Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 9, 2000

1 - Preface to the Series [Seite Preface to the Series ]
Synthetic Methods of Organometallic and Inorganic Chemistry - 5 [Seite 5]
2 - Preface to Volume 9 [Seite 7]
3 - Contents [Seite 8]
4 - Chapter 1: [Seite Chapter 1:]
Alkenyl, Allyl, and Dienyl Complexes of Main Group Elements and Transition Metals - 11 [Seite 11]
4.1 - 1.1 Introduction [Seite 12]
4.2 - 1.2 1-Alkenyl Compounds [Seite 13]
4.2.1 - 1.2.1 General Syntheses of Transition Metal-Vinyl Complexes [Seite 14]
4.2.2 - 1.2.2 Main Group Elements [Seite 17]
4.2.3 - 1.2.3 Transition Metal Compounds [Seite 19]
4.3 - 1.3 Allyl Compounds [Seite 23]
4.3.1 - 1.3.1 Main Group Compounds [Seite 23]
4.3.2 - 1.3.2 Transition Metal Compounds [Seite 29]
4.4 - 1.4 Dienyl Compounds [Seite 53]
4.5 - 1.5 Polyenyl Metal Complexes [Seite 60]
5 - Chapter 2: p [Seite Chapter 2: p]
-Complexes with HeterocyclicLigands - 63 [Seite 63]
5.1 - 2.1 Introduction [Seite 64]
5.2 - 2.2 Pentamethylpyrrole Complexes [Seite 67]
5.3 - 2.3 (. 5-Pyrrolyl)tricarbonylmanganese (Azacymantrene) [Seite 2.3 (. 5-Pyrrolyl)tricarbonylmanganese (Azacymantrene)]
- 69 [Seite 69]
5.4 - 2.4 (.5-Cyclopentadienyl)(. [Seite 2.4 (.5-Cyclopentadienyl)(.]
5-1H-pyrrol-1-y1)fron (Azaferrocene) - 70 [Seite 70]
5.5 - 2.5 2,5-Di-tert.-butyl-l-azacyclopentadienylmetal Complexes [Seite 72]
5.6 - 2.6 . [Seite 2.6 .]
5-Phospholy1 Complexes of Early Transition Metals - 74 [Seite 74]
5.6.1 - 2.6.1 Synthesis of the Phospholyl Precursors [Seite 75]
5.6.2 - 2.6.2 Synthesis of the Phospholyl Complexes [Seite 78]
5.7 - 2.7 4,5-Diphenyl-1,3-Diphospholide Anion and (.5-4,5-Dipheny1-1,3-diphospholy1)(. [Seite 2.7 4,5-Diphenyl-1,3-Diphospholide Anion and (.5-4,5-Dipheny1-1,3-diphospholy1)(.]
5-cyclopentadienyl)iron - 82 [Seite 82]
5.8 - 2.8 2,21 ,5,5'-Tetrakis(trimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-distibaferrocen e [Seite 2.8 2,21 ,5,5'-Tetrakis(trimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-distibaferrocen e]
- 86 [Seite 86]
5.9 - 2.9 Bis(1-tert.-butyl-2-methyl-1H-1,2-azaborolyl)iron and (Wert.-Buty1-2-methy1-1H-1,2-azaborolyl [Seite 2.9 Bis(1-tert.-butyl-2-methyl-1H-1,2-azaborolyl)iron and (Wert.-Buty1-2-methy1-1H-1,2-azaborolyl]
)(dicarbonyl)cobalt - 90 [Seite 90]
6 - Chapter 3: [Seite Chapter 3:]
Complexes of N-Heterocyclic Carbenes - 94 [Seite 94]
6.1 - 3.1 Introduction [Seite 95]
6.2 - 3.2 High-Yielding Synthesis of Functionalized N-Heterocyclic [Seite 3.2 High-Yielding Synthesis of Functionalized N-Heterocyclic ]
Carbenes in Liquid Ammonia - 95 [Seite 95]
6.3 - 3.3 Synthesis of NHC Complexes by a Metalla-Ugi Reaction [Seite 97]
6.4 - 3.4 Nickel(II) Complexes [Seite 98]
6.5 - 3.5 Nickel(0) Complexes [Seite 100]
6.6 - 3.6 Palladium(II) Complexes [Seite 102]
6.7 - 3.7 Immobilization of Pd(II)-NHC Complexes [Seite 107]
6.8 - 3.8 Palladium(0) Complexes [Seite 111]
6.9 - 3.9 Iridium(III) Complexes [Seite 114]
6.10 - 3.10 Ruthenium(II) Complexes [Seite 116]
7 - Chapter 4: [Seite Chapter 4:]
