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ABOUT THE AUTHOR
Keith Grainger is a wine writer, educator and consultant in wines and wine technology. His last book Wine Production and Quality, 2nd Edition (with co-author Hazel Tattersall) won the Gourmand Award for the Best Wine Book for Professionals in 25 Years.
ACKNOWLEDGMENTS
PREFACE
INTRODUCTION
CHAPTER 1 Faults, Flaws, Off-Flavours, Taints, and Undesirable Compounds
1.1 Introduction
1.2 Advances in wine technology in recent decades
1.3 Changes in markets and the pattern of wine consumption in recent decades
1.4 The possible impact of some fault compounds upon human health
1.5 Sulfur dioxide and other possible allergens
1.6 Faults and taints
1.7 Distinguishing between faults and flaws
1.8 Sensory detection (perception) thresholds and sensory recognition thresholds
1.9 Consumer Rejection Thresholds (CRTs)
1.10 Basic categories of wine faults
1.11 Flaws
1.12 The incidence of wine faults
1.13 'Faulty' wines that exude excellence
1.14 Final reflections
CHAPTER 2 Wine Tasting
2.1 Introduction
2.2 Anosimics, the Fatigue Effect, and Supertasters
2.3 Tasting conditions, equipment and glassware
2.4 The use of a structured tasting technique, and detection of faults
2.5 Appearance
2.6 Nose
2.7 Palate
2.8 Assessment of Quality
2.9 Assessment of Readiness for drinking/potential for ageing
2.10 Grading wine - the award of points
2.11 Blind tasting
2.12 Final reflections
CHAPTER 3 Chloroanisoles, Bromoanisoles, Halophenols
3.1 Introduction
3.2 Haloanisole contaminations in the food, drinks, water, and pharmaceutical industries
3.3 Haloanisole contamination of wines
3.4 The economic and reputational costs to wine producers and the wine industry
3.5 Sensory characteristics and detection of haloanisoles in wine
3.6 The haloanisoles responsible and their detection thresholds
3.7 The formation pathways of haloanisoles from halophenols
3.8 Contamination of cork with TCA and other chloroanisoles
3.9 The cork industry in the dock
3.10 The cork industry begins to address the issues
3.11 The cork industry's recent initiatives for haloanisole prevention and extraction
3.12 Winery and cooperage sources of haloanisole contamination in wines
3.13 Laboratory analysis for TCA and other haloanisoles in corks and wine
3.14 Prevention of haloanisole contamination of wineries and wines
3.15 Treatment of wines contaminated with haloanisoles
3.16 Chlorophenols and bromophenols as taints
3.17 'Musty' taints unrelated to halophenols and haloanisoles.
