Emerging Fluorinated Motifs

Volume I

Part I: Carbon-Linked Fluorine-Containing Motifs
Chapter 1: Difluoromethylation and Difluoroalkylation of (Hetero)Arenes. Access to Ar(Het)-CF2H and Ar(Het)-CF2R
Chapter 2: Difluoromethylation and Difluoroalkylation of Aliphatic Unsaturated C=C, CC,-NC Bonds
Chapter 3: Difluoromethylation and Difluoroalkylation at Csp3 Centres, C=O , C=C, and C=N Bonds
Chapter 4: Monofluoromethylation Reactions of Aliphatic Substrates and (Hetero)Arenes
Chapter 5: Synthesis of gem-Difluorocyclopropanes

Part II: Oxygen-Linked Fluorine-Containing Motifs
Chapter 6: Indirect Construction of the OCF3 Motif
Chapter 7: Reagents for Direct Trifluoromethoxylation
Chapter 8: Direct Trifluoromethoxylation of Aromatics and Heteroaromatics
Chapter 9: Direct Trifluoromethoxylation of Aliphatic Compounds
Chapter 10: Extension to the Construction of ORf Motifs (OCF2H, OCFH2, OCH2CF3, OCFHCH3)

Volume II
Part III: Sulfur-Linked Fluorine-Containing Motifs
Chapter 11: Indirect Trifluoromethylthiolation Methods
Chapter 12: Reagents for Direct Trifluoromethylthiolation
Chapter 13: Trifluoromethylthiolation of Aromatics and Heteroaromatic Compounds
Chapter 14: Synthesis of Trifluoromethylthiolated Alkenes and Alkynes
Chapter 15: Direct Trifluoromethylthiolation toward C(sp3)-SCF3 Compounds
Chapter 16: Extension to the SCF2H, SCH2F, and SCF2R motifs (R = PO(OEt)2, CO2R, Rf)
Chapter 17: Synthesis and Applications of Fluorinated Sulfoxides (RSORf) and Sulfones (RSO2Rf)
Chapter 18: Pentafluorosulfanylation of Aromatics and Heteroaromatics
Chapter19: Pentafluorosulfanylation of Aliphatic Substrates
Chapter 20: Extension to SF4CF3 and SF4FG Groups
Chapter 21: Properties & applications of sulfur(VI) fluorides
Chapter 22: Construction S-Rf Sulfilimines and S-Rf Sulfoximines

Part IV: Selenium-Linked Fluorine-Containing Motifs
Chapter 23: When Fluorine Meets Selenium

Part V: Nitrogen-Linked Fluorine-Containing Motifs
Chapter 24: Construction of N-CF2H, N-CF3, N-CH2CF3 Motifs

Part VI: Phosphorus-Linked Fluorine-Containing Motifs
Chapter 25: Synthesis and Applications of P-Rf-Containing Molecules