1 - Science of Synthesis: Knowledge Updates 2012/4 [Seite 1]
1.1 - Title page [Seite 5]
1.2 - Imprint [Seite 7]
1.3 - Preface [Seite 8]
1.4 - Abstracts [Seite 10]
1.5 - Overview [Seite 16]
1.6 - Table of Contents [Seite 18]
1.7 - Volume 1: Compounds with Transition Metal--Carbon p-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) [Seite 30]
1.7.1 - 1.2 Product Class 2: Organometallic Complexes of Palladium [Seite 30]
1.7.1.1 - 1.2.5 Product Subclass 5: Palladium(III)-Containing Complexes [Seite 30]
1.7.1.1.1 - 1.2.5.1 Synthesis of Palladium(III)-Containing Complexes [Seite 30]
1.7.1.1.1.1 - 1.2.5.1.1 Mononuclear Palladium(III) Complexes [Seite 30]
1.7.1.1.1.1.1 - 1.2.5.1.1.1 Method 1: Disproportionation of Palladium(II) Complexes [Seite 31]
1.7.1.1.1.1.2 - 1.2.5.1.1.2 Method 2: Oxidation of Palladium(II) Complexes with Perchloric Acid [Seite 31]
1.7.1.1.1.1.3 - 1.2.5.1.1.3 Method 3: Electrochemical Oxidation of Palladium(II) Complexes [Seite 32]
1.7.1.1.1.1.4 - 1.2.5.1.1.4 Method 4: Oxidation of Palladium(II) with Single-Electron Oxidants [Seite 33]
1.7.1.1.1.1.5 - 1.2.5.1.1.5 Method 5: Oxidation of Palladium(II) Complexes with Oxygen [Seite 33]
1.7.1.1.1.2 - 1.2.5.1.2 Binuclear Palladium(III) Complexes without a Pd--Pd Bond [Seite 34]
1.7.1.1.1.2.1 - 1.2.5.1.2.1 Method 1: Electrochemical Oxidation [Seite 34]
1.7.1.1.1.2.2 - 1.2.5.1.2.2 Method 2: Comproportionation of Palladium(II) and Palladium(IV) Complexes [Seite 35]
1.7.1.1.1.3 - 1.2.5.1.3 Binuclear Palladium(2.5) Complexes with a Pd--Pd Bond Order of 0.5 [Seite 36]
1.7.1.1.1.3.1 - 1.2.5.1.3.1 Method 1: Binuclear Palladium(2.5) Complexes by Electrochemical Oxidation [Seite 36]
1.7.1.1.1.3.2 - 1.2.5.1.3.2 Method 2: Binuclear Palladium(2.5) Complexes Using Single-Electron Oxidants [Seite 37]
1.7.1.1.1.4 - 1.2.5.1.4 Tetrabridged Binuclear Palladium(III) Complexes with a Pd--Pd Bond [Seite 38]
1.7.1.1.1.4.1 - 1.2.5.1.4.1 Method 1: Binuclear Palladium(III) Complexes by Oxidation with Hypervalent Iodine [Seite 38]
1.7.1.1.1.4.2 - 1.2.5.1.4.2 Method 2: Inorganic Binuclear Palladium(III) Complexes via Ligand Metathesis [Seite 39]
1.7.1.1.1.4.3 - 1.2.5.1.4.3 Method 3: Organometallic Tetrabridged Binuclear Palladium(III) Complexes [Seite 39]
1.7.1.1.1.5 - 1.2.5.1.5 Binuclear Palladium(III) Complexes Supported by Two Bridging Ligands [Seite 41]
1.7.1.1.1.5.1 - 1.2.5.1.5.1 Method 1: Oxidation with Hypervalent Iodine Reagents [Seite 41]
1.7.1.1.1.5.2 - 1.2.5.1.5.2 Method 2: Oxidation with Peroxides [Seite 42]
1.7.1.1.1.5.3 - 1.2.5.1.5.3 Method 3: Oxidation with Halogens [Seite 42]
1.7.1.1.1.6 - 1.2.5.1.6 Unbridged Pd(III)--Pd(III) Bonds [Seite 43]
1.7.1.1.1.6.1 - 1.2.5.1.6.1 Method 1: Oxidation of Acetate-Bridged Binuclear Palladium(III) Complexes with Xenon Difluoride [Seite 43]
1.7.1.1.2 - 1.2.5.2 Stoichiometric Organometallic Chemistry of Isolated Palladium(III) Complexes [Seite 45]
1.7.1.1.2.1 - 1.2.5.2.1 Organometallic Chemistry of Mononuclear Palladium(III) Complexes [Seite 45]
1.7.1.1.2.1.1 - 1.2.5.2.1.1 Method 1: C--C Bond-Forming Reactions of Mononuclear Palladium(III) Complexes [Seite 45]
1.7.1.1.2.1.2 - 1.2.5.2.1.2 Method 2: C--C Bond-Forming Reactions Initiated by Ligation of Anionic Donors [Seite 47]
1.7.1.1.2.2 - 1.2.5.2.2 Organometallic Chemistry of Binuclear Palladium(III) Complexes [Seite 48]
1.7.1.1.2.2.1 - 1.2.5.2.2.1 Method 1: C--X Bimetallic Reductive Elimination from Binuclear Palladium(III) Complexes [Seite 48]
1.7.1.1.3 - 1.2.5.3 Organometallic Reactions Proposed To Proceed via Unobserved Mononuclear Palladium(III) Intermediates [Seite 48]
1.7.1.1.3.1 - 1.2.5.3.1 Method 1: C--C Bond-Forming Reactions Initiated by One-Electron Oxidation of Mononuclear Palladium(II) Complexes [Seite 48]
1.7.1.1.3.2 - 1.2.5.3.2 Method 2: Oxygen-Insertion Reactions [Seite 49]
1.7.1.1.4 - 1.2.5.4 Binuclear Palladium(III) in the Synthesis of Mononuclear Palladium(IV) Complexes [Seite 51]
1.7.1.1.4.1 - 1.2.5.4.1 Method 1: Pd--Pd Heterolysis in Trifluoromethylation [Seite 51]
1.7.1.1.4.2 - 1.2.5.4.2 Method 2: Heterolysis of Unbridged Pd(III)--Pd(III) Bonds [Seite 52]
1.7.1.1.5 - 1.2.5.5 Proposed Catalysis via Mononuclear Palladium(III) Intermediates [Seite 53]