3.18 Final reflections
CHAPTER 4 Brettanomyces (Dekkera) and Ethyl phenols
4.1 Introduction
4.2 Background and history
4.3 The Brett Controversy
4.4 Sensory characteristics, and detection of Brettanomyces related compounds in wine
4.5 The origins of Brettanomyces and formation of related compounds in wines
4.6 The danger periods and favourable conditions for the growth of Brettanomyces
4.7 Why are Brettanomyces related compounds found mostly in red wines?
4.8 Prevention - Formulation and implementation a Brett Control Strategy.
4.9 Laboratory Analysis for Brettanomyces and volatile phenols
4.10 Treatment of affected wines
4.11 What the future might hold for microbiological methods to inhibit Brettanomyces?
4.12 Final reflections
CHAPTER 5 Oxidation, Premox and Excessive Acetaldehyde
5.1 Introduction
5.2 Oxidation in must and wine
5.3 Sensory characteristics and detection of excess acetaldehyde and oxidation in wine
5.4 Deliberately oxidised and highly oxygenated wines
5.5 Metal ions and substrates for oxidation
5.6 Enzymatic oxidation
5.7 Chemical oxidation
5.8 Microbial oxidation
5.9 Acetaldehyde
5.10 Sotolon
5.11 Oxygen management in winemaking
5.12 Oxygen uptake during cellar operations
5.13 Containers and closures
5.14 Pinking
5.15 Premature oxidation (Premox)
5.16 Prevention of excess acetaldehyde and oxidation
5.17 Additions of ascorbic acid - antioxidant or oxidising agent?
5.18 Laboratory analysis
5.19 Treatments
5.20 Final Reflections
CHAPTER 6 Excessive sulfur dioxide, volatile sulfur compounds and reduced aromas
6.1. Introduction
6.2 The presence and role of sulfur, sulfur dioxide, sulfite and sulfate in wine production
6.3 Excessive sulfur dioxide
6.4 Oxygen management in winemaking
6.5 Reduction in wine - positive and negative
6.6 Hydrogen sulfide
6.7 Prevention of hydrogen sulfide formation
6.8 Treatment for hydrogen sulfide in wine
6.9 Laboratory analysis for sulfur dioxide, hydrogen sulfide and volatile sulfur compounds
6.10 Final reflections
CHAPTER 7 Excessive volatile acidity and ethyl acetate
7.1 Introduction
7.2 Volatile acidity and ethyl acetate
7.3 The controversy of high levels of volatile acidity
7.4 Fixed acids and volatile acids
7.5 Sensory characteristics and detection of volatile acidity
7.6. Legal limits
7.7 Acetic acid bacteria
7.8 Production of acetic acid in wine
7.9 Ethyl acetate
7.10 Prevention of excessive volatile acidity and ethyl acetate.
7.11 Laboratory analysis
7.12 Treatments
7.13 Final reflections
CHAPTER 8 Atypical ageing (ATA) - sometimes called Untypical ageing (UTA)
8.1 Introduction
8.2 The Atypical Ageing Controversy
8.3 The causes of Atypical Ageing and formation pathways
8.4 Sensory detection
8.5 Laboratory detection
8.6 The main viticultural causes of ATA.
8.7 Prevention
8.8 Treatments
8.9 Final reflections
CHAPTER 9 Fermentation in bottle
9.1 Introduction
9.2 Sensory detection
9.3 Alcoholic fermentation in bottle
9.4 Malolactic fermentation (MLF) in bottle.
9.5 Prevention - preparing wine for bottling and the bottling process
9.6 Treatment
9.7 Final reflections
CHAPTER 10 Hazes
10.1 Introduction
10.2 Protein haze
10.3 Microbial hazes
10.4 Metal hazes
CHAPTER 11 Lactic acid bacteria related faults
11.1 Introduction to lactic acid bacteria
11.2 Lactic acid bacteria and their natural sources
11.3 Malolactic fermentation (MLF)
11.4 Undesirable aromas, off-flavours and wine spoilage caused by Lactic Acid Bacteria
11.5 Prevention of lactic acid bacteria related faults
11.5 Analysis
11.6 Final reflections
CHAPTER 12 Smoke taint and other airborne contaminations
12.1 Introduction
12.2 Smoke taint compounds in the atmosphere
12.3 Critical times in the growing season and duration of exposure for smoke taint to impact
12.4 The volatile phenols responsible for smoke taint; their odours and flavours and sensory detection thresholds
12.5 Smoke taint in wines
12.6 Other sources of guaiacol and 4-methyl-gauaiacol in wines
12.7 Laboratory Testing
12.8 Prevention of development of smoke related volatile phenols from affected grapes
12.9 Treatments.
12.10 Other airborne contaminations
12.11 Final reflections
CHAPTER 13 Ladybeetle and brown marmorated stink bug taints
13.1 Introduction
13.2 Methoxypyrazines
13.3 Ladybeetles (also known as ladybirds and ladybugs)
13.4 Brown marmorated stink bug (Halyomorpha halys) taint
13.5 Final reflections
CHAPTER 14 Sundry faults, contaminants, including undesirable compounds from a health perspective and flaws due to poor balance
14.1 Mycotoxins, particularly Ochratoxin A
14.2 Dibutyl phthalate and other phthalates
14.3 Ethyl Carbamate
14.4 Biogenic amines
14.5 Ethyl sorbate and sorbyl alcohol (geraniol) off-odours
14.6 Paper-taste
14.7 Plastic taints - styrene
14.8 Indole
14.9 Geosmin
14.10 2-bromo-4-methylphenol - iodine, oyster taste
14.11 Heat damage
14.12 Matters of balance
14.13 Final reflections
CHAPTER 15 Faults or not? TDN and tartrate crystals
15.2 Tartrate deposits
15.3 Final reflections
CHAPTER 16 Must correction, wine correction and alcohol reduction using membrane technologies
