Chapter 4. Monohydric Alcohols, Their Ethers and Esters Introduction 1. Monohydric Alcohols a. Saturated Alcohols, Paraffin Alcohols or Alkanols, CnH2n+1OH b. Derivatives of Saturated Alcohols c. Unsaturated Alcohols 2. Ethers a. Saturated Ethers; Dialkyl Ethers, (CnH2n+1)2O b. Substituted Dialkyl Ethers c. Unsaturated Ethers 3. Alkyl Peroxides a. Alkyl Hydroperoxides, Ro.OH b. Dialkyl Peroxides, RO.OR' 4. Esters of Mineral or Inorganic Acids a. Esters of Boric Acid, Trialkyl Orthoborates b. Esters of Silicic Acid, Tetra-Alkoxysilanes c. Esters of Nitrous Acid, Alkyl Nitrites d. Esters of Nitric Acid e. Esters of Phosphorous Acid, Alkyl Phosphites and Related Compounds f. Esters of Phosphoric Acid, Alkyl Phosphates and Related Compounds g. Esters of Sulphurous Acid and Related Compounds h. Esters of Sulphuric Acid and Related Compounds i. Esters of Hypochlorous and Perchloric AcidsChapter 5. Sulphur Analogues of the Alcohols and Their Derivatives Introduction 1. Thiols, Mercaptans, or Alkyl Hydrosulphides 2. Sulphides or Thio-Ethers a. Dialkyl Sulphides, Alkylthioalkanes b. Olefinic Sulphides, Dialkenyl Sulphides or Thioethers, Alkenylthioalkenes c. Acetylenic Sulphides, Ethynyl Thioethers or Alkylthioalkynes 3. Derivatives of Alkanesulphenic Acids 4. Dialkyl Disulphides or Alkyldithioalkanes 5. Alkyl Polysulphides 6. Alkylthiosulphuric Acids 7. Sulphonium Compounds 8. Dialkyl Sulphoxides or Alkylsulphinylalkanes 9. Alkanesulphinic Acids 10. Sulphones 11. Alkanesulphonic Acids and Derivatives 12. Alkanethiosulphonic AcidsChapter 6. Nitrogen Derivatives of the Aliphatic Hydrocarbons 1. Nitro- and Nitroso-Compounds a. Nitroalkanes and Related Compounds b. Nitro-Olefins or Nitroalkenes c. Dinitroalkanes or Dinitroparaffins d. Polynitroalkanes e. Nitrosoalkanes and Derivatives f. Nitronitrosoalkanes, Pseudonitroles and Nitrolic Acids 2. Amines and Quaternary Ammonium Compounds a. Alkylamines b. Halogen-Substituted Alkylamines c. Nitroalkylamines d. Quaternary Ammonium Compounds e. Unsaturated Amines and Ammonium Compounds 3. N-Substituted Derivatives of the Alkylamines a. N-Halogenoalkylamines b. N-Oxygen Derivatives of the Alkylamines c. N-Sulphur Derivatives of the Alkylamines d. Boron, Silicon, Phosphorus, Arsenic, and Antimony Derivatives of Alkylamines e. Derivatives of Alkylamines with a Nitrogen-Nitrogen LinkageChapter 7. Aliphatic Organometallic and Organometalloidal Compounds 1. Introduction (i) History and Development of Organometallic Chemistry (ii) Nomenclature (iii) Carbon-Metal Bonding (iv) General Methods of Preparation Of Organometallic Compounds (v) General Physical Properties Of Organometallic Compounds (vi) Reactivity of Metal-Carbon Bonds (vii) Reactions of Metal and Metalloid Alkyls 2. Group IA: Lithium, Sodium, Potassium, Rubidium, Cesium a. Lithium b. Other Metals of Group IA 3. Group IIA: Beryllium, Magnesium, Calcium, Strontium, Barium; Group IIB: Zinc, Cadmium, Mercury a. Beryllium b. Magnesium c. Calcium, Strontium and Barium d. Zinc e. Cadmium f. Mercury 4. Group IIIB: Boron, Aluminum, Gallium, Indium, Thallium a. Boron b. Aluminum c. Gallium d. Indium e. Thallium 5. Group IVB: Silicon, Germanium, Tin, Lead a. Silicon b. Germanium, Tin, Lead 6. Group VB: Phosphorus, Arsenic, Antimony, Bismuth a. Phosphorus b. Arsenic c. Antimony d. Bismuth 7.