1.7.1.1.5.1 - 1.2.5.5.1 Method 1: Kharasch Reaction [Seite 53]
1.7.1.1.6 - 1.2.5.6 Catalysis via Proposed Binuclear Palladium(III) Intermediates [Seite 54]
1.7.1.1.6.1 - 1.2.5.6.1 Method 1: Binuclear Palladium(III) Intermediates in C--H Arylation [Seite 54]
1.7.1.1.6.2 - 1.2.5.6.2 Method 2: Binuclear Palladium(III) Intermediates in C--H Chlorination [Seite 54]
1.7.1.1.6.3 - 1.2.5.6.3 Method 3: Binuclear Palladium(III) Complexes in C--H Acetoxylation [Seite 55]
1.7.1.1.6.4 - 1.2.5.6.4 Method 4: C--N Bond-Forming Reactions Initiated by One-Electron Oxidants [Seite 56]
1.7.1.1.6.5 - 1.2.5.6.5 Method 5: Binuclear Catalysts for C--H Hydroxylation Chemistry [Seite 57]
1.7.1.1.7 - 1.2.5.7 Binuclear Palladium(III) Precatalysts [Seite 58]
1.7.1.1.7.1 - 1.2.5.7.1 Method 1: Alkene Diboration [Seite 58]
1.8 - Volume 2: Compounds of Groups 7-3 (Mn···, Cr···, V···, Ti···, Sc···, La···, Ac···) [Seite 62]
1.8.1 - 2.10 Product Class 10: Organometallic Complexes of Titanium [Seite 62]
1.8.1.1 - 2.10.20 Organometallic Complexes of Titanium (Update 2) [Seite 62]
1.8.1.1.1 - 2.10.20.1 Titanium-Mediated Reductive Cross-Coupling Reactions (Intermolecular Metallacycle-Mediated C--C Bond Formation) [Seite 62]
1.8.1.1.1.1 - 2.10.20.1.1 Method 1: Synthesis of Allylic Alcohols by Alkoxide-Directed Regioselective Coupling of Internal Alkynes with Aldehydes (Class I) [Seite 65]
1.8.1.1.1.2 - 2.10.20.1.2 Method 2: Synthesis of Trisubstituted E-1,3-Dienes by Alkoxide-Directed Regioselective Coupling of Internal Alkynes with Terminal Alkynes (Class I) [Seite 71]
1.8.1.1.1.3 - 2.10.20.1.3 Method 3: Synthesis of Tetrasubstituted 1,3-Dienes by Alkoxide-Directed Regioselective Cross-Coupling Reactions of Internal Alkynes (Class II) [Seite 75]
1.8.1.1.1.4 - 2.10.20.1.4 Method 4: Titanium Alkoxide Mediated Alkene-Alkyne Cross Coupling (Class II) [Seite 78]
1.8.1.1.1.5 - 2.10.20.1.5 Method 5: Titanium Alkoxide Mediated Allylic Alcohol-Alkyne Cross Coupling (Class II) [Seite 82]
1.8.1.1.1.6 - 2.10.20.1.6 Method 6: Alkoxide-Directed Coupling of Allylic Alcohols with Vinylsilanes (Class II) [Seite 91]
1.8.1.1.1.7 - 2.10.20.1.7 Method 7: Alkoxide-Directed Coupling of Imines with Internal Alkynes (Class II) [Seite 93]
1.8.1.1.1.8 - 2.10.20.1.8 Method 8: Alkoxide-Directed Coupling of Imines with Alkenes (Class II) [Seite 97]
1.8.1.1.1.9 - 2.10.20.1.9 Method 9: Alkoxide-Directed Coupling of Imines with Allylic Alcohols (Class II) [Seite 108]
1.8.1.1.1.10 - 2.10.20.1.10 Method 10: Allenes in Alkoxide-Directed Titanium-Mediated Reductive Cross Coupling (Class II) [Seite 116]
1.8.1.1.1.11 - 2.10.20.1.11 Method 11: Alkoxide-Directed Coupling of Vinylcyclopropanes with Silyl-Substituted Ethene and Alkynes (Class II) [Seite 121]
1.8.1.1.1.12 - 2.10.20.1.12 Method 12: Titanium-Mediated Cyclopropanation of Vinylogous Esters (Class I Alkoxide-Directed Reductive Cross Coupling) [Seite 122]
1.8.2 - 2.13 Product Class 13: Organometallic Complexes of the Actinides [Seite 128]
1.8.2.1 - 2.13.1 Product Subclass 1: Actinide-Cyclooctatetraene Complexes [Seite 129]
1.8.2.1.1 - Synthesis of Product Subclass 1 [Seite 129]
1.8.2.1.1.1 - 2.13.1.1 Method 1: Metathesis with Alkali Metal Salts [Seite 129]
1.8.2.1.1.2 - 2.13.1.2 Method 2: Transmetalation with Magnesium Salts [Seite 131]
1.8.2.1.1.3 - 2.13.1.3 Method 3: Electrolytic Amalgamation [Seite 131]
1.8.2.1.1.4 - 2.13.1.4 Method 4: Reduction with Lithium Naphthalenide [Seite 132]
1.8.2.1.1.5 - 2.13.1.5 Method 5: Redistribution [Seite 132]
1.8.2.1.1.6 - 2.13.1.6 Method 6: Cyclooctatetraene-Bridged Actinide Complexes [Seite 133]
1.8.2.1.2 - Applications of Product Subclass 1 in Organic Synthesis [Seite 134]
1.8.2.1.2.1 - 2.13.1.7 Method 7: Binding of Carbon Monoxide [Seite 134]
1.8.2.2 - 2.13.2 Product Subclass 2: Actinide-Arene Complexes [Seite 136]
1.8.2.2.1 - Synthesis of Product Subclass 2 [Seite 136]
1.8.2.2.1.1 - 2.13.2.1 Method 1: Friedel-Crafts Route [Seite 136]
1.8.2.2.1.2 - 2.13.2.2 Method 2: Synthesis of Bimetallic Species [Seite 137]
1.8.2.2.1.3 - 2.13.2.3 Method 3: Thermolysis of Uranium(IV) Borohydride [Seite 137]
1.8.2.2.1.4 - 2.13.2.4 Method 4: Synthesis of Bridged Uranium-Arene Complexes by Salt Metathesis [Seite 138]