16.1 Introduction
16.2 Membrane processes used in the wine industry
16.3 Clarification
16.4.3 Cross-flow micro filtration
16.5 Membrane Fouling
16.6 Must correction, wine correction and alcohol reduction using membrane technologies.
16.7 Fault correction
16.8 Wine stabilisation and pH adjustment by electrodialysis
16.9 Final redlections
CHAPTER 17 The impact of container and closure upon wine faults
17.1 Introduction
17.2 Glass bottles
17.3 Bottle closures
17.4 The maintenance of adequate fee and molecular SO2 in bottled wine.
17.5 Natural Cork
17.6 Technical corks, including agglomerated corks
17.7 Diam cork closure
17.8 Synthetic closures
17.9 Screwcaps
17.10 VINOLOK
17.11 Some advantages and disadvantages of various closure types
17.12 The bottling operation
17.12 PET bottles.
17.13 Cans
17.14 Bag-in-box
17.15 Final reflections
CHAPTER 18 Best practice for fault and flaw prevention
18.1 The wine industry
18.2 HACCP
18.3 Standard operating procedures (SOPs)
18.4 Traceability
18.5 Winery design
18.6 Cleaning and sanitation
18.7 Good practice winemaking procedures to avoid spoilage, faults and flaws.
18.8 The use of oenological additions and processing aids
18.9 Routine wine analysis
18.10 Final, final reflections
References
APENDIX
BIBLIOGRAPHY
GLOSSARY
USEFUL WEBSITES
This book comprises a detailed examination of faults, flaws, and taints that can affect the quality and merchantability of wines. Technically, there is a distinction between a taint and fault that will be discussed in Chapter 1. However, wine consumers, merchants, and the press rarely observe such distinction, simply referring to the affected product as faulty. Some faults render affected wines unsaleable and undrinkable. Others that have a negative effect upon quality, enjoyment, or potential for ageing.
There are no reliable figures regarding the total global financial cost of faulty and tainted wines to producers, agents, distributors, and retailers. However, there can be no doubt that it runs into many £/? billions annually. A recent estimate of the economic costs to EU wine producers of haloanisoles taint in wines (so-called 'cork taint') is 700 million euros annually [1]. Product recalls due to matters other than incidences of physical contamination are relatively rare in the wine industry. When bottles of faulty wines do reach the consumer, the impact upon the producers' and suppliers' reputations is incalculable. Although the purchaser may not have the knowledge or skill to identify the fault in question, it is unlikely that they will repurchase any other bottles of the same wine, and may avoid the brand or producer in question. In other words, the consumer will believe the faulty wine to be very low quality. If they have no recourse to financial redress, as will most likely be the case for wines purchased many years previously and which they have been patiently nurturing in their 'cellar' in anticipation of the complex delights of full maturity, consumers may well feel somewhat cheated.
Wine is, without doubt, the most discussed food or drink in the world, and wine lovers readily communicate their experiences to friends, colleagues, and those who share a love for what can be the most exciting and individual of products. Today, such discussions are livelier and more influential than ever. With the proliferation of blogs and social media postings, the opinions of a consumer's peers are, for better or worse, as or even more important than those of professional critics and reviewers. Wine writers, authors, and journalists are generally hugely supportive of the wine industry, without which their profession would not exist. Most are 'deeply in love' with wine, or at least 'fine wine'. However, it is the nature of writing that certain topics become 'hot' and are then developed and pursued for as long as the readership retains an interest. Amongst the wine faults that have received considerable coverage in specialist consumer media in the last decade or two are so-called 'cork taint', 'reduced' aromas (often referred to as reduction or reductivity), premature oxidation (premox), and the aromas produced by Brettanomyces yeasts. When such topics are discussed in a global context, articles can be informative, but they can also weaken confidence and influence buying habits. However, if the coverage relates to individual producers, the damage inflicted can be both instant and ongoing. Reputational damage may be done simply by naming faulty wines submitted for assessment at comparative tastings conducted by specialist magazines, or for tasting competitions. By way of example, during the early years of this century, the influential USA published magazine Wine Spectator revealed the identity and details of several 'high-end' Californian producers who had marketed wines tainted by 2,4,6-trichloroanisole (TCA) and 2,4,6-tribromoanisole (2,4,6-TBA). These compounds are usually, and particularly in the case of 2,4,6-TBA erroneously, referred to as 'cork taint'. The negative impact upon the reputations of producers that had taken decades to build is apparent.
