Spectroscopic Properties of Inorganic and Organometallic Compounds

Name: Spectroscopic Properties of Inorganic and Organometallic Compounds | Volume 5
Brand: Royal Society of Chemistry
Price: 385.99 EUR
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Volume 5

N. N. Greenwood(Herausgeber*in)

Royal Society of Chemistry (Verlag)

1. Auflage

Erschienen am 31. Oktober 2007

630 Seiten

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Spectroscopic Properties Of Inorganic And Organometallic Compounds
Contents
Chapter 1 Nuclear Magnetic Resonance Spectroscopy
1 Introduction
Instrumentation and Techniques
Coupling Constants and Chemical Shifts
Coupling Constants
1H and 19F Chemical Shifts
11B, 13C, 29Si, 14N, and 15N Chemical Shifts
31P Chemical Shifts
Metal Chemical Shifts
2 Stereochemistry
Complexes of Mg, V, Ti, Zr, Hf, Nb, and Ta
Complexes of Cr, Mo, and W
Complexes of Mn and Re
Complexes of Fe, Ru, and Os
Complexes of Co, Rh, and Ir
Complexes of Ni, Pd, and Pt
Complexes of Cu, Au, Zn, Cd, and Hg
3 Dynamic Systems
Rotational and Conformational Exchange
Main-group Compounds
Transition-metal Carbonyls
Other Compounds of Transition Elements
Fluxional Behaviour and Valence Tautomerism
Main-group Compounds
Transition-metal Compounds
Ligand Exchange and Equilibria in Multi-component System
Alkyls and aryls of Be, Mg, Zn, Cd, Hg, Al, and Ga
Other compounds of the main-group elements
Other compounds of the transition metals
Ionic Solutions
Aqueous electrolyte solutions
Non-aqueous electrolyte solutions
4 Paramagnetic Complexes
Compounds of d-Block Transition Elements
Compounds of the Lanthanides and Actinides
5 Solid State N.M.R.
Motion in Solids
Structure of Solids
6 Group III Compounds
Boron Hydrides and Carboranes
Other Compounds of Boron
Complexes of Other Group III Elements
7 Compounds of Silicon, Germanium, Tin, and Lead
Hydride and Organic Derivatives
Nitrogen Derivatives
Other Complexes
8 Compounds of Groups V, VI, VII, and Xenon
Phosphorus-Nitrogen Compounds
Other Phosphorus-containing Compounds
Other Compounds
9 Appendix: Compounds not Referred to in Detail
10 Bibliography
Chapter 2 Nuclear Quadrupole Resonance Spectroscopy
1 Introduction
2 Instrumentation
3 Main Group Elements
Group I (Sodium-23)
Group III (Aluminium-27 and Indium-115)
Group V (Nitrogen-14, Arsenic-75, Antimony-121, and Antimony-123)
Group VII (Chlorine-35, Chlorine-37, Bromine-79, Bromine-81, and Iodine-127
4 Transition Metals and Lanthanides
Manganese-55
Cobalt-59
Copper-63
Lutetium-175
Chapter 3 Microwave Spectroscopy
1 Instrumentation and Techniques
2 Diatomic Molecules
3 Triatomic Molecules
4 Tetra-atomic Molecules
5 Molecules containing Six or More Atoms
6 Other Studies
Chapter 4 Vibrational Spectra
1 General Introduction
2 Spectra of Small Species
Diatomic Molecules, Ions, and Radicals
Triatomic Molecules, Ions, and Radicals
Tetra-atomic Molecules and Ions
Penta-atomic Molecules and Ions
Hexa-atomic Molecules and Ions
Hepta-atomic Molecules and Ions
Larger Molecules and Ions
3 Single-crystal and other Solid State Spectroscopy
'Simple' Lattice Types
Mixed Oxides and Fluorides
Sheet and Chain Structures
Complex Halides
Oxoanion-containing Crystals
Complex Cationic Salts
Complex Anionic Salts
Aquo-complexes
Complex Cyanides
Molecular Crystals
Others
Chapter 5 Characteristic Vibrational Frequencies of Compounds containing Main-group Elements
1 Group I Elements
2 Group II Elements
3 Group III Elements
Compounds containing B-H Bonds
Compounds containing Al-H or Ga-H Bonds
Compounds containing M-C Bonds (M = B, Al, In, or Tl )
Compounds containing M-N Bonds (M = B, Al, Ga, In, or Tl )
Compounds containing M-O Bonds (M = B, Al, Ga, In, or Tl )
Compounds containing M-S Bonds (M = B, In, or Tl) or Tl-Se Bonds
Compounds containing M-Halogen Bonds (M = B, Al, Ga, In, or Tl )
4 Group IV Elements
Compounds containing M-H Bonds (M = Si, Ge, or Sn)
Compounds containing M-C Bonds (M = Si, Ge, Sn, or Pb)
Compounds containing M-M or M-M' Bonds (M,M' = Si, Ge, Sn, or Pb)