1.8.2.3 - 2.13.3 Product Subclass 3: Actinide-Cyclopentadienyl Complexes [Seite 139]
1.8.2.3.1 - Synthesis of Product Subclass 3 [Seite 142]
1.8.2.3.1.1 - 2.13.3.1 Method 1: Metathesis with Alkali Metal Salts [Seite 142]
1.8.2.3.1.2 - 2.13.3.2 Method 2: Transmetalation [Seite 143]
1.8.2.3.1.3 - 2.13.3.3 Method 3: Reduction of Tetravalent Actinide Precursors [Seite 144]
1.8.2.3.1.3.1 - 2.13.3.3.1 Variation 1: Reduction with Sodium Hydride [Seite 144]
1.8.2.3.1.3.2 - 2.13.3.3.2 Variation 2: Reduction with Alkali Metals [Seite 145]
1.8.2.3.1.4 - 2.13.3.4 Method 4: Reaction with Tetramethylfulvene [Seite 146]
1.8.2.3.2 - Applications of Product Subclass 3 in Organic Synthesis [Seite 147]
1.8.2.3.2.1 - 2.13.3.5 Method 5: Catalytic Reduction of Azides and Hydrazines [Seite 147]
1.8.2.3.2.2 - 2.13.3.6 Method 6: Intermolecular Hydroamination of Terminal Alkynes [Seite 148]
1.8.2.3.2.3 - 2.13.3.7 Method 7: Hydrosilylation of Terminal Alkynes [Seite 150]
1.8.2.3.2.4 - 2.13.3.8 Method 8: Polymerization of a-Alkenes [Seite 152]
1.8.2.3.2.5 - 2.13.3.9 Method 9: C--H Bond Activation [Seite 153]
1.8.2.4 - 2.13.4 Product Subclass 4: Allyl- and Pentadienylactinide Complexes [Seite 154]
1.8.2.4.1 - Synthesis of Product Subclass 4 [Seite 155]
1.8.2.4.1.1 - 2.13.4.1 Method 1: Transmetalation with Grignard Reagents [Seite 155]
1.8.2.4.1.2 - 2.13.4.2 Method 2: Metathesis with Alkali Metal Salts [Seite 156]
1.8.2.5 - 2.13.5 Product Subclass 5: Alkylactinide Complexes [Seite 156]
1.8.2.5.1 - Synthesis of Product Subclass 5 [Seite 157]
1.8.2.5.1.1 - 2.13.5.1 Method 1: Metathesis with Alkali Metal Salts [Seite 157]
1.8.2.5.1.2 - 2.13.5.2 Method 2: Application of Stabilizing Phosphine Ancillary Ligands [Seite 157]
1.8.2.6 - 2.13.6 Product Subclass 6: Actinide-Carbene Complexes [Seite 158]
1.8.2.6.1 - Synthesis of Product Subclass 6 [Seite 159]
1.8.2.6.1.1 - 2.13.6.1 Method 1: Metathesis with Alkali Metal Salts [Seite 159]
1.8.2.6.1.2 - 2.13.6.2 Method 2: Ligand Redistribution [Seite 160]
1.8.2.7 - 2.13.7 Product Subclass 7: Oxygen-Ligand Complexes of Actinide Systems [Seite 161]
1.8.2.7.1 - Synthesis of Product Subclass 7 [Seite 161]
1.8.2.7.1.1 - 2.13.7.1 Method 1: Ligand Substitution [Seite 161]
1.8.2.7.1.1.1 - 2.13.7.1.1 Variation 1: Nucleophilic Displacement of Halides [Seite 161]
1.8.2.7.1.1.2 - 2.13.7.1.2 Variation 2: By Ligand Redistribution [Seite 162]
1.8.2.7.2 - Applications of Product Subclass 7 in Organic Synthesis [Seite 164]
1.8.2.7.2.1 - 2.13.7.2 Method 2: Molecular Nitrogen Reduction [Seite 164]
1.8.2.8 - 2.13.8 Product Subclass 8: Nitrogen-Ligand Complexes of Actinide Systems [Seite 165]
1.8.2.8.1 - Synthesis of Product Subclass 8 [Seite 165]
1.8.2.8.1.1 - 2.13.8.1 Method 1: Formation of Actinide Amide Complexes [Seite 165]
1.8.2.8.1.1.1 - 2.13.8.1.1 Variation 1: Homoleptic Actinide Amide Formation by Nucleophilic Halide Displacement [Seite 165]
1.8.2.8.1.1.2 - 2.13.8.1.2 Variation 2: Heteroleptic Actinide Amide Synthesis by Nucleophilic Halide Displacement [Seite 167]
1.8.2.8.1.1.3 - 2.13.8.1.3 Variation 3: Reaction of Organoactinide Species with Nitriles and Thiocyanates [Seite 170]
1.8.2.8.1.2 - 2.13.8.2 Method 2: Formation of Actinide Imides [Seite 173]
1.8.2.8.1.2.1 - 2.13.8.2.1 Variation 1: By Oxidation of the Actinide Center [Seite 173]
1.8.2.8.1.2.2 - 2.13.8.2.2 Variation 2: By Reductive Cleavage with Amines and Hydrazines [Seite 175]
1.8.2.8.1.2.3 - 2.13.8.2.3 Variation 3: By Reductive Cleavage with Azides and Diazenes [Seite 176]
1.8.2.8.1.3 - 2.13.8.3 Method 3: Synthesis of Actinide Amidinate Complexes [Seite 178]
1.8.2.8.1.3.1 - 2.13.8.3.1 Variation 1: By Reaction of Actinide Halides with Lithium Amidinates [Seite 178]
1.8.2.8.1.3.2 - 2.13.8.3.2 Variation 2: By Carbodiimide Insertion [Seite 180]
1.8.2.8.1.4 - 2.13.8.4 Method 4: Synthesis of Actinide Complexes Bearing N-Heterocyclic Ligands [Seite 182]
1.8.2.8.1.4.1 - 2.13.8.4.1 Variation 1: Actinide Complexes Bearing Pyrrolyl Ligands and Polypyrrole Macrocycles [Seite 182]
1.8.2.8.1.4.2 - 2.13.8.4.2 Variation 2: Organoactinide Complexes Bearing Pyrazole and Imidazole Functionality [Seite 184]
1.8.2.8.1.4.3 - 2.13.8.4.3 Variation 3: Pyridine-Stabilized Organoactinide Systems [Seite 185]
