Macromolecular Self-Assembly

1 - Cover [Seite 1]
2 - Title Page [Seite 3]
3 - Copyright [Seite 4]
4 - Contents [Seite 5]
5 - List of Contributors [Seite 9]
6 - Preface [Seite 13]
7 - Chapter 1 A Supramolecular Approach to Macromolecular Self-Assembly: Cyclodextrin Host/Guest Complexes [Seite 17]
7.1 - 1.1 Introduction [Seite 17]
7.2 - 1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks [Seite 19]
7.2.1 - 1.2.1 CD Functionalization [Seite 19]
7.2.2 - 1.2.2 Suitable Guest Groups [Seite 21]
7.3 - 1.3 Supramolecular CD Self-Assemblies [Seite 23]
7.3.1 - 1.3.1 Linear Polymers [Seite 23]
7.3.2 - 1.3.2 Branched Polymers [Seite 28]
7.3.3 - 1.3.3 Cyclic Polymer Architectures [Seite 33]
7.4 - 1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward Nanostructures [Seite 33]
7.4.1 - 1.4.1 Micelles/Core-Shell Particles [Seite 33]
7.4.2 - 1.4.2 Vesicles [Seite 35]
7.4.3 - 1.4.3 Nanotubes and Fibers [Seite 36]
7.4.4 - 1.4.4 Nanoparticles and Hybrid Materials [Seite 37]
7.4.5 - 1.4.5 Planar Surface Modification [Seite 38]
7.5 - 1.5 Applications [Seite 39]
7.6 - 1.6 Conclusion and Outlook [Seite 42]
7.7 - References [Seite 42]
8 - Chapter 2 Polymerization-Induced Self-Assembly: The Contribution of Controlled Radical Polymerization to The Formation of Self-Stabilized Polymer Particles of Various Morphologies [Seite 49]
8.1 - 2.1 Introduction [Seite 49]
8.2 - 2.2 Preliminary Comments Underlying Controlled Radical Polymerization [Seite 52]
8.2.1 - 2.2.1 Introduction [Seite 52]
8.2.2 - 2.2.2 Major Methods Based on a Reversible Termination Mechanism [Seite 53]
8.2.3 - 2.2.3 Major Methods Based on a Reversible Transfer Mechanism [Seite 55]
8.3 - 2.3 Pisa Via CRP Based on Reversible Termination [Seite 56]
8.3.1 - 2.3.1 PISA Using NMP [Seite 56]
8.3.2 - 2.3.2 Using ATRP [Seite 62]
8.4 - 2.4 Pisa Via CRP Based on Reversible Transfer [Seite 64]
8.4.1 - 2.4.1 Using RAFT in Emulsion Polymerization [Seite 64]
8.4.2 - 2.4.2 Using RAFT in Dispersion Polymerization [Seite 77]
8.4.3 - 2.4.3 Using TERP [Seite 86]
8.5 - 2.5 Concluding Remarks [Seite 87]
8.6 - Acknowledgments [Seite 89]
8.7 - Abbreviations [Seite 89]
8.8 - References [Seite 91]
9 - Chapter 3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in Aqueous Solution [Seite 99]
9.1 - 3.1 Introduction [Seite 99]
9.2 - 3.2 Synthetic Strategies for The Preparation of Gradient Copolymers [Seite 102]
9.2.1 - 3.2.1 Preparation of Gradient Copolymers by Controlled Radical Copolymerization [Seite 103]
9.2.2 - 3.2.2 Preparation of Block-Gradient Copolymers Using Controlled Radical Polymerization [Seite 122]
9.3 - 3.3 Self-Assembly [Seite 126]
9.3.1 - 3.3.1 Gradient Copolymers [Seite 126]
9.3.2 - 3.3.2 Diblock-Gradient Copolymers [Seite 127]
9.3.3 - 3.3.3 Triblock-Gradient Copolymers [Seite 129]
9.4 - 3.4 Conclusion and Outlook [Seite 130]
9.5 - Abbreviations [Seite 131]
9.6 - References [Seite 133]
10 - Chapter 4 Electrostatically Assembled Complex Macromolecular Architectures Based on Star-Like Polyionic Species [Seite 141]