Oxo- and Alkoxy-Complexes - 123 [Seite 123]
7.1 - 4.1 Alkyltrioxometal Compounds [Seite 124]
7.2 - 4.2 Oxohalides of Molybdenum and Tungsten [Seite 127]
7.2.1 - 4.2.1 Tetrachlorooxomolybdenum and -tungsten [Seite 127]
7.2.2 - 4.2.2 Dichlorodioxomolybdenum and -tungsten [Seite 128]
7.2.3 - 4.2.3 Dichlorodioxobis(triphenylphosphane oxide)molybdenum and -tungsten,Dioxotungstenacetylacetonate [Seite 129]
7.3 - 4.3 Trichlorooxotungsten Compounds with Pyridyl Alcoholate Ligands [Seite 131]
7.4 - 4.4 Dioxomolybdenum and -tungsten Compounds with Pyridyl [Seite 4.4 Dioxomolybdenum and -tungsten Compounds with Pyridyl ]
Alcoholate Ligands - 133 [Seite 133]
7.5 - 4.5 Other Complexes with Pyridyl Alcoholate Ligands [Seite 137]
7.5.1 - 4.5.1 Rhenium(V) Complexes [Seite 137]
7.5.2 - 4.5.2 Palladium and Copper Complexes [Seite 140]
7.6 - 4.6 Solvent Adducts of (Dibromo)dioxomolybdenum(VI) [Seite 141]
7.7 - 4.7 Lewis Base Adducts of Dihalodioxomolybdenum(VI) [Seite 144]
7.7.1 - 4.7.1 Dihalo(1,4-di-p-toly1-1,4-diazabuta-1,3-diene)dioxomolybdenum(VI) [Seite 144]
7.7.2 - 4.7.2 (1,4-Di-tert.-buty1-1,4-diazabuta- 1,3-diene)dihalodioxomolybdenum(VI) [Seite 145]
7.7.3 - 4.8 Trigonal Bipyramidal Lewis Base Adducts of Methyltrioxorhenium(VII) [Seite 147]
7.7.3.1 - 4.8.1 Pyridine Adducts of Methyltrioxorhenium [Seite 147]
7.7.3.2 - 4.8.2 Bipyridine Adducts of Methyltrioxorhenium [Seite 148]
8 - Chapter 5: Highly Reduced TantalumCarbonyls Derived from the Hexacarbonyltantalum Anion [Seite 151]
8.1 - 5.1 Hexacarbonyltantalates(1-) [Seite 152]
8.2 - 5.2 Pentacarbonyltantalates(3-) [Seite 155]
8.3 - 5.3 Pentacarbonylhydridotantalates(2-) [Seite 157]
8.4 - 5.4 (Ammine)(pentacarbonyl)tantalates(1-) [Seite 158]
8.5 - 5.5 (tert.-Butyl Isocyanide)(pentacarbonyl)tantalates(1-) [Seite 159]
8.6 - 5.6 (Cyano)(pentacarbonyl)tantalates(2-) [Seite 160]
9 - Chapter 6: Water-Soluble Metal Complexes of Sulfonated Triphenylphosphane [Seite Chapter 6: Water-Soluble Metal Complexes of Sulfonated Triphenylphosphane ]
(TPPTS) - 163 [Seite 163]
9.1 - 6.1 Introduction [Seite 164]
9.2 - 6.2 General Remarks [Seite 165]
9.3 - 6.3 Gel Permeation Chromatography [Seite 165]
9.3.1 - 6.3.1 Apparatus [Seite 165]
9.3.2 - 6.3.2 Column Packing [Seite 167]
9.4 - 6.4 Sulfonated Phosphanes [Seite 168]
9.5 - 6.5 TPPTS-Metal Complexes [Seite 170]
10 - Chapter 7: [Seite Chapter 7:]
Miscellaneous Complexes - 188 [Seite 188]
10.1 - 7.1 (Pentamethylcyclopentadienyl)(phosphane)ruthenium Complexes [Seite 189]
10.2 - 7.2 Ally! and Phosphane Complexes of Palladium [Seite 192]
10.3 - 7.3 A Selection of Important Alkylidene-Metal Complexes [Seite 195]
10.3.1 - 7.3.1 Introduction [Seite 195]
10.3.2 - 7.3.2 Ruthenium-Alkylidene Complexes [Seite 195]
10.3.3 - 7.3.3 Tungsten-Alkylidene Complexes [Seite 197]
10.3.4 - 7.3.4 Ruthenium-Vinylidene- and -Allenylidene Complexes [Seite 199]
10.4 - 7.4 Bisimino Systems (Brookhart/Gibson Systems) [Seite 206]
11 - Index [Seite 213]
12 - List of Transition Metal Complexes in other Volumes [Seite 229]