1.8.2.8.1.5 - 2.13.8.5 Method 5: Actinide Complexes Bearing Ketimide Ligands [Seite 187]
1.8.2.8.2 - Applications of Product Subclass 8 in Organic Synthesis [Seite 188]
1.8.2.8.2.1 - 2.13.8.6 Method 6: Binding of Carbon Dioxide [Seite 188]
1.8.2.8.2.2 - 2.13.8.7 Method 7: Oligomerization of e-Caprolactone [Seite 189]
1.8.2.8.2.3 - 2.13.8.8 Method 8: Dehydrogenative Coupling of Amines with Silanes [Seite 190]
1.8.2.8.2.4 - 2.13.8.9 Method 9: Catalytic Hydrosilylation of Alkynes [Seite 191]
1.8.2.8.2.5 - 2.13.8.10 Method 10: Binding of Molecular Nitrogen [Seite 192]
1.8.2.8.2.6 - 2.13.8.11 Method 11: Alkene Polymerization [Seite 193]
1.8.2.9 - 2.13.9 Product Subclass 9: Sulfur- and Phosphorus-Ligand Complexes of Actinide Systems [Seite 194]
1.8.2.9.1 - Synthesis of Product Subclass 9 [Seite 194]
1.8.2.9.1.1 - 2.13.9.1 Method 1: Synthesis of Organoactinide Complexes Bearing Sulfur Ligands [Seite 194]
1.8.2.9.1.1.1 - 2.13.9.1.1 Variation 1: Formation of Actinide Thiolate Complexes by Coordinative Insertion [Seite 194]
1.8.2.9.1.1.2 - 2.13.9.1.2 Variation 2: Formation of Actinide Thiolate Complexes by Nucleophilic Halide Displacement [Seite 195]
1.8.2.9.1.2 - 2.13.9.2 Method 2: Synthesis of Organoactinide Complexes Bearing Phosphorus Ligands [Seite 196]
1.8.2.9.1.2.1 - 2.13.9.2.1 Variation 1: Formation of Actinide-Phospholyl Complexes [Seite 196]
1.8.2.9.1.2.2 - 2.13.9.2.2 Variation 2: Reactions Forming Actinide-Phosphine Complexes [Seite 197]
1.8.2.9.1.2.3 - 2.13.9.2.3 Variation 3: Reactions Forming Actinide-Phosphine Oxide Complexes [Seite 198]
1.8.2.9.1.2.4 - 2.13.9.2.4 Variation 4: Reactions Forming Actinide-Phosphoranimide Complexes [Seite 199]
1.8.2.10 - 2.13.10 Product Subclass 10: Organoactinide Complexes Bearing Bridged Ligands [Seite 200]
1.8.2.10.1 - Synthesis of Product Subclass 10 [Seite 201]
1.8.2.10.1.1 - 2.13.10.1 Method 1: Organoactinide Complexes Bearing Bridged Ligands [Seite 201]
1.8.2.10.1.1.1 - 2.13.10.1.1 Variation 1: Carbon-Bridged Ancillary Ligand Complexes of the Actinides [Seite 201]
1.8.2.10.1.1.2 - 2.13.10.1.2 Variation 2: Nitrogen-Bridged Ancillary Ligand Complexes of the Actinides [Seite 203]
1.8.2.10.1.1.3 - 2.13.10.1.3 Variation 3: Oxygen-Bridged Ancillary Ligand Complexes of the Actinides [Seite 206]
1.8.2.10.1.1.4 - 2.13.10.1.4 Variation 4: Silicon-Bridged Ancillary Ligand Complexes of the Actinides [Seite 207]
1.8.2.10.2 - Applications of Product Subclass 10 in Organic Synthesis [Seite 209]
1.8.2.10.2.1 - 2.13.10.2 Method 2: Catalytic Intramolecular Hydroamination/Cyclization Mediated by Constrained-Geometry Actinide Complexes [Seite 209]
1.8.2.10.2.2 - 2.13.10.3 Method 3: Intermolecular Hydrosilylation with Phenylsilane Mediated by Constrained-Geometry Thorium Complexes [Seite 211]
1.8.2.10.2.3 - 2.13.10.4 Method 4: Intermolecular Hydrothiolation [Seite 214]
1.8.2.11 - 2.13.11 Product Subclass 11: Multimetallic Actinide Complexes [Seite 215]
1.8.2.11.1 - Synthesis of Product Subclass 11 [Seite 215]
1.8.2.11.1.1 - 2.13.11.1 Method 1: Homobimetallic Actinide Complexes [Seite 215]
1.8.2.11.1.1.1 - 2.13.11.1.1 Variation 1: Nitrogen-Bridged Homobimetallic Actinide Complexes [Seite 215]
1.8.2.11.1.1.2 - 2.13.11.1.2 Variation 2: Halogen-Bridged Homobimetallic Actinide Complexes [Seite 217]
1.8.2.11.1.1.3 - 2.13.11.1.3 Variation 3: Oxygen-Bridged Homobimetallic Complexes [Seite 218]
1.8.2.11.1.1.4 - 2.13.11.1.4 Variation 4: Carbide-Bridged Homobimetallic Actinide Complexes [Seite 220]
1.8.2.11.1.2 - 2.13.11.2 Method 2: Heterobimetallic Complexes [Seite 220]
1.8.2.11.1.2.1 - 2.13.11.2.1 Variation 1: Hydride-Bridged Heterobimetallic Complexes [Seite 221]
1.8.2.11.1.2.2 - 2.13.11.2.2 Variation 2: Phosphorus-Bridged Heterobimetallic Actinide Complexes [Seite 222]
1.8.2.11.1.2.3 - 2.13.11.2.3 Variation 3: Heterobimetallic Actinide-Ferrocenyl Complexes [Seite 222]
1.8.2.11.1.2.4 - 2.13.11.2.4 Variation 4: Heterobimetallic Actinide Complexes with Unsupported Metal--Metal Bonds [Seite 223]
1.8.2.11.1.2.5 - 2.13.11.2.5 Variation 5: Heterobimetallic Nitrogen-Bridged Actinide Complexes [Seite 224]
1.8.2.11.2 - Applications of Product Subclass 11 in Organic Synthesis [Seite 225]
