Applications of Metal-Organic Frameworks and Their Derived Materials

Name: Applications of Metal-Organic Frameworks and Their Derived Materials
Brand: Wiley
Price: 190.99 EUR
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Inamuddin Rajender Boddula Mohd Imran Ahamed Abdullah M. Asiri(Herausgeber*in)

Wiley (Verlag)

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Erschienen am 23. April 2020

496 Seiten

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Inhalt

Cover
Title Page
Copyright Page
Contents
Preface
Chapter 1 Application of MOFs and Their Derived Materials in Sensors
1.1 Introduction
1.2 Application of MOFs and Their Derived Materials in Sensors
1.2.1 Optical Sensor
1.2.1.1 Colorimetric Sensor
1.2.1.2 Fluorescence Sensor
1.2.1.3 Chemiluminescent Sensor
1.2.2 Electrochemical Sensor
1.2.2.1 Amperometric Sensor
1.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor
1.2.3 Field-Effect Transistor Sensor
1.2.4 Mass-Sensitive Sensor
1.3 Conclusion
Acknowledgments
References
Chapter 2 Applications of Metal-Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics
2.1 Introduction
2.1.1 Brief Introduction to Piezo/Ferroelectricity
2.2 Fundamentals of Piezo/Ferroelectricity
2.3 Metal-Organic Frameworks for Piezo/ Ferroelectricity
2.4 Ferro/Piezoelectric Behavior of Various MOFs
2.5 Conclusion
References
Chapter 3 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials "MOF Architecture"
3.1 Introduction
3.2 Fabrication and Functionalization of MOFs
3.2.1 Metal Nodes
3.2.2 Organic Linkers
3.2.3 Secondary Building Units
3.2.4 Synthesis Methods
3.2.4.1 Hydrothermal and Solvothermal Method
3.2.4.2 Microwave Synthesis
3.2.4.3 Electrochemical Method
3.2.4.4 Mechanochemical Synthesis
3.2.4.5 Sonochemical (Ultrasonic Assisted) Method
3.2.4.6 Diffusion Method
3.2.4.7 Template Method
3.2.5 Synthesis Strategies
3.3 MOF Derived Materials
3.4 Conclusion
References
Chapter 4 Application of MOFs and Their Derived Materials in Molecular Transport
4.1 Introduction
4.2 MOFs as Nanocarriers for Membrane Transport
4.2.1 MIL-89
4.2.2 MIL-88A
4.2.3 MIL-100
4.2.4 MIL-101
4.2.5 MIL-53
4.2.6 ZIF-8
4.2.7 Zn-TATAT
4.2.8 BioMOF-1 (Zn)
4.2.9 UiO (Zr)
4.3 Conclusion
References
Chapter 5 Role of MOFs as Electro/-Organic Catalysts
5.1 What Is MOFs
5.2 MOFs as Electrocatalyst in Sensing Applications
5.3 MOFs as Organic Catalysts in Organic Transformations
5.4 Conclusion and Future Prospects
References
Chapter 6 Application of MOFs and Their Derived Materials in Batteries
6.1 Introduction
6.2 Metal-Organic Frameworks
6.2.1 Classification and Properties of Metal-Organic Frameworks
6.2.2 Potential Applications of MOFs
6.2.3 Synthesis of MOFs
6.3 Polymer Electrolytes
6.3.1 Historical Perspectives and Classification of Polymer Electrolytes
6.3.2 MOF Based Polymer Electrolytes
6.4 Ionic Liquids
6.4.1 Properties of Ionic Liquids
6.4.2 Ionic Liquid Incorporated MOF
6.5 Ion Transport in Polymer Electrolytes
6.5.1 General Description of Ionic Conductivity
6.5.2 Models for Ionic Transport in Polymer Electrolytes
6.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements
6.5.4 Concept of Mismatch and Relaxation
6.5.5 Scaling of ac Conductivity
6.6 IL Incorporated MOF Based Composite Polymer Electrolytes
6.7 Conclusion and Perspectives
References
Chapter 7 Fine Chemical Synthesis Using Metal-Organic Frameworks as Catalysts
7.1 Introduction
7.2 Oxidation Reaction
7.2.1 Epoxidation
7.2.2 Sulfoxidation
7.2.3 Aerobic Oxidation of Alcohols
7.3 1,3-Dipolar Cycloaddition Reaction
7.4 Transesterification Reaction
7.5 C-C Bond Formation Reactions
7.5.1 Heck Reactions
7.5.2 Sonogashira Coupling
7.5.3 Suzuki Coupling
7.6 Conclusion
References
Chapter 8 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis
8.1 Introduction
8.1.1 The Active Centers in Parent MOF Materials
8.1.2 The Active Centers in MOF Catalyst
8.1.3 Metal Nodes
8.2 Hydrogenation Reactions
8.2.1 Hydrogenation of Alpha-Beta Unsaturated Aldehyde
8.2.2 Hydrogenation of Cinnamaldehyde
8.2.3 Hydrogenation of Nitroarene
8.2.4 Hydrogenation of Nitro Compounds
8.2.5 Hydrogenation of Benzene
8.2.6 Hydrogenation of Quinoline
