It is now some sixteen years since the author's first series of books on the analysis of organometallic compounds. Many developments in the subject have occurred since that time and a new book on the subject is now overdue. The present book aims to provide a comprehensive review of the subject. It covers not only all aspects of the analysis of organometallic compounds but also contains two additional chapters, dealing with environmental analysis and the use of chelates of metals in the determination of very low concentrations of organic metals. Whilst reviewing the literature for the present book, it was observed that whereas papers published prior to 1973 dealt almost exclusively with various forms of analysis, a high proportion of those published during the past ten years were concerned with the application of proven or newly developed methods to the determination of organometallic compounds in environmental samples such as water, air, soil, river and ocean sediments, fish life and biota samples. An increasing range of elements including mercury, lead, arsenic, tin, antimony, selenium and manganese are now being found in organically bound forms in the environment, some resulting from pollution, others formed in nature by bacterial processes. As many of these substances have appreciable implications to human and animal health and the ecosystem as a whole, it was considered that it would be timely to include a separate chapter in the book devoted entirely to this subject.
Auflage
Sprache
Verlagsort
Verlagsgruppe
Illustrationen
ISBN-13
978-1-4615-9498-7 (9781461594987)
DOI
10.1007/978-1-4615-9498-7
Schweitzer Klassifikation
1 Determination of Elements and Functional Groups.- Organoaluminium Compounds.- Organoantimony Compounds.- Organoarsenic Compounds.- Organoberyllium Compounds.- Organobismuth Compounds.- Organoboron Compounds.- Organocalcium Compounds.- Organo chromium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogermanium Compounds.- Organoiron Compounds.- Organolead Compounds.- Organolithium Compounds.- Organomagnesium Compounds.- Organomanganese Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organopalladium Compounds.- Organophosphorus Compounds.- Organoplatinum Compounds.- Organopotassium Compounds.- Organoselenium Compounds.- Organosilicon Compounds.- Determination of Elements.- Determination of Functional Groups.- Organothallium Compounds.- Organotin Compounds.- Organotitanium Compounds.- Organozinc Compounds.- Organozirconium Compounds.- 2 Titration Procedures.- Organoaluminium Compounds.- Organoboron Compounds.- Organocalcium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogermanium Compounds.- Organoiron Compounds.- Organolead Compounds.- Organolithium Compounds.- Organomagnesium Compounds.- Organomercury Compounds.- Organophosphorus Compounds.- Organoselenium Compounds.- Organosodium Compounds.- Organosilicon Compounds.- Organotin Compounds.- Organozinc Compounds.- 3 Spectroscopic Techniques, Visible And Ultraviolet Spectroscopy.- A. Visible Spectroscopy.- B. Ultraviolet Spectroscopy.- 4 Other Spectroscopic Techniques.- Organoaluminium Compounds.- Organoboron Compounds.- Organochromium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogallium Compounds.- Organogermanium Compounds.- Organoiron Compounds.- Organolead Compounds.- Organolithium Compounds.- Organomanganese Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organophosphorus Compounds.- Organosilicon Compounds.- Organotin Compounds.- Organozinc Compounds.- 5 Polarographic Techniques.- Organoarsenic Compounds.- Organoboron Compounds.- Organochromium Compounds.- Organocobalt Compounds.- Organoiron Compounds.- Organolead Compounds.- Organomercury Compounds.- Organonickel Compounds.- Organophosphorus Compounds.- Organoselenium Compounds.- Organotin Compounds ,.- Organozinc Compounds.- 6 Gas Chromatography.- Organoaluminium Compounds.- Organoantimony Compounds.- Organoarsenic Compounds.- Organoberyllium Compounds.- Organoboron Compounds.- Organochromium Compounds.- Organocobalt Compounds.- Organocopper Compounds.- Organogallium Compounds.- Organogermanium Compounds.- Organoiron Compounds.- Organolead Compounds.- Organolithium Compounds.- Organomagnesium Compounds.- Organomanganese Compounds.- Organomercury Compounds.- Organomolybdenum Compounds.- Organophosphorus Compounds.- Organoruthenium Compounds.- Organo selenium Compounds.- Organosilicon Compounds.- Organotellurium Compounds.- Organotin Compounds.- Organozinc Compounds.- 7 Chromatography of Metal Chelates.- A. Introductory.- B. Gas Chromatography, Acetyl Acetonates.- C. Gas Chromatography, Fluorinated Acetylacetonates.- D. Gas Chromatography, Hexafluoroacetylacetonates.- E. Gas Chromatography, ß-Diketone Derivatives.- F. Gas Chromatography, Amino Substituted 3-Diketonates.- G. Gas Chromatography, DialkyIdithiophosphates.- H. Gas Chromatography, Salicyaldimes.- I. Gas Chromatography, Diethyldithiocarbamates.- J. Gas Chromatography, Non-chelated Metal Complexes.- K. Gas Chromatography, Metal Porphyrins.- L. Gas Chromotographic detection of Metal Chelates.- M. Gas Chromatography, Conclusions.- N. Liquid Chromatography of Metal Chelates.- O. SizeExclusion Chromatography of Metal Chelates.- P. High performance Thin-Layer Chromatography of Metal&Chelates.- Q. Index of Metal Analysis by Gas Chromatography of their&volatile Chelates.- R. Gas Chromatography.- S. High performance Liquid Chromatography.- T. Size-exclusion Chromatography.- U. High performance Thin-Layer Chromatography.- 8 Other Chromatographic Techniques.- A. Thin-layer Chromatography.- B. Paper Chromatography.- C. Column Chromatography.- D. Electrophoresis.- 9 Organometallic Compounds in the Environment.- A. Introductory.- B. Organometallic Compounds in Water.- C. Organometallic Compounds in Sediments.- D. Organometallic Compounds in Plants.- E. Organometallic Compounds in Biological Materials.- F. Organometallic Compounds in Air.- References.
