High-Performance Materials from Bio-based Feedstocks

Name: High-Performance Materials from Bio-based Feedstocks
Brand: Wiley
Price: 153.99 EUR
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Andrew J. Hunt Nontipa Supanchaiyamat Kaewta Jetsrisuparb Jesper T. N. Knijnenburg(Herausgeber*in)

Wiley (Verlag)

1. Auflage

Erschienen am 22. März 2022

432 Seiten

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Inhalt

Cover
Title Page
Copyright Page
Contents
List of Contributors
Series Preface
Chapter 1 High-performance Materials from Bio-based Feedstocks: Introduction and Structure of the Book
1.1 Introduction
1.2 High-performance Bio-based Materials and Their Applications
1.2.1 Biomass Constituents
1.2.2 Bioderived Materials
1.3 Structure of the Book
References
Chapter 2 Bio-based Carbon Materials for Catalysis
2.1 Introduction
2.2 Biomass Resources for Carbon Materials
2.2.1 Wood from Natural Forests
2.2.2 Agricultural Residues
2.3 Thermochemical Conversion Processes
2.3.1 Carbonization and Pyrolysis
2.3.2 Activation
2.3.3 Hydrothermal Carbonization
2.3.4 Graphene Preparation from Biomass
2.4 Fundamentals of Heterogeneous Catalysis
2.5 Catalysis Applications of Selected Bio-based Carbon Materials
2.5.1 Biochar
2.5.2 Modified Biochar
2.5.3 Biomass-Derived Activated Carbon
2.5.4 Hydrothermal Bio-based Carbons
2.5.5 Sugar-Derived Carbon Catalysts
2.5.6 Carbon Nanotubes from Biomass
2.5.7 Graphene and Its Derivatives
2.6 Summary and Future Aspects
Chapter 3 Starbon®: Novel Template-Free Mesoporous Carbonaceous Materials from Biomass - Synthesis, Functionalisation and Applications in Adsorption, and Catalysis
3.1 Introduction
3.2 Choice of Polysaccharide
3.2.1 Synthetic Procedure
3.2.2 Derivatisation
3.2.3 Applications
3.2.4 Adsorption Processes
3.2.5 Conclusion
References
Chapter 4 Conversion of Biowastes into Carbon-based Electrodes
4.1 Introduction
4.2 Conversion Techniques of Biowastes
4.2.1 Carbonization
4.2.2 Activation
4.3 Structure and Doping
4.3.1 Biowaste Selection
4.3.2 Structure Control
4.3.3 Heteroatom Doping
4.4 Electrochemical Applications
4.4.1 Supercapacitors
4.4.2 Capacitive Deionization Cells
4.4.3 Hydrogen and Oxygen Evolution
4.4.4 Fuel Cells
4.4.5 Lithium-Ion Batteries and Others
4.5 Conclusion and Outlook
Chapter 5 Bio-based Materials in Electrochemical Applications
5.1 Introduction
5.2 Fundamentals of Bio-based Materials
5.2.1 Bio-based Polymers
5.2.2 Carbonaceous Materials from Biological Feedstocks
5.3 Application of Bio-based Materials in Batteries
5.3.1 General Concept of Metal-Ion Batteries
5.4 Application of Bio-based Polymers in Capacitors
5.4.1 General Concept of Electrochemical Capacitors
5.4.2 Electrode Materials
5.5 Alternative Binders for Sustainable Electrochemical Energy Storage
5.5.1 Polysaccharides and Cellulose-based Binders
5.5.2 Lignin
5.6 Application of Bio-based Polymers in Fuel Cells
5.6.1 Chitosan
5.6.2 Other Biopolymers
5.7 Conclusion and Outlook
Chapter 6 Bio-based Materials Using Deep Eutectic Solvent Modifiers
6.1 Introduction
6.2 Bio-based Materials
