Basic Organometallic Chemistry

Name: Basic Organometallic Chemistry | Containing Comprehensive Bibliography
Brand: De Gruyter
Price: 149.95 EUR
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Containing Comprehensive Bibliography

Ionel Haiduc Jerry J. Zuckerman(Autor*in)

De Gruyter (Verlag)

1. Auflage

Erschienen am 1. Juni 2011

XVI, 488 Seiten

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978-3-11-084788-8 (ISBN)

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Inhalt

Intro
Part I
1. Introduction
1.1. The Scope of Organometallic Chemistry
1.2. Some Historical Notes
1.3. The Classification of Organometallic Compounds
2. The Metal-Carbon Bond
2.1 Bond Types
Ionic Bonds
Sigma Covalent Bonds (Bicentric Bielectronic)
Electron-Deficient Bonds (Localized Polycentric Bonds)
Delocalized Bonds in Polynuclear Systems
Dative Bonds, with d-Orbital participation (Sigma Donor - Pi Acceptor)
2.2. Metal-Carbon Ionic Bonds
2.3. Sigma (s ) Covalent Bonds (Bicentric Bielectronic)
2.4. Electron-Deficient Bonds (Polycentric Localized-Bonds)
2.5. Delocalized Bonds in Polynuclear Systems
2.6. Dative Bonds with Participation of d-Orbitals
3. Laboratory Techniques in Organometallic Chemistry
3.1. Synthesis and Isolation of Compounds
3.2. Analysis and Structural Characterization
4. The Literature of Organometallic Chemistry
4.1. Textbooks and General Monographs
4.2. Reviews
4.3. Primary Literature
Part II Organometallic Compounds of Non-Transition Elements
5. Organometallic Compounds of Alkali Metals
5.1. Organolithium Compounds
5.2. Organometallic Derivatives of Sodium and the Heavier Alkali Metals
6. Organometallic Compounds of the Group II Elements
6.1. Organoberyllium Compounds
6.2. Organomagnesium Compounds
6.3. Organometallic Compounds of Calcium, Strontium and Barium
6.4. Organozinc Compounds
6.5. Organocadmium Derivatives
6.6. Organomercury Compounds
7. Organometallic Compounds of Group III A Elements
7.1. Organoboron Compounds
7.2. Organoaluminum Compounds
7.3. Organogallium Compounds
7.4. Organoindium Compounds
Trisubstituted Derivatives, InR3
Diorganoindium Halides, R2InX
Organoindium Dihalides, RInX2
7.5. Organothallium Compounds
8. Organometallic Compounds of Group IVA Elements
8.1. Organosilicon Compounds
8.2. Organogermanium Compounds
8.3. Organotin Compounds
8.4. Organolead Compounds
9. Organometallic Compounds of Group VA Elements
9.1. Organoarsenic Compounds
9.2. Organoantimony Compounds
9.3. Organobismuth Compounds
Part III Organometallic Compounds of Transition Metals
10. The Electronic Structure and Classification of Transition-Metal Organometallic Compounds
10.1 The Transition Metals
10.2. The Ligands
11. Compounds with Two-Electron Ligands
11.1. Metal Carbonyls
11.2. Metal Thiocarbonyls
11.3. Metal Selenocarbonyls
11.4. Metal-Isocyanide Complexes
11.5. Metal-Carbene Complexes and Related Compounds
11.6. p -Olefinic Complexes
12. Compounds with Three-Electron Ligands
12.1. p -Allylic Complexes and Related Compounds
Scandium, Lanthanides, Actinides
Titanium, Zirconium, Hafnium
Vanadium, Niobium, Tantalum
Chromium, Molybdenum, Tungsten
Manganese, Technetium, Rhenium
Iron, Ruthenium, Osmium
Cobalt, Rhodium, Iridium
Nickel, Palladium, Platinum
12.2. Cyclopropenyl Complexes
12.3. Metal-Carbyne Complexes
13. Compounds with Four-Electron Ligands
13.1. Butadiene Complexes and Related Compounds
13.2. Cyclobutadiene Complexes
13.3. ? 4-Complexes of Cyclopentadiene, Cyclopentadienone, Fulvene and Heterocycles Derived from Cyclopentadiene
Cyclopentadiene
Cyclopentadienones
Fulvenes
Heterocycles
13.4. Complexes with Other Cyclic Dienes and Polyenes
Cyclohexadiene-1,3
Cycloheptadiene-1,3
Cycloheptatriene-1,3,5
Cyclooctatetrane
13.5. Trimethylenemethyl Complexes
13.6. Boron-Containing Four-Electron Ligands
14. Compounds with Five-Electron Ligands
14.1. Transition Metal, ? 5-Cyclopentadienyl Complexes
Scandium, Yttrium, Lanthanides and Actinides. (Group III Elements)
Titanium, Zirconium, Hafnium
Vanadium, Niobium, Tantalum
Chromium, Molybdenum, Tungsten
Manganese, Technetium, Rhenium
Iron, Ruthenium, Osmium
Cobalt, Rhodium, Iridium
Nickel, Palladium, Platinum
Copper, Silver, Gold
14.2. Acyclic Pentadienyl ? 5-Complexes
14.3. ? 5-Complexes of Some Heterocyclic Ligands
14.4. ? 5-Cyclohexadienyl Complexes
14.5. ? 5-Cycloheptadienyl Complexes
14.6. Complexes of Carborane Ligands
15. Compounds with Six-Electron Ligands
15.1. ? 6-Complexes of Benzene and its Derivatives
Titanium, Zirconium, Hafnium
Vanadium, Niobium, Tantalum
Chromium, Molybdenum, Tungsten
Manganese, Technetium, Rhenium
Iron, Ruthenium, Osmium
Cobalt, Rhodium, Iridium
15.2 ? 6-Cycloheptatriene Complexes
15.3. Cyclooctatriene and Cyclooctatetraene as Six-Electron Ligands
15.4. Some ? 6-Complexes with Heterocyclic Ligands
16. Compounds with Seven- and Eight-Electron Ligands
16.1. Seven-Electron Ligands
16.2. Eight-Electron Ligands
17. Organometallic Compounds Derived from Acetylenes
17.1. Complexes of Untransformed Acetylenes as Terminal (Dihapto) Ligands
Titanium, Zirconium, Hafnium
Vanadium, Niobium, Tantalum
Chromium, Molybdenum, Tungsten
Manganese, Technetium, Rhenium
Iron, Ruthenium, Osmium
Cobalt, Rhodium, Iridium
Nickel, Palladium, Platinum
17.2. Binuclear Complexes with Bridging Acetylene Ligands
17.3. Compounds Incorporating the Acetylene in a Polynuclear Cluster
17.4. Complexes Formed by Chemical Transformations of Acetylenes
18. Organometallic Compounds with s -Metal-Carbon Bonds
Scandium, Yttrium, Lanthanides and Actinides (Group IIIB Elements)
Titanium, Zirconium, Hafnium
Vanadium, Niobium, Tantalum
Chromium, Molybdenum, Tungsten
Manganese, Technetium, Rhenium
Iron, Ruthenium, Osmium
Cobalt, Rhodium, Iridium
Nickel, Palladium, Platinum
Copper, Silver, Gold
Bibliography
Subject Index

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