1.8.2.11.2.1 - 2.13.11.3 Method 3: Reversible Carbon--Carbon Coupling [Seite 225]
1.8.2.11.2.2 - 2.13.11.4 Method 4: Inter- and Intramolecular Hydroamination [Seite 227]
1.8.2.11.2.3 - 2.13.11.5 Method 5: s-Bond Metathesis of Silylalkynes [Seite 229]
1.9 - Volume 4: Compounds of Group 15 (As, Sb, Bi) and Silicon Compounds [Seite 242]
1.9.1 - 4.4 Product Class 4: Silicon Compounds [Seite 242]
1.9.1.1 - 4.4.3 Product Subclass 3: Silylenes [Seite 242]
1.9.1.1.1 - Synthesis of Product Subclass 3 [Seite 244]
1.9.1.1.1.1 - 4.4.3.1 Method 1: Reduction of Dihalosilanes [Seite 244]
1.9.1.1.1.2 - 4.4.3.2 Method 2: Reduction of Trichlorosilanes or Silicon Tetrachloride [Seite 256]
1.9.1.1.1.3 - 4.4.3.3 Method 3: Reaction of a Silyliumylidene Cation [Seite 258]
1.9.1.1.1.4 - 4.4.3.4 Method 4: Dehydrochlorination of Hydrochlorosilanes [Seite 260]
1.9.1.1.2 - Applications of Product Subclass 3 in Organic Synthesis [Seite 263]
1.9.1.1.2.1 - 4.4.3.5 Method 5: Insertion Reactions [Seite 263]
1.9.1.1.2.2 - 4.4.3.6 Method 6: Addition Reactions to 1,3-Dienes [Seite 284]
1.9.1.1.2.3 - 4.4.3.7 Method 7: Addition Reactions to Aldehydes, Ketones, and Imines [Seite 289]
1.9.1.1.2.4 - 4.4.3.8 Method 8: Addition Reactions to Alkynes and Cyanides [Seite 293]
1.9.1.1.2.5 - 4.4.3.9 Method 9: Addition Reactions to Isocyanides and Azides [Seite 295]
1.9.1.1.2.6 - 4.4.3.10 Method 10: Addition Reactions to Alkenes and Silenes [Seite 301]
1.9.1.1.2.7 - 4.4.3.11 Method 11: Reactions with Carbenes and 4-(Dimethylamino)pyridine [Seite 302]
1.9.1.1.2.8 - 4.4.3.12 Method 12: Reactions with Elemental Chalcogens or Phosphorus [Seite 303]
1.9.1.1.2.9 - 4.4.3.13 Method 13: Reactions with Transition Metals [Seite 310]
1.10 - Volume 6: Boron Compounds [Seite 326]
1.10.1 - 6.1 Product Class 1: Boron Compounds [Seite 326]
1.10.1.1 - 6.1.28.24 Vinylboranes [Seite 326]
1.10.1.1.1 - 6.1.28.24.1 Synthesis of Vinylboranes [Seite 326]
1.10.1.1.1.1 - 6.1.28.24.1.1 Method 1: Insertion of Borylenes into C--H Bonds [Seite 327]
1.10.1.1.1.2 - 6.1.28.24.1.2 Method 2: Dimetalation of Allenes and Alkynes [Seite 327]
1.10.1.1.1.2.1 - 6.1.28.24.1.2.1 Variation 1: Palladium-Catalyzed Enantioselective Diboration of Allenes [Seite 327]
1.10.1.1.1.2.2 - 6.1.28.24.1.2.2 Variation 2: Silaboration of Alkynes [Seite 329]
1.10.1.1.1.2.3 - 6.1.28.24.1.2.3 Variation 3: Silaboration of Allenes [Seite 331]
1.10.1.1.1.2.4 - 6.1.28.24.1.2.4 Variation 4: Silaborative C--C Cleavage Reactions of Methylenecyclopropanes [Seite 335]
1.10.1.1.1.2.5 - 6.1.28.24.1.2.5 Variation 5: Copper-Catalyzed Addition of Diboron Reagents to Alkynes [Seite 337]
1.10.1.1.1.3 - 6.1.28.24.1.3 Method 3: Transmetalation of Vinylic Metal Complexes with Boron Reagents [Seite 339]
1.10.1.1.1.3.1 - 6.1.28.24.1.3.1 Variation 1: Copper Hydride Catalyzed Addition of Pinacolborane to Acetylenic Esters [Seite 339]
1.10.1.1.1.3.2 - 6.1.28.24.1.3.2 Variation 2: Transmetalation of Vinylaluminums [Seite 340]
1.10.1.1.1.3.3 - 6.1.28.24.1.3.3 Variation 3: Transmetalation of Cyclic Vinyllithium Compounds [Seite 342]
1.10.1.1.1.3.4 - 6.1.28.24.1.3.4 Variation 4: Palladium-Catalyzed Borylation of Vinyl Halides [Seite 342]
1.10.1.1.1.4 - 6.1.28.24.1.4 Method 4: Carboboration of Alkynes [Seite 342]
1.10.1.1.1.5 - 6.1.28.24.1.5 Method 5: Miscellaneous Methods [Seite 345]
1.10.1.1.1.5.1 - 6.1.28.24.1.5.1 Variation 1: Protodeboronation of Alkenyl Geminal Diboron Species [Seite 345]
1.10.1.1.1.5.2 - 6.1.28.24.1.5.2 Variation 2: Stereoselective Synthesis of Tetrasubstituted Vinylboronates [Seite 346]
1.10.1.1.2 - 6.1.28.24.2 Applications of Vinylboranes in Organic Synthesis [Seite 347]
1.10.1.1.2.1 - 6.1.28.24.2.1 Method 1: Reduction of Double Bonds [Seite 347]
1.10.1.1.2.2 - 6.1.28.24.2.2 Method 2: Synthesis of Cyclopropylboronates and Oxiran-2-ylboronates [Seite 348]
1.10.1.1.2.3 - 6.1.28.24.2.3 Method 3: Cycloadditions [Seite 350]
1.10.1.1.2.4 - 6.1.28.24.2.4 Method 4: Heck Reactions [Seite 352]
1.10.1.1.2.5 - 6.1.28.24.2.5 Method 5: Substitution Reactions [Seite 353]
1.10.1.1.2.5.1 - 6.1.28.24.2.5.1 Variation 1: Vinylogous Intramolecular Alkyl-Transfer Reactions [Seite 353]
1.10.1.1.2.5.2 - 6.1.28.24.2.5.2 Variation 2: Reactions of Borylated Allylic Reagents [Seite 354]
