Spectra of Atoms and Molecules 2/e

Name: Spectra of Atoms and Molecules 2/e
Brand: Oxford University Press
Price: 122.29 EUR
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BERNATH PETER F(Autor*in)

Oxford University Press

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Erschienen am 19. Mai 2005

454 Seiten

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Beschreibung

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Inhalt

Intro
Contents
1 Introduction
1.1 Waves, Particles, and Units
1.2 The Electromagnetic Spectrum
1.3 Interaction of Radiation with Matter
Blackbody Radiation
Einstein A and B Coefficients
Absorption and Emission of Radiation
Beer's Law
Lineshape Functions
Natural Lifetime Broadening
Pressure Broadening
Doppler Broadening
Transit-Time Broadening
Power Broadening
2 Molecular Symmetry
2.1 Symmetry Operations
Operator Algebra
Symmetry Operator Algebra
2.2 Groups
Point Groups
Classes
Subgroups
2.3 Notation for Point Groups
3 Matrix Representation of Groups
3.1 Vectors and Matrices
Matrix Eigenvalue Problem
Similarity Transformations
3.2 Symmetry Operations and Position Vectors
Reflection
Rotation
Inversion
Rotation-Reflection
Identity
3.3 Symmetry Operators and Basis Vectors
3.4 Symmetry Operators and Basis Functions
Function Spaces
Gram-Schmidt Procedure
Transformation Operators
3.5 Equivalent, Reducible, and Irreducible Representations
Equivalent Representations
Unitary Representations
Reducible and Irreducible Representations
3.6 Great Orthogonality Theorem
Characters
3.7 Character Tables
Mulliken Notation
4 Quantum Mechanics and Group Theory
4.1 Matrix Representation of the Schrödinger Equation
4.2 Born-Oppenheimer Approximation
4.3 Symmetry of the Hamiltonian Operator
4.4 Projection Operators
4.5 Direct Product Representations
4.6 Integrals and Selection Rules
5 Atomic Spectroscopy
5.1 Background
5.2 Angular Momentum
5.3 The Hydrogen Atom and One-Electron Spectra
Vector Model
Spin-Orbit Coupling
5.4 Many-Electron Atoms
5.5 Selection Rules
5.6 Atomic Spectra
Hyperfine Structure
Hydrogen Atom
5.7 Intensity of Atomic Lines
5.8 Zeeman Effect
Paschen-Back Effect
5.9 Stark Effect
6 Rotational Spectroscopy
6.1 Rotation of Rigid Bodies
6.2 Diatomic and Linear Molecules
Selection Rules
Centrifugal Distortion
Vibrational Angular Momentum
6.3 Line Intensities for Diatomic and Linear Molecules
6.4 Symmetric Tops
Molecule and Space-Fixed Angular Momenta
Rotational Spectra
Centrifugal Distortion
Line Intensity
6.5 Asymmetric Tops
Selection Rules
Line Intensity
6.6 Structure Determination
7 Vibrational Spectroscopy
7.1 Diatomic Molecules
Wavefunctions for Harmonic and Anharmonic Oscillators
Vibrational Selection Rules for Diatomics
Dissociation Energies from Spectroscopic Data
Vibration-Rotation Transitions of Diatomics
Combination Differences
7.2 Vibrational Motion of Polyatomic Molecules
Classical Mechanical Description
Quantum Mechanical Description
Internal Coordinates
Symmetry Coordinates
Symmetry of Normal Modes
Selection Rules for Vibrational Transitions
Vibration-Rotation Transitions of Linear Molecules
Nuclear Spin Statistics
Excited Vibrational States of Linear Molecules
7.3 Vibrational Spectra of Symmetric Tops
Coriolis Interactions in Molecules
7.4 Infrared Transitions of Spherical Tops
7.5 Vibrational Spectra of Asymmetric Tops
7.6 Vibration-Rotation Line Intensities
Line Intensity Calculations
7.7 Fermi and Coriolis Perturbations
7.8 Inversion Doubling and Fluxional Behavior
8 Light Scattering and the Raman Effect
8.1 Background
Classical Model
Quantum Model
Polarization
8.2 Rotational Raman Effect
Diatomic Molecules
8.3 Vibration-Rotation Raman Spectroscopy
Diatomic Molecules
8.4 Rayleigh and Raman Intensities
Classical Theory
Vibrational Intensity Calculations
8.5 Conclusions
9 Electronic Spectroscopy of Diatomics
9.1 Orbitals and States
9.2 Vibrational Structure
9.3 Rotational Structure of Diatomic Molecules
Singlet-Singlet Transitions
Nonsinglet Transitions
9.4 The Symmetry of Diatomic Energy Levels: Parity
Total (+/-) Parity
Rotationless (e/f) Parity
Gerade/Ungerade (g/u) Parity
Symmetric/Antisymmetric (s/a) Parity
9.5 Rotational Line Intensities
9.6 Dissociation, Photodissociation, and Predissociation
A Units, Conversions, and Physical Constants
B Character Tables
C Direct Product Tables
D Introductory Textbooks
Figure Acknowledgments
Index
A
B
C
D
E
F
G
H
I
J
K
L
M
N
O
P
Q
R
S
T
U
V
W
Z

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