6.2.1 Ionic Liquids
6.2.2 Deep Eutectic Solvents
6.2.3 Morphological/Mechanical Modification
6.2.4 Chemical Modification
6.2.5 Composite Formation
6.2.6 Gelation
6.3 Conclusion
References
Chapter 7 Biopolymer Composites for Recovery of Precious and Rare Earth Metals
7.1 Introduction
7.2 Mechanisms of Metal Adsorption
7.2.1 Silver
7.2.2 Gold and Platinum Group Metals
7.2.3 Rare Earth Metals
7.3 Composite Materials and Their Adsorption
7.3.1 Cellulose-based Composite Adsorbents
7.3.2 Chitosan-based Composite Adsorbents
7.3.3 Alginate-based Adsorbents
7.3.4 Lignin-based Composite Adsorbents
7.4 Conclusion and Outlook
Chapter 8 Bio-Based Materials in Anti-HIV Drug Delivery
8.1 Introduction
8.2 Biomedical Strategies for HIV Prophylaxis
8.3 Properties of Anti-HIV Drug Delivery Systems
8.4 Bio-based Materials for Anti-HIV Drug Delivery Systems
8.4.1 Cellulose
8.4.2 Chitosan
8.4.3 Polylactic Acid
8.4.4 Carrageenan
8.4.5 Alginate
8.4.6 Hyaluronic Acid
8.4.7 Pectin
8.5 Conclusion
References
Chapter 9 Chitin - A Natural Bio-feedstock and Its Derivatives: Chemistry and Properties for Biomedical Applications
9.1 Bio-feedstocks
9.1.1 Chitin
9.1.2 Chitosan
9.1.3 Glucan
9.1.4 Chitin-Glucan Complex
9.1.5 Polyphenols
9.2 Synthetic Route
9.2.1 Isolation of ChGC
9.2.2 Derivatives of ChGC and Its Modified Polymers
9.2.3 Preparation of d-Glucosamine from Chitin/Chitosan-Glucan
9.3 Properties of Chitin, ChGC, and Its Derivatives for Therapeutic Applications
9.3.1 Antibacterial Activity
9.3.2 Anticancer Activity
9.3.3 Antioxidant Activity
9.3.4 Therapeutic Applications
9.4 Gene Therapy - A Biomedical Approach
9.5 Cs: Properties and Factors Affecting Gene Delivery
9.6 Organic Modifications of Cs Backbone for Enhancing the Properties of Cs Associated with Gene Delivery
9.6.1 Modification of Cs with Hydrophilic Groups
9.6.2 Modification in Cs by Hydrophobic Groups
9.6.3 Modification by Cationic Substituents
9.6.4 Modification by Target Ligands
9.7 Multifunctional Modifications of Cs
9.8 Miscellaneous
9.9 Conclusion
Acknowledgments
References
Chapter 10 Carbohydrate-Based Materials for Biomedical Applications
10.1 Introduction
10.2 Bio-based Glycopolymers
10.2.1 Chitin and Chitosan
10.2.2 Cellulose
10.2.3 Starch
10.2.4 Dextran
10.3 Synthetic Carbohydrate-based Functionalized Materials
10.3.1 Glycomimetics
10.3.2 Presentation of Glycomimetics in Multivalent Scaffolds
10.4 Conclusion
References
Chapter 11 Organic Feedstock as Biomaterial for Tissue Engineering
11.1 Introduction
11.2 Protein-based Natural Biomaterials
11.2.1 Silk
11.2.2 Collagen
11.2.3 Decellularized Skins
11.2.4 Fibrin/Fibrinogen
11.3 Polysaccharide-based Natural Biomaterials
11.3.1 Chitosan
11.3.2 Alginate
11.3.3 Agarose
11.4 Summary
References
Chapter 12 Green Synthesis of Bio-based Metal-Organic Frameworks
12.1 Introduction
12.2 Green Synthesis of MOFs
12.2.1 Solvent-Free and Low Solvent Synthesis
12.2.2 Green Solvents
12.2.3 Sonochemical Synthesis
12.2.4 Electrochemical Synthesis
12.3 Bio-based Ligands
12.3.1 Amino Acids
12.3.2 Aliphatic Diacids