1.10.1.1.2.6 - 6.1.28.24.2.6 Method 6: Formation of Carbon--Halogen Bonds [Seite 357]
1.10.1.1.2.6.1 - 6.1.28.24.2.6.1 Variation 1: Formation of a C--Cl Bond through Iodination of a Double Bond [Seite 357]
1.10.1.1.2.6.2 - 6.1.28.24.2.6.2 Variation 2: Fluorination through Tandem Transmetalation-Fluorination [Seite 358]
1.10.1.1.2.7 - 6.1.28.24.2.7 Method 7: Formation of C--N Bonds [Seite 359]
1.10.1.1.2.7.1 - 6.1.28.24.2.7.1 Variation 1: Chan-Lam-Evans Cross Coupling [Seite 359]
1.10.1.1.2.7.2 - 6.1.28.24.2.7.2 Variation 2: Formation of Imines [Seite 359]
1.10.1.1.2.8 - 6.1.28.24.2.8 Method 8: Formation of C--O Bonds [Seite 360]
1.10.1.1.2.9 - 6.1.28.24.2.9 Method 9: Formation of C--S and C--Se Bonds [Seite 361]
1.10.1.1.2.10 - 6.1.28.24.2.10 Method 10: Addition to Heteroatom--Carbon Double Bonds [Seite 362]
1.10.1.1.2.11 - 6.1.28.24.2.11 Method 11: Addition to Carbon--Carbon Multiple Bonds [Seite 364]
1.10.1.1.2.12 - 6.1.28.24.2.12 Method 12: Homocoupling of Vinylboranes [Seite 364]
1.10.1.1.2.13 - 6.1.28.24.2.13 Method 13: Cross Coupling of Vinylboranes [Seite 365]
1.11 - Volume 9: Fully Unsaturated Small-Ring Heterocycles and Monocyclic Five-Membered Hetarenes with One Heteroatom [Seite 370]
1.11.1 - 9.14 Product Class 14: Phospholes [Seite 370]
1.11.1.1 - 9.14.4 Phospholes [Seite 370]
1.11.1.1.1 - 9.14.4.1 .3-1H-Phospholes [Seite 370]
1.11.1.1.1.1 - 9.14.4.1.1 Synthesis by Ring-Closure Reactions [Seite 370]
1.11.1.1.1.1.1 - 9.14.4.1.1.1 By Formation of Two P--C Bonds [Seite 370]
1.11.1.1.1.1.1.1 - 9.14.4.1.1.1.1 Method 1: Reaction of Primary Phosphines with Diynes [Seite 370]
1.11.1.1.1.1.2 - 9.14.4.1.1.2 By Formation of One C--C Bond [Seite 371]
1.11.1.1.1.1.2.1 - 9.14.4.1.1.2.1 Method 1: Ring Closure of Dialk-1-ynylphosphines [Seite 371]
1.11.1.1.1.2 - 9.14.4.1.2 Synthesis by Ring Transformation [Seite 372]
1.11.1.1.1.2.1 - 9.14.4.1.2.1 Method 1: Reaction of Dihalophosphines with Zirconacyclopentadienes [Seite 372]
1.11.1.1.1.2.1.1 - 9.14.4.1.2.1.1 Variation 1: Reaction of Zirconacyclopentadienes with Iodine, Butyllithium, and Dihalophosphines [Seite 373]
1.11.1.1.1.2.1.2 - 9.14.4.1.2.1.2 Variation 2: Reaction of Zirconacyclopentadienes with Copper(I) Chloride and Dihalophosphines [Seite 374]
1.11.1.1.1.2.1.3 - 9.14.4.1.2.1.3 Variation 3: Reaction of Dihalophosphines with Titanacyclopentadienes [Seite 374]
1.11.1.1.1.3 - 9.14.4.1.3 Aromatization [Seite 375]
1.11.1.1.1.3.1 - 9.14.4.1.3.1 Method 1: Dehydrohalogenation of 1-Halodihydrophospholium Ions [Seite 375]
1.11.1.1.1.4 - 9.14.4.1.4 Synthesis by Substituent Modification [Seite 376]
1.11.1.1.1.4.1 - 9.14.4.1.4.1 Method 1: Reaction of Electrophiles with Phospholide Ions [Seite 376]
1.11.1.1.1.4.2 - 9.14.4.1.4.2 Method 2: Reaction of Nucleophiles with Phospholes [Seite 378]
1.11.1.1.1.4.3 - 9.14.4.1.4.3 Method 3: Electrophilic Functionalization of Phospholes [Seite 380]
1.11.1.1.1.4.4 - 9.14.4.1.4.4 Method 4: Transformation of a-Substituents [Seite 380]
1.11.1.1.1.4.5 - 9.14.4.1.4.5 Method 5: Reduction of .5-Phospholes [Seite 382]
1.11.1.1.2 - 9.14.4.2 Phospholide Ions [Seite 383]
1.11.1.1.2.1 - 9.14.4.2.1 Method 1: Cleavage of the Exocyclic P--R Bond of 1H-Phospholes by Alkali Metals [Seite 383]
1.11.1.1.2.1.1 - 9.14.4.2.1.1 Variation 1: Cleavage of the Exocyclic P--C Bond of 1H-Phospholes by Bases [Seite 383]
1.11.1.1.2.1.2 - 9.14.4.2.1.2 Variation 2: Deprotonation of Transient 2H-Phospholes [Seite 384]
1.11.1.1.3 - 9.14.4.3 .5-Phospholyl Complexes [Seite 386]
1.11.1.1.3.1 - 9.14.4.3.1 Method 1: Synthesis from .3-1H-Phospholes [Seite 386]
1.11.1.1.3.2 - 9.14.4.3.2 Method 2: Synthesis from .3-2H-Phospholes [Seite 387]
1.11.1.1.3.3 - 9.14.4.3.3 Method 3: Synthesis from Phospholide Ions [Seite 387]
1.11.1.1.3.3.1 - 9.14.4.3.3.1 Variation 1: Via Intermediate 1-Stannylphospholes [Seite 388]
1.11.1.1.3.4 - 9.14.4.3.4 Method 4: Electrophilic Functionalization [Seite 388]
1.11.1.1.3.5 - 9.14.4.3.5 Method 5: Transformation of Substituents [Seite 388]
1.12 - Volume 40: Amines, Ammonium Salts, Amine N-Oxides, Haloamines, Hydroxylamines and Sulfur Analogues, and Hydrazines [Seite 394]
1.12.1 - 40.1 Product Class 1: Amino Compounds [Seite 394]
