Analytical Chemistry, Second Edition covers the fundamental principles of analytical chemistry. This edition is organized into 30 chapters that present various analytical chemistry methods.
This book begins with a core of six chapters discussing the concepts basic to all of analytical chemistry. The fundamentals, concepts, applications, calculations, instrumentation, and chemical reactions of five major areas of analytical chemistry, namely, neutralization, potentiometry, spectroscopy, chromatography, and electrolysis methods, are emphasized in separate chapters. Other chapters are devoted to a discussion of precipitation and complexes in analytical chemistry. Principles and applications and the relationship of these reactions to the other areas are stressed. The remaining chapters of this edition are devoted to the laboratory. A chapter discusses the basic laboratory operations, with an emphasis on safety. This topic is followed by a series of experiments designed to reinforce the concepts developed in the chapters.
This book is designed for introductory courses in analytical chemistry, especially those shorter courses servicing chemistry majors and life and health science majors.
Sprache
Verlagsort
Verlagsgruppe
Elsevier Science & Techn.
ISBN-13
978-0-323-14300-4 (9780323143004)
Schweitzer Klassifikation
Preface Chapter One Introduction to Analytical Chemistry To the Student Analytical Chemistry Analytical Chemistry in Allied Areas The Analytical Chemist and the AnalystChapter Two Development of an Analytical Method The Analytical Problem Choosing an Analytical Method Types of Analytical Methods Methods of Analysis Literature in Analytical Chemistry Chapter Three Stoichiometry Introduction Units Concentration Calculations Standards Questions ProblemsChapter Four Statistical Treatment of Analytical Data Introduction Definitions Elimination of Data Propagation of Errors Questions Problems Chapter Five Preliminary Operations in Quantitative Analysis Introduction Sampling Drying Weighing Dissolving Questions Chapter Six Introduction to Chemical Reactions in Analytical Chemistry Scope Completeness of Reaction Equilibrium Concept Reaction Rates Equilibrium Constant Application of the Equilibrium Concept Equilibrium Condition: Fundamental Definition Summary Questions Chapter Seven Precipitation Methods Introduction Gravimetry Formation of a Precipitate Properties of Precipitates Coprecipitation Types of Precipitating Reagents Solubility Solubility Product Typical Gravimetric Examples Homogeneous Precipitation Calculations Questions Problems Chapter Eight Neutralization in Analytical Chemistry Introduction Acid-Base Theories Acid and Base Strength Leveling Effect pH pH Scale pH of Acid and Base Solutions Buffers Neutralization as a Volumetric Method Polyfunctional Acids and Bases Titration of Salts Differential Titration Primary Standards End-Point Detection Summary of Acid-Base Titration Curves Applications Calculations Questions Problems Chapter Nine Nonaqueous Acid-Base Titrations Scope Solvents Equilibria in a Nonaqueous Solvent Choosing a Solvent Titrants End-Point Detection Applications Indirect Acid-Base Methods Calculations Questions Problems Chapter Ten Oxidation-Reduction Equilibria Definitions Electrochemical Cells Cell Calculations Nernst Equation Equilibrium Constant Measurement of Potential Reference-Indicator Electrodes Biological Systems Questions Problems Chapter Eleven Oxidation-Reduction Titrations Introduction Titration Curve Differential Titrations End-Point Detection Questions Problems Chapter Twelve Oxidizing and Reducing Agents as Titrants in Analytical Chemistry Introduction Oxidizing Titrants Reducing Titrants Adjustment of Oxidation State Calculations Questions Problems Chapter Thirteen Ion-Selective Electrodes Introduction Electrodes for Hydronium Ion Non-Half-Cell Ion-Selective Electrodes Glass Membrane Electrode Solid State and Precipitate Electrodes Liquid-Liquid Electrode Gas- and Enzyme-Sensing Electrodes Calibration Applications Measurements with a pH Meter Questions Problems Chapter Fourteen Precipitation Titrations I