Compounds containing Si-N Bonds
Compounds containing Group IV Elements Bonded to P or As
Compounds containing M-O Bonds (M = Si, Ge, Sn, or Pb)
Compounds containing M-S Bonds (M = Si, Ge, or Sn)
Compounds containing M-Halogen Bonds (M = Si, Ge, Sn, or Pb)
5 Group V Elements
Compounds containing E-H Bonds ( E = N, P, or As)
Compounds containing E-C Bonds (E = N, P, As, or Sb)
Compounds containing N-N or N-P Bonds
Compounds containing As-N, Bi-N, or As-As Bonds
Compounds containing E-O Bonds (E = N, P, As, Sb, or Bi)
Compounds containing E-S or P-S Bonds
Other Compounds containing a Group V Element Bonded to a Group VI Element
Compounds containing Group V-Halogen Bonds
6 Group VI Elements
Compounds containing O-H or S-H Bonds
Compounds containing E-C Bonds (E = S, Se, or Te )
Compounds containing O-O, S-O, Se-O, or S-S Bonds
Compounds containing Group VI-Halogen Bonds
7 Group VII Elements
8 Group VIII Elements
Chapter 6 Vibrational Spectra of Transition-element Compounds
1 Introduction
2 Scandium and Yttrium
3 Titanium, Zirconium, and Hafnium
4 Vanadium, Niobium, and Tantalum
5 Chromium, Molybdenum, and Tungsten
6 Manganese and Rhenium
7 Iron, Ruthenium, and Osmium
8 Cobalt, Rhodium, and Iridium
9 Nickel, Palladium, and Platinum
10 Copper, Silver, and Gold
11 Zinc, Cadmium, and Mercury
12 Lanthanides
13 Actinides
Chapter 7 Vibrational Spectra of Some Co-ordinated Ligands
1 Carbon Donors
2 Carbonyls
3 Nitrogen Donors
Molecular Nitrogen, Azido, and Related Complexes
Amines and Related Ligands
Oximes
Ligands containing C=N-groups
Cyanides and Isocyanides
Nitrosyls
4 Phosphorus, Arsenic, and Antimony Donors
5 Oxygen Donors
Molecular Oxygen, Peroxo-, and Hydroxy-complexes
Acetylacetonates and Related Complexes
Carboxylates
Keto-, Alkoxy-, Phenoxy-, and Ether Ligands
O-Bonded Amides and Ureas
Nitrates and Nitrato-complexes
Ligands containing O-N, O-P, or O-As Bonds
Ligands containing O--S or O-Se Bonds
6 Sulphur and Selenium Donors
7 Potentially Ambident Ligands
Cyanate, Thiocyanate Complexes etc., and Isoanalogues
Nitrito- and Nitro-complexes
Other Ligands containing O and N Donor Atoms
Ligands containing O and S Donor Atoms
8 Appendix: Additional References to Metal Carbonyl Complexes
Titanium Carbonyl Complex
Vanadium, Niobium, and Tantalum Carbonyl Complexes
Chromium Carbonyl Complexes
Molybdenum Carbonyl Complexes
Tungsten Carbonyl Complexes
Manganese Carbonyl Complexes
Rhenium Carbonyl Complexes
Iron Carbonyl Complexes
Ruthenium Carbonyl Complexes
Osmium Carbonyl Complexes
Cobalt Carbonyl Complexes
Rhodium Carbonyl Complexes
Iridium Carbonyl Complexes
Nickel Carbonyl Complexes
Platinum Carbonyl Complexes
Copper Carbonyl Complexes
Mixed Transition-metal Carbonyls
Chapter 8 Mössbauer Spectroscopy
1 Introduction
2 Theoretical
3 Instrumentation and Methodology
4 Iron-57
General Topics
NucIear Parameters, Hyperfine Interactions, and New Effects
Pressure-dependence Studies
Lattice Dynamics and Relaxation Phenomena
Alloy-type Systems and Impurity Studies
New 57Co Sources and Decay After-effect Phenomena
Compounds of Iron
High-spin Iron(II) Compounds
High-spin Iron(III) Compounds
Spin-crossover Systems and Biological Compounds
Low-spin and Covalent Comp ounds
Oxide and Sulphide Systems containing Iron
Binary Oxides
Spinel Oxides and Garnets
Other Oxide Systems
Minerals
5 Tin-119
General Topics
Tin(II) Compounds
Tin(IV) Compounds
6 Other Elements
Main-group Elements
Germanium ( 73Ge)
Krypton(83Kr)
Antimony (121Sb)
Tellurium (125Te)
Iodine (127I, 129I)
Transition Elements
Nickel (61Ni)
Ruthenium (99Ru, 101Ru )
Hafnium (177Hf, 178Hf, 180Hf)
Tungsten (180W, 182W, 183W, 184W, 186W)
Tantalum (181Ta)
Iridium (193Ir)
Platinum (195Pt)
Gold (197Au)
Mercury (201Hg)
Lanthanide and Actinide Elements
Praseodymium (141Pr)
Samarium (147Sm, 149Sm
Europium (151Eu, 153Eu)
Dysprosium (161Dy)
Erbium (166Er)
Ytterbium (170Yb, 171Yb, 172Yb, 1 74Yb)
Thorium (232Th)
Neptunium (237Np)
7 Bibliography
Author Index

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