1.12.1.1 - 40.1.1.5.6 Transition-Metal-Catalyzed Functionalization of C(sp3)--H Bonds of Amines [Seite 394]
1.12.1.1.1 - 40.1.1.5.6.1 Transition-Metal-Catalyzed Oxidation of a-C(sp3)--H Bonds of Tertiary N-Methylamines and Amides [Seite 395]
1.12.1.1.1.1 - 40.1.1.5.6.1.1 Method 1: Ruthenium-Catalyzed Oxidation of Tertiary Amines [Seite 395]
1.12.1.1.1.2 - 40.1.1.5.6.1.2 Method 2: Palladium-Catalyzed Acetoxylation of tert-Butoxycarbonyl-Protected N-Methylamines [Seite 398]
1.12.1.1.2 - 40.1.1.5.6.2 Transition-Metal-Catalyzed Cross-Dehydrogenative Coupling Reactions of C(sp3)--H Bonds at the a-Position of Amines [Seite 400]
1.12.1.1.2.1 - 40.1.1.5.6.2.1 Method 1: Transition-Metal-Catalyzed Alkynylation of a-C(sp3)--H Bonds of Tertiary Amines [Seite 401]
1.12.1.1.2.1.1 - 40.1.1.5.6.2.1.1 Variation 1: Synthesis of Propargylamines by Copper(I)-Catalyzed Alkynylation of Tertiary Amines [Seite 401]
1.12.1.1.2.1.2 - 40.1.1.5.6.2.1.2 Variation 2: Alkynylation of Tertiary Amines Catalyzed by Iron(II) Chloride [Seite 404]
1.12.1.1.2.2 - 40.1.1.5.6.2.2 Method 2: Synthesis of ß-Amino Ketones (Mannich Products) by Transition-Metal-Catalyzed C(sp3)--H Bond Functionalization [Seite 406]
1.12.1.1.2.2.1 - 40.1.1.5.6.2.2.1 Variation 1: Synthesis of ß-Amino Ketones Catalyzed by Copper Salts [Seite 406]
1.12.1.1.2.2.2 - 40.1.1.5.6.2.2.2 Variation 2: Synthesis of ß-Amino Ketones (Mannich Products) Catalyzed by a Combination of a Transition-Metal Catalyst and an Organocatalyst [Seite 409]
1.12.1.1.2.2.3 - 40.1.1.5.6.2.2.3 Variation 3: Synthesis of ß-Amino Ketones (Mannich Products) by Aerobic Oxidative Coupling of Tertiary Amines with Silyl Enol Ethers and Ketene Acetals [Seite 412]
1.12.1.1.2.3 - 40.1.1.5.6.2.3 Method 3: Nitro-Mannich (Aza-Henry) Reaction via C(sp3)--H Functionalization [Seite 414]
1.12.1.1.2.3.1 - 40.1.1.5.6.2.3.1 Variation 1: Copper-Catalyzed Cross-Dehydrogenative Coupling of Tertiary Amines and Nitroalkanes [Seite 414]
1.12.1.1.2.3.2 - 40.1.1.5.6.2.3.2 Variation 2: Aza-Henry and Mannich Reaction by Platinum-Catalyzed Cross-Dehydrogenative Coupling of Tertiary Amines in the Absence of Oxidant [Seite 416]
1.12.1.1.2.3.3 - 40.1.1.5.6.2.3.3 Variation 3: Aza-Henry (Nitro-Mannich) Reactions in the Presence of Ruthenium Complexes via Visible Light Photoredox Catalyzed C(sp3)--H Functionalization [Seite 420]
1.12.1.1.2.4 - 40.1.1.5.6.2.4 Method 4: Transition-Metal-Catalyzed Oxidative a-Cyanation of Tertiary Amines [Seite 425]
1.12.1.1.2.4.1 - 40.1.1.5.6.2.4.1 Variation 1: Aerobic Oxidative a-Cyanation of Tertiary Amines with Sodium Cyanide/Acetic Acid [Seite 425]
1.12.1.1.2.4.2 - 40.1.1.5.6.2.4.2 Variation 2: a-Cyanation of Tertiary Amines with Sodium Cyanide/Acetic Acid in the Presence of Hydrogen Peroxide or tert-Butyl Hydroperoxide [Seite 428]
1.12.1.1.2.4.3 - 40.1.1.5.6.2.4.3 Variation 3: a-Cyanation of Tertiary Amines Catalyzed by Gold Complexes under Acid-Free Conditions [Seite 430]
1.12.1.1.2.5 - 40.1.1.5.6.2.5 Method 5: Iron(III)-Catalyzed Oxidative Allylation of a C--H Bond Adjacent to a Nitrogen Atom: Synthesis of Homoallyl Tertiary Amines [Seite 434]
1.12.1.1.2.6 - 40.1.1.5.6.2.6 Method 6: Copper-Catalyzed Aerobic Phosphonation of C(sp3)--H Bonds [Seite 437]
1.12.1.1.2.7 - 40.1.1.5.6.2.7 Method 7: Transition-Metal-Catalyzed (Het)Arylation of C(sp3)--H Bonds Adjacent to Nitrogen [Seite 438]
1.12.1.1.2.7.1 - 40.1.1.5.6.2.7.1 Variation 1: Iron-Catalyzed Oxidative Coupling of Hetarenes and Tertiary N-Methylamines [Seite 439]
1.12.1.1.2.7.2 - 40.1.1.5.6.2.7.2 Variation 2: Copper-Catalyzed Cross-Dehydrogenative Coupling Reaction of Tertiary Amines and Indoles Using tert-Butyl Hydroperoxide as Oxidant [Seite 441]
1.12.1.1.2.7.3 - 40.1.1.5.6.2.7.3 Variation 3: Ruthenium-Catalyzed Cross-Dehydrogenative Coupling Reactions of Tertiary Amines and Indoles [Seite 443]
1.12.1.1.2.7.4 - 40.1.1.5.6.2.7.4 Variation 4: Iron-Catalyzed Cross-Dehydrogenative Coupling Reactions of tert-Butoxycarbonyl-Protected 1,2,3,4-Tetrahydroisoquinoline and Indoles [Seite 446]
1.12.1.1.2.7.5 - 40.1.1.5.6.2.7.5 Variation 5: Copper-Catalyzed Cross-Dehydrogenative Coupling Reaction of Hetarenes Using Air/Oxygen as Oxidant [Seite 447]