On the other hand, there are 'under the radar' faults that are seldom discussed in the popular wine media or amongst professionals. A prime example is 'atypical ageing', by which white wines very rapidly lose varietal character and develop undesirable aroma and palate characteristics. This fault, often confused with premature oxidation, has been described as 'one of the most serious quality problems in white wine making in nearly all wine producing countries' [2]. It has been estimated that up to 20% of USA wines might be affected [3].
The financial impact upon producers and distributors who have sold faulty product can be immediate and direct. Supermarkets and merchants impose chargebacks upon suppliers when customers return wines. On an individual basis, this may be the cost of the bottle in question, the cost of analysis of other bottles, the cost of replacement bottles and a 'fine', or service handling fee. On a volume basis, the trade customer may demand reimbursement for pallets or even containers of affected wine, shipping and warehouse costs, handling, and possibly also excise duties which, in some countries, can amount to several times the value of the wine in question. If there are problems with subsequent shipments, the merchant may well blacklist the producer or supplier. The longer-term financial impact can be massive. For example, winery contamination with haloanisoles has, on occasions, necessitated the destruction and rebuilding of cuveries and chais, as discussed in Chapter 3.
In Chapters 3-14, I discuss in detail individual categories of wine faults. I do not claim the list of faults included to be exhaustive. The discussion of each fault generally includes:
The 'history' of the individual faults is also covered. Throughout the book, particularly Chapter 18, there is a general discussion of the implementation of what constitutes good procedures and practices in the vineyard and winery to enhance quality and minimise the likelihood of faults from occurring. Carrying out audits of premises, equipment, and inventory to identify microbial or chemical contamination can be costly and taking steps to address issues identified even more so. The cost of being unaware of problems, or doing nothing to rectify them, is incalculable. I am acutely aware of budget constraints that are an everyday challenge, particularly to the small producer, and such implementation may be generally achieved at minimum expense. Information on the identification of faults by laboratory analysis, and how faults may be rectified is given in general terms. However, producers seeking to address specific issues are advised to seek advice from any of the laboratories, consultants, and companies specialising in the identification and treatment of oenological problems. It is the responsibility of producers to check the legality of any method suggested, or the addition of any oenological products, in the country/region of production and market.
There are several challenges posed in undertaking any discussion of wine faults and flaws. These include matters of definitions, boundaries, concentrations, and the matrices of individual wines. From a sensory perspective, determining when a microbial or chemical issue is a fault is not necessarily straightforward. In addition to the issue of a taster's sensory detection thresholds, there can often be a dispute whether a particular characteristic is perceived as beneficial, harmless, a flaw or a fault. These perceptions are even subject to the vagaries of fashion. In 1982, Master of Wine and Burgundy expert Anthony Hanson wrote in the first edition of his critically acclaimed book Burgundy: 'great Burgundy smells of shit' [4]. If there were any raised eyebrows at the time, these were only because of Hanson's choice of language.
Indeed many Burgundies exuded the odours of stables and farmyards. By 1995, Hanson was already finding such a nose objectionable and blamed microbial activity [5]. We now know that these odours have nothing to do with Pinot Noir (the variety from which pretty much all red Burgundy is made). Nor do they stem from any of the myriads of Burgundy terroirs, but result from volatile phenols and other compounds produced by the yeast Brettanomyces (or to be technically correct Dekkera although it is rarely so-called in the wine industry). Today, Brettanomyces is generally regarded in the wine industry as a rogue yeast, and odours of farmyards, stables, or BAND-AID® are generally considered to be undesirable and regarded by most winemakers, oenologists, and critics to be a fault. This means that aromas in 1982 regarded by an expert taster as a sign of quality are today usually seen as a fault. However, Brettanomyces (often referred to as 'Brett') remains a controversial topic. Many producers, critics, and wine lovers believe it can, at low levels, add complexity to a wine. This poses the question as to where the boundary should be drawn. Purists perceive Brett always to be a fault and define it as such. Some lovers of 'natural' wines consider it to be one of nature's...
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