12.3.3 Cyclodextrins
12.3.4 Other
12.3.5 Exemplars: Bio-based MOFs Obtainable via Green Synthesis
12.4 Metal Ion Considerations
12.4.1 Calcium
12.4.2 Magnesium
12.4.3 Manganese
12.4.4 Iron
12.4.5 Titanium
12.4.6 Zirconium
12.4.7 Aluminium
12.4.8 Zinc
12.5 Challenges for Further Development Towards Applications
12.5.1 Stability Issues
12.5.2 Scalability and Cost
12.5.3 Competing Alternative Materials
12.6 Conclusion
Chapter 13 Geopolymers Based on Biomass Ash and Bio-based Additives for Construction Industry
13.1 Introduction
13.2 Pozzolan and Agricultural Waste Ash
13.3 Geopolymer
13.4 Combustion of Biomass
13.4.1 Open Field Burning
13.4.2 Controlled Burning
13.4.3 Boiler Burning
13.4.4 Fluidized Bed Burning
13.5 Properties and Utilization of Biomass Ashes
13.6 Biomass Ash-based Geopolymer
13.6.1 Rice Husk Ash-based Geopolymer
13.6.2 Bagasse Ash-based Geopolymer
13.6.3 Palm Oil Fuel Ash-based Geopolymer
13.6.4 Other Biomass-based Geopolymers
13.6.5 Use of Biomass in Making Sodium Silicate Solution and Other Products
13.6.6 Fire Resistance of Bio-based Geopolymer
13.7 Conclusion
References
Chapter 14 The Role of Bio-based Excipients in the Formulation of Lipophilic Nutraceuticals
14.1 Introduction
14.2 Emulsions and the Importance of Bio-based Materials as Emulsifiers
14.2.1 Conventional Micro- and Nanoemulsions
14.2.2 Pickering-Stabilised Emulsions
14.3 Novel Formulation Technologies: Colloidal Delivery Vesicles
14.3.1 Microgels
14.3.2 Nanoprecipitation
14.3.3 Liposomes
14.3.4 Complex Coacervation
14.3.5 Complexation
14.4 Key Drying Technologies Employed During Formulation
14.4.1 Spray Drying
14.4.2 Spray-Freeze Drying
14.4.3 Electrohydrodynamic Processing
14.4.4 Fluid Bed Drying
14.4.5 Extrusion
14.5 Conclusions and Future Perspectives
References
Chapter 15 Bio-derived Polymers for Packaging
15.1 Introduction
15.2 Starch
15.3 Chitin/Chitosan
15.4 Cellulose and Its Derivatives
15.4.1 Cellulose Nanocrystals
15.4.2 Cellulose Nanofibers
15.4.3 Bacterial Nanocellulose
15.4.4 Carboxymethyl Cellulose
15.5 Poly(Lactic Acid)
15.5.1 Bio-based Toughening Agents Used in PLA Toughness Improvement
15.5.2 Toughening of PLA and Its Properties Related to Packaging Applications
15.6 Bio-based Active and Intelligent Agents for Packaging
15.6.1 Active Agents
15.6.2 Intelligent Packaging
15.7 Conclusion
References
Chapter 16 Recent Developments in Bio-Based Materials for Controlled-Release Fertilizers
16.1 Introduction and Historical Review
16.1.1 Early Fertilizer Development and Its Impact on Environment
16.1.2 Controlled-Release Fertilizer
16.2 Mechanistic View of Controlled-Release Fertilizer from Bio-based Materials
16.2.1 Coating Type
16.2.2 Matrix Type
16.2.3 Other Release Mechanisms
16.3 Controlled Release Technologies from Bio-based Materials
16.3.1 Natural Polymers and Their Fertilizer Applications
16.3.2 Bio-based Modified Polymer Coatings for Controlled-Release Fertilizer
16.3.3 Biochar and Other Carbon-based Fertilizers
16.4 Conclusion and Foresight
Index
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