medical Applications of HNMs
10.5.1 Catalytic Micro or Nanoreactors
10.5.2 Energy Storage
10.5.2.1 Lithium Ion Battery
10.5.2.2 Supercapacitor
10.5.3 Nanosensors
10.5.4 Wastewater Treatment
10.6 Toxicity of 2D HNMs
10.7 Future Challenges
10.8 Conclusion
Acknowledgement
References
Chapter 11 2D Layered Double Hydroxides
11.1 Introduction
11.2 Structural Aspects
11.3 Synthesis of LDHs
11.3.1 Co-Precipitation Method
11.3.2 Urea Hydrolysis
11.3.3 Ion-Exchange Method
11.3.4 Reconstruction Method
11.3.5 Hydrothermal Method
11.3.6 Sol-Gel Method
11.4 Nonmedical Applications of LDH
11.4.1 Adsorbent
11.4.2 Catalyst
11.4.3 Sensors
11.4.4 Electrode
11.4.5 Polymer Additive
11.4.6 Anion Scavenger
11.4.7 Flame Retardant
11.5 Biomedical Applications
11.5.1 Biosensors
11.5.2 Scaffolds
11.5.3 Anti-Microbial Agents
11.5.4 Drug Delivery
11.5.5 Imaging
11.5.6 Protein Purification
11.5.7 Gene Delivery
11.6 Toxicity
11.7 Conclusion
Acknowledgement
References
Chapter 12 Experimental Techniques for Layered Materials
12.1 Introduction
12.2 Methods for Synthesis of Graphene Layered Materials
12.3 Selection of a Suitable Metallic Substrate
12.4 Graphene Synthesis by HFTCVD
12.5 Graphene Transfer
12.6 Characterization Techniques
12.6.1 X-Ray Diffraction Technique
d D k
12.6.2 Field Emission Scanning Electron Microscopy (FESEM)
12.6.3 Transmission Electron Microscopy (TEM)
12.6.4 Fourier Transform Infrared Radiation (FTIR)
12.6.5 UV-Visible Spectroscopy
12.6.6 Raman Spectroscopy
12.6.7 Low Energy Electron Microscopy (LEEM)
12.7 Potential Applications of Graphene and Derived Materials
12.8 Conclusion
Acknowledgement
References
Chapter 13 Two-Dimensional Hexagonal Boron Nitride and Borophenes
13.1 Two-Dimensional Hexagonal Boron Nitride (2D h-BN): An Introduction
13.2 Properties of 2D h-BN
13.2.1 Structural Properties
13.2.2 Electronic and Dielectric Properties
13.2.3 Optical Properties
13.3 Synthesis Methods of 2D h-BN
13.3.1 Mechanical Exfoliation
13.3.2 Liquid Exfoliation
13.3.3 Chemical Vapor Deposition (CVD)
13.3.3.1 Synthesis Parameters
13.3.3.2 Growth Mechanism
13.3.3.3 Transfer of 2D h-BN Onto Other Substrates
13.3.4 Physical Vapor Deposition Method (PVD)
13.3.5 Surface Segregation Method
13.4 Application of 2D h-BN
13.4.1 2D h-BN in Electronic Manufacturing
13.4.2 2D h-BN as a Filler in Polymer Composites
13.4.3 2D h-BN as a Protective Barrier
13.4.4 2D h-BN in Optoelectronics
13.5 Borophene
13.5.1 Theoretical Investigation and Experimental Synthesis
13.5.2 Properties and Application of Borophene
13.5.2.1 Electronic Properties of Borophene
13.5.2.2 Chemical Properties
13.5.3 Potential Applications of Borophene
References
Chapter 14 Transition-Metal Dichalcogenides for Photoelectrochemical Hydrogen Evolution Reaction
14.1 Introduction
14.2 TMDC-Based Photoactive Materials for HER
14.2.1 MoS2
14.2.2 MoSe2
14.2.3 WS2
14.2.4 CoSe
14.2.5 FeS2
14.2.6 NiSe2
14.3 TMDCs Fabrication Methods
14.3.1 Hydrothermal
14.3.2 Chemical Vapor Deposition/Vapor Phase Growth Process
14.3.3 Metal-Organic Chemical Vapor Deposition (MOCVD)
14.3.4 Atomic Layer Deposition (ALD)
14.4 Current Photocatalytic Activity Performance
14.5 Summary and Perspective
References
Chapter 15 State-of-the-Art and Perspective of Layered Materials
15.1 Introduction
15.2 State-of-the-Art and Future Perspective
15.2.1 Electronic Devices
15.2.2 Optoelectronic Devices
15.2.3 Energy Storage Devices
15.3 Conclusion
References
Index
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