10.1 - 4.1 Introduction [Seite 141]
10.2 - 4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed with Linear Polyions [Seite 143]
10.3 - 4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic Amphiphilic Diblock Copolymers Complexed with Linear Polyions [Seite 146]
10.4 - 4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed with Linear Polyions [Seite 149]
10.5 - 4.5 Conclusions [Seite 153]
10.6 - Acknowledgment [Seite 153]
10.7 - References [Seite 153]
11 - Chapter 5 Solution Properties of Associating Polymers [Seite 157]
11.1 - 5.1 Introduction [Seite 157]
11.2 - 5.2 Structures of Associating Polyelectrolytes [Seite 158]
11.3 - 5.3 Associating Polyelectrolytes in Dilute Solutions [Seite 158]
11.3.1 - 5.3.1 Intramolecular Association [Seite 161]
11.3.2 - 5.3.2 Intermolecular Association [Seite 163]
11.4 - 5.4 Associating Polyelectrolytes in Semidilute Solutions [Seite 167]
11.5 - 5.5 Conclusions [Seite 171]
11.6 - References [Seite 171]
12 - Chapter 6 Macromolecular Decoration of Nanoparticles for Guiding Self-Assembly in 2D and 3D [Seite 175]
12.1 - 6.1 Introduction [Seite 175]
12.2 - 6.2 Guiding Assembly by Decoration with Artificial Macromolecules [Seite 176]
12.2.1 - 6.2.1 Decoration of Nanoparticles [Seite 177]
12.2.2 - 6.2.2 Distance Control in 2D and 3D [Seite 182]
12.2.3 - 6.2.3 Breaking the Symmetry [Seite 187]
12.3 - 6.3 Guiding Assembly by Decoration with Biomacromolecules [Seite 189]
12.3.1 - 6.3.1 DNA-Assisted Assembly [Seite 189]
12.3.2 - 6.3.2 Protein-Assisted Assembly [Seite 193]
12.4 - 6.4 Application of Assemblies [Seite 197]
12.5 - 6.5 Conclusions and Outlook [Seite 199]
12.6 - References [Seite 200]
13 - Chapter 7 Self-Assembly of Biohybrid Polymers [Seite 209]
13.1 - 7.1 Introduction [Seite 209]
13.1.1 - 7.1.1 Amphiphiles [Seite 210]
13.1.2 - 7.1.2 Packing Parameter and Interfacial Tension [Seite 211]
13.1.3 - 7.1.3 Interaction Forces in Self-Assembly [Seite 212]
13.2 - 7.2 Self-Assembly of Biohybrid Polymers [Seite 214]
13.2.1 - 7.2.1 Polymer-DNA Hybrids [Seite 214]
13.2.2 - 7.2.2 Polypeptide Block Copolymers [Seite 220]
13.2.3 - 7.2.3 Block Copolypeptides [Seite 221]
13.3 - 7.3 Self-Assembly Driven Nucleation Polymerization [Seite 223]
13.3.1 - 7.3.1 Polymer-DNA Hybrids [Seite 225]
13.3.2 - 7.3.2 Polymer-Peptide Hybrids [Seite 225]
13.3.3 - 7.3.3 DNA-Peptide Hybrids [Seite 228]
13.4 - 7.4 Self-Assembly Driven by Electrostatic Interactions [Seite 229]
13.4.1 - 7.4.1 DNA/Polymer Bio-IPECs [Seite 232]
13.4.2 - 7.4.2 DNA/Copolymer Bio-IPECs [Seite 232]
13.5 - 7.5 Conclusion [Seite 234]
13.6 - References [Seite 235]
14 - Chapter 8 Biomedical Application of Block Copolymers [Seite 247]
14.1 - 8.1 Introduction [Seite 247]
14.2 - 8.2 Diblock and Triblock Copolymers [Seite 250]
14.3 - 8.3 Graft and Statistical Copolymers [Seite 256]
14.4 - 8.4 Concluding Remarks [Seite 261]
14.5 - Acknowledgment [Seite 261]
14.6 - References [Seite 261]
15 - Index [Seite 267]
16 - EULA [Seite 275]