Fundamentals of Molecular Catalysis

Name: Fundamentals of Molecular Catalysis
Brand: Elsevier
Price: 255.0 EUR
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Elsevier (Verlag)

Erschienen am 2. April 2003

536 Seiten

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978-0-08-053213-4 (ISBN)

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Inhalt

Cover
Fundamentals of Molecular Catalysis
Copyright
Contents
Preface
List of Contributors
Chapter 1 General Introduction
1.1 Introduction
1.2 Elucidation of catalytic mechanisms as cycles composed of elementary steps
1.3 Comments on elementary processes involved in metal-catalyzed organic synthesis
1.4 Catalytic cycles constituted of multiple components of elementary processes
1.5 Other relevant aspects
1.6 Further prospects
1.7 References
Chapter 2 Activation of Substrates with Non-Polar Single Bonds
2.1 Significance of the area
2.2 Activation pathways
2.3 s bond complexes
2.4 Non-polar s bond activation
2.5 Conclusion
2.6 References
Chapter 3 Activation of Substrates with Polar Single Bonds
3.1 Introduction
3.2 Carbon-halogen bond cleavage reactions
3.3 Carbon-oxygen bond cleavage reactions
3.4 Carbon-sulfur bond cleavage reactions
3.5 Recent developments on other polar single bond cleavage
3.6 Summary
3.7 References
Chapter 4 Transition Metal-Carbene Complexes in Olefin Metathesis and Related Reactions
4.1 Scope
4.2 Classification of transition metal-carbene complexes
4.3 Reactivity of transition metal-carbene complexes
4.4 Olefin metathesis
4.5 Catalysts for olefin metathesis
4.6 Conclusions
4.7 References
Chapter 5 Transmetalation
5.1 Introduction
5.2 Organic ligand transfer from main group metal to transition metal
5.3 Organic ligand transfer between transition metals
5.4 Transmetalation of main group metal compounds
5.5 Summary
5.6 References
Chapter 6 1,2-Insertion and ß-Elimination
6.1 Introduction
6.2 Insertion of alkenes into M-H or M-C bonds
6.3 Insertion of other substrates into M-H and M-C bonds
6.4 Insertion into other M-E bonds
6.5 References
Chapter 7 1,1-Insertion into Metal-Carbon Bond
7.1 Introduction
7.2 CO insertion
7.3 Isocyanide insertion
7.4 SO2 insertion
7.5 a-Elimination and 1,1-insertion involving alkylidene ligands
7.6 References
Chapter 8 Addition to Unsaturated Ligands
8.1 Introduction
8.2 Nucleophilic attack at coordinated ligand
8.3 Electrophilic attack at coordinated ligand
8.4 Radical attack at coordinated ligand
8.5 Summary
8.6 References
Chapter 9 Reductive Elimination
9.1 Introduction
9.2 Reductive elimination from d8 cis-MR(R' )L2 complexes
9.3 Reductive elimination from d8 trans-MR(R' )L2 complexes
9.4 Reductive elimination from d8 p-allyl complexes
9.5 Reductive elimination from d6 metal complexes
9.6 Reductive elimination from other metal complexes
9.7 References
Subject index

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