1.12.1.1.2.7.6 - 40.1.1.5.6.2.7.6 Variation 6: Transition-Metal-Catalyzed Oxidative Coupling of Alkylamides with Electron-Rich (Het)Arenes [Seite 450]
1.12.1.1.2.7.7 - 40.1.1.5.6.2.7.7 Variation 7: Copper-Catalyzed Oxidative Coupling of Tertiary Amines and Siloxyfurans [Seite 454]
1.12.1.1.2.7.8 - 40.1.1.5.6.2.7.8 Variation 8: Dirhodium(II) Caprolactamate Catalyzed Oxidative Coupling of Tertiary Amines and Siloxyfurans [Seite 456]
1.12.1.1.2.8 - 40.1.1.5.6.2.8 Method 8: Copper-Catalyzed Oxidative C(sp³)--H Bond Arylation with Arylboronic Acids (Petasis-Mannich Reaction) [Seite 458]
1.12.1.1.2.9 - 40.1.1.5.6.2.9 Method 9: Synthesis of Nonnatural Amino Acids via Functionalization of a-C(sp3)--H Bonds of Tertiary Amines [Seite 460]
1.12.1.1.2.9.1 - 40.1.1.5.6.2.9.1 Variation 1: Functionalization of Glycine Derivatives by Direct C--C Bond Formation [Seite 460]
1.12.1.1.2.9.2 - 40.1.1.5.6.2.9.2 Variation 2: Cross-Dehydrogenative Coupling Reactions of Amino Acids and Ketones by Cooperative Transition-Metal and Amino Catalysis [Seite 465]
1.12.1.1.2.10 - 40.1.1.5.6.2.10 Method 10: a-Functionalization of Nonactivated Aliphatic Amines in the Absence of Oxidant: Ruthenium-Catalyzed Alkynylations [Seite 467]
1.12.1.1.3 - 40.1.1.5.6.3 Transition-Metal-Catalyzed Nonoxidative Functionalization of a-C(sp3)--H Bonds of Amines [Seite 469]
1.12.1.1.3.1 - 40.1.1.5.6.3.1 Transition-Metal-Catalyzed Hydroaminoalkylation [Seite 470]
1.12.1.1.3.1.1 - 40.1.1.5.6.3.1.1 Method 1: Transition-Metal-Catalyzed Intermolecular Hydroaminoalkylation of Unactivated Alkenes [Seite 470]
1.12.1.1.3.1.1.1 - 40.1.1.5.6.3.1.1.1 Variation 1: Hydroaminoalkylation of Unactivated Alkenes with N-Alkylarylamines [Seite 470]
1.12.1.1.3.1.1.2 - 40.1.1.5.6.3.1.1.2 Variation 2: Hydroaminoalkylation of Unactivated Alkenes with Dialkylamines [Seite 475]
1.12.1.1.3.1.1.3 - 40.1.1.5.6.3.1.1.3 Variation 3: Hydroaminoalkylation with Secondary Amines: Enantioselective Synthesis of Chiral Amines [Seite 477]
1.12.1.1.3.1.2 - 40.1.1.5.6.3.1.2 Method 2: Transition-Metal-Catalyzed Intramolecular C--H Activation of Primary and Secondary Amines [Seite 488]
1.12.1.1.4 - 40.1.1.5.6.4 a-C(sp3)--H Bond Functionalization of Amines via Transition-Metal-Catalyzed Hydride Transfer Cyclization [Seite 493]
1.12.1.1.4.1 - 40.1.1.5.6.4.1 Method 1: Coupling of Unactivated Alkynes and C(sp3)--H Bonds [Seite 493]
1.12.1.1.4.1.1 - 40.1.1.5.6.4.1.1 Variation 1: Direct Coupling of Unactivated Alkynes and C(sp3)--H Bonds Catalyzed by Platinum(IV) Iodide [Seite 493]
1.12.1.1.4.1.2 - 40.1.1.5.6.4.1.2 Variation 2: A Two-Step, One-Pot Gold-Catalyzed Cyclization of 1-(But-3-ynyl)piperidine Derivatives [Seite 495]
1.12.1.1.4.2 - 40.1.1.5.6.4.2 Method 2: Coupling of Electron-Deficient Alkenes and a-C(sp3)--H Bonds of Amines [Seite 496]
1.12.1.1.4.2.1 - 40.1.1.5.6.4.2.1 Variation 1: Enantioselective Synthesis of 1,2,3,4-Tetrahydroquinolines via Cobalt(II)-Catalyzed Tandem 1,5-Hydride Transfer/Cyclization [Seite 496]
1.12.1.1.4.2.2 - 40.1.1.5.6.4.2.2 Variation 2: Gold-Catalyzed Enantioselective Functionalization of C(sp3)--H Bonds by Redox-Neutral Domino Reactions [Seite 500]
1.12.1.1.5 - 40.1.1.5.6.5 Transition-Metal-Catalyzed a-Arylation of Saturated Amines [Seite 503]
1.12.1.1.5.1 - 40.1.1.5.6.5.1 Method 1: C(sp3)--H Bond Arylation Directed by an Amidine Protecting Group: a-Arylation of Pyrrolidines and Piperidines [Seite 503]
1.12.1.1.5.2 - 40.1.1.5.6.5.2 Method 2: Iron-Catalyzed Arylation at the a-Position of Aliphatic Amines [Seite 507]
1.12.1.1.6 - 40.1.1.5.6.6 Remote Functionalization of Unactivated C(sp3)--H Bonds of Amines and Amides [Seite 509]
1.12.1.1.6.1 - 40.1.1.5.6.6.1 Method 1: Palladium-Catalyzed Picolinamide-Directed Remote Arylation of Unactivated C(sp3)--H Bonds [Seite 509]
1.12.1.1.6.2 - 40.1.1.5.6.6.2 Method 2: Synthesis of Fused Indolines by Palladium-Catalyzed Asymmetric C--C Coupling Involving an Unactivated Methylene Group at the Position ß to Nitrogen [Seite 513]
1.12.1.1.6.3 - 40.1.1.5.6.6.3 Method 3: C(sp3)--H Bond Activation with Ruthenium(II) Catalysts and C3-Alkylation of Cyclic Amines [Seite 515]
1.13 - Author Index [Seite 524]
1.14 - Abbreviations [Seite 546]
1.15 - List of All Volumes [Seite 552]