The lead-acid accumulator was introduced in the middle of the19th Century, the diverse variants of nickel accumulators betweenthe beginning and the end of the 20th Century. Although old, thesetechnologies are always very present on numerous markets.Unfortunately they are still not used in optimal conditions, oftenbecause of the misunderstanding of the internal electrochemicalphenomena.
This book will show that batteries are complex systems, madecommercially available thanks to considerable amounts of scientificresearch, empiricism and practical knowledge. However, the designof batteries is not fixed; it is subject to constant developmentsas a result of user feedback and validation processes which areoften long and fastidious. This book attempts to show that it isnot possible to consider a family of batteries as having fixed,applicable properties and characteristics whatever the applicationand the technology used in their manufacture. For this reason, theauthors have chosen to present the fundamental electrochemical andchemical phenomena involved in as simple and as clear a way aspossible. It is essential to be aware of these mechanisms in orderto develop suitable theoretical models.
This work will be of particular interest to those working in thefield of electrical engineering and to industrialists, the finalusers of these technologies. It will also be of interest toelectrochemists, as experts in lead or nickel batteries arebecoming fewer and farther between, and their knowledge andpractical skills are steadily being lost.
Contents
Part 1. Universal Characteristics of Batteries
1. Definitions and Methods of Measurement.
Part 2. Lead-Acid Batteries
2. The Operation of Lead-Acid Batteries.
3. Internal Composition and Types of Lead-AcidBatteries.
4. Lead Batteries: Main Characteristics.
5. Manufacturing Starting, Lighting and Ignition Batteries.
Part 3. Introduction to Nickel-Based Batteries
6. Nickel-Cadmium Batteries.
7. Nickel-Metal Hydride Batteries.
8. Other Nickel-Based Batteries.
Auflage
Sprache
Verlagsort
Verlagsgruppe
Produkt-Hinweis
Dateigröße
ISBN-13
978-1-118-56312-0 (9781118563120)
Schweitzer Klassifikation
Preface xv
Acknowledgments xvii
Introduction xix
PART 1. UNIVERSAL CHARACTERISTICS OF BATTERIES 1
Chapter 1. Definitions and Methods of Measurement 3
1.1. Introduction 3
1.2. Terminology 3
1.3. Definitions of characteristics 7
1.4. Battery states 20
1.5. Faradic efficiency 32
1.6. Charge coefficient 34
1.7. Overcharge coefficient 34
1.8. Energy efficiency 34
1.9. Self-discharge 36
1.10. Acceptance current 37
1.11. Conclusion 37
1.12. Appendix: Nernst's law 38
1.13. Solutions to exercises 48
PART 2. Lead-ACID BATTERIES 55
Chapter 2. The Operation of Lead-Acid Batteries59
2.1. Principles of operation 59
2.2. Properties due to electrochemical reactions 80
2.3. Polarity inversion 96
2.4. Effects of temperature, aging and thermal runaway 97
2.5. Failure modes 100
2.6. Appendices 107
2.7. Solutions to exercises 110
Chapter 3. Internal Composition and Types of Lead-AcidBatteries 115
3.1. Composition of lead-acid batteries 115
3.2. Families of lead-acid batteries 126
3.3. Other battery types and future prospects 132
Chapter 4. Lead Batteries: Main Characteristics 135
4.1. Introduction 135
4.2. Electrical characteristics 135
4.3. Charge of lead batteries 149
4.4. Energy management 155
4.5. SOC indicator 156
4.6. Conditions of use 162
4.7. Economic considerations 171
4.8. Applicable standards 174
4.9. Future developments 175
4.10. To find out more 176
4.11. Solutions to exercises 176
Chapter 5. Manufacturing Starting, Lighting and IgnitionBatteries 181
5.1. Introduction 181
5.2. Manufacturing an SLI battery 182
5.3. Raw materials 184
5.4. Different ways of manufacturing lead SLI batteries 189
5.5. Composition of the paste 201
5.6. Pasting the grids 204
5.7. Curing of the plates 204
5.8. Assembly 209
5.9. Formation of the battery 218
5.10. Final test and dispatch 225
5.11. Solutions to exercises 225
PART 3. INTRODUCTION TO NICKEL-BASED BATTERIES 227
Chapter 6. Nickel-Cadmium Batteries 229
6.1. Introduction 229
6.2. Operating principle 230
6.3. Main characteristics 236
Chapter 7. Nickel-Metal Hydride Batteries 251
7.1. Introduction 251
7.2. Operating principle 252
7.3. Main characteristics 256
7.4. Solution to exercise 271
Chapter 8. Other Nickel-Based Batteries 273
8.1. Introduction 273
8.2. Nickel-iron batteries 273
8.3. Nickel-zinc batteries 277
8.4. More information on nickel-based batteries 286
8.4.1. Resources and properties of nickel 286
8.4.2. Recycling channels for nickel-based batteries 286
8.4.3. Bibliography 287
Conclusion 289
Index 291