8.2.7 Hydrogenation of Carbon Dioxide
8.2.8 Hydrogenation of Aromatics
8.2.9 Hydrogenation of Levulinic Acid
8.2.10 Hydrogenation of Alkenes and Alkynes
8.2.11 Hydrogenation of Phenol
8.3 Conclusion
References
Chapter 9 Application of MOFs and Their Derived Materials in Solid-Phase Extraction
9.1 Solid-Phase Extraction
9.1.1 Materials in SPE
9.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (µSPE)
9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-µSPE)
9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-µSPE)
9.5 Concluding Remarks
Acknowledgments
References
Chapter 10 Anticancer and Antimicrobial MOFs and Their Derived Materials
10.1 Introduction
10.2 Anticancer MOFs
10.2.1 MOFs as Drug Carriers
10.2.2 MOFs in Phototherapy
10.3 Antibacterial MOFs
10.4 Antifungal MOFs
References
Chapter 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Pe
11.1 Introduction
11.2 General Synthesis Routes
11.2.1 Hydrothermal Synthesis
11.2.2 Solvothermal Synthesis of MOFs
11.2.3 Room Temperature Synthesis
11.2.4 Microwave Assisted Synthesis
11.2.5 Mechanochemical Synthesis
11.2.6 Electrochemical Synthesis
11.3 Postsynthetic Modification in MOF
11.4 Computational Method
11.5 Results and Discussion
11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone)
11.6 Conclusion
References
Chapter 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds
12.1 Introduction
12.2 VOCs and Their Potential Hazards
12.2.1 Other Sources of VOCs
12.3 VOCs Removal Techniques
12.4 Fabricated MOF for VOC Removal
12.4.1 MIL Series MOFs
12.4.2 Isoreticular MOFs
12.4.2.1 Adsorption Comparison of the Isoreticular MOFs
12.4.3 NENU Series MOFs
12.4.4 MOF-5, Eu-MOF, and MOF-199
12.4.5 Amine-Impregnated MIL-100
12.4.6 Biodegradable MOFs MIL-88 Series
12.4.7 Catalytic MOFs
12.4.8 Photo-Degradating MOFs
12.4.9 Some Other Studied MOFs
12.5 MOF Composites
12.5.1 MIL-101 Composite With Graphene Oxide
12.5.2 MIL-101 Composite With Graphite Oxide
12.6 Generalization Adsorptive Removal of VOCs by MOFs
12.7 Simple Modeling the Adsorption
12.7.1 Thermodynamic Parameters
12.7.2 Dynamic Sorption Methods
12.8 Factor Affecting VOCs Adsorption
12.8.1 Breathing Phenomena
12.8.2 Activation of MOFs
12.8.3 Applied Pressure
12.8.4 Relative Humidity
12.8.5 Breakthrough Conditions
12.8.6 Functional Group of MOFs
12.8.7 Concentration, Molecular Size, and Type of VOCs
12.9 Future Perspective
References
Chapter 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis
List of Abbreviations
13.1 Introduction
13.2 Perspective Synthesis of MOF and Their Derived Materials
13.3 MOF for Hydrogen Evolution Reaction
13.4 MOF for Oxygen Evolution Reaction
13.5 MOF for Oxygen Reduction Reaction
13.6 MOF for CO2 Electrochemical Reduction Reaction
13.6.1 Electrosynthesis of MOF for CO2 Reduction
13.6.2 Composite Electrodes as MOF for CO2 Reduction
13.6.3 Continuous Flow Reduction of CO2
13.6.4 CO2 Electrochemical Reduction in Ionic Liquid
13.7 MOF for Electrocatalytic Sensing
13.8 Electrocatalytic Features of MOF
13.9 Conclusion
Acknowledgment
References
Chapter 14 Applications of MOFs and Their Composite Materials in LightDriven Redox Reactions
14.1 Introduction
14.1.1 MOFs as Photocatalysts
14.1.2 Charge Transfer Mechanisms
14.1.3 Methods of Synthesis
14.2 Pristine MOFs and Their Application in Photocatalysis
14.2.1 Group 4 Metallic Clusters
14.2.2 Groups 8, 9, and 10 Metallic Clusters
14.2.3 Group 11 Metallic Clusters
14.2.4 Group 12 Metallic Clusters
14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis
14.3.1 Ag-MOF Composites
14.3.2 Au-MOF Composites
14.3.3 Cu-MOF Composites
14.3.4 Pd-MOF Composites
14.3.5 Pt-MOF Composites
14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis
14.4.1 TiO2-MOF Composites
14.4.2 Graphitic Carbon Nitride-MOF Composites
14.4.3 Bismuth-Based Semiconductors
14.4.4 Reduced Graphene Oxide-MOF Composites
14.4.5 Silver-Based Semiconductors
14.4.6 Other Semiconductors
14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis
14.5.1 Semiconductor-Semiconductor-MOF Composites
14.5.2 Semiconductor-Metal-MOF Composites
14.6 Conclusions
References
Index
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