Comprehensive Chiroptical Spectroscopy

Comprehensive Chiroptical Spectroscopy, Volume 1
PREFACE ix
CONTRIBUTORS xi
PART I INTRODUCTION 1
1 ON THE INTERACTION OF LIGHT WITH MOLECULES: PATHWAYS TO THETHEORETICAL INTERPRETATION OF CHIROPTICAL PHENOMENA 3
Georges H. Wagnière
PART II EXPERIMENTAL METHODSANDINSTRUMENTATION 35
2 MEASUREMENT OF THE CIRCULAR DICHROISM OF ELECTRONICTRANSITIONS 37
John C. Sutherland
3 CIRCULARLY POLARIZED LUMINESCENCE SPECTROSCOPY ANDEMISSION-DETECTED CIRCULAR DICHROISM 65
James P. Riehl and Gilles Muller
4 SOLID-STATE CHIROPTICAL SPECTROSCOPY: PRINCIPLES ANDAPPLICATIONS 91
Reiko Kuroda and Takunori Harada
5 INFRARED VIBRATIONAL OPTICAL ACTIVITY: MEASUREMENT ANDINSTRUMENTATION 115
Laurence A. Nafie
6 MEASUREMENT OF RAMAN OPTICAL ACTIVITY 147
Werner Hug
7 NANOSECOND TIME-RESOLVED NATURAL AND MAGNETIC CHIROPTICALSPECTROSCOPIES 179
David S. Kliger, Eefei Chen, and Robert A. Goldbeck
8 FEMTOSECOND INFRARED CIRCULAR DICHROISM AND OPTICAL ROTATORYDISPERSION 203
Hanju Rhee and Minhaeng Cho
9 CHIROPTICAL PROPERTIES OF LANTHANIDE COMPOUNDS IN AN EXTENDEDWAVELENGTH RANGE 221
Lorenzo Di Bari and Piero Salvadori
10 NEAR-INFRARED VIBRATIONAL CIRCULAR DICHROISM: NIR-VCD247
Sergio Abbate, Giovanna Longhi, and Ettore Castiglioni
11 OPTICAL ROTATION AND INTRINSIC OPTICAL ACTIVITY 275
Patrick H. Vaccaro
12 CHIROPTICAL IMAGING OF CRYSTALS 325
John Freudenthal, Werner Kaminsky, and Bart Kahr
13 NONLINEAR OPTICAL SPECTROSCOPY OF CHIRAL MOLECULES 347
Peer Fischer
14 IN SITU MEASUREMENT OF CHIRALITY OF MOLECULES ANDMOLECULAR ASSEMBLIES WITH SURFACE NONLINEAR SPECTROSCOPY 373
Hong-fei Wang
15 PHOTOELECTRON CIRCULAR DICHROISM 407
Ivan Powis
16 MAGNETOCHIRAL DICHROISM AND BIREFRINGENCE 433
G. L. J. A. Rikken
17 X-RAY DETECTED OPTICAL ACTIVITY 457
Jose Goulon, Andrei Rogalev, and Christian Brouder
18 LINEAR DICHROISM 493
Alison Rodger
19 ELECTRO-OPTICAL ABSORPTION SPECTROSCOPY 525
Hans-Georg Kuball and Matthias Stolte
PART III THEORETICAL SIMULATIONS 541
20 INDEPENDENT SYSTEMS THEORY FOR PREDICTING ELECTRONIC CIRCULARDICHROISM 543
Gerhard Raabe, Joerg Fleischhauer, and Robert W. Woody
21 AB INITIO ELECTRONIC CIRCULAR DICHROISM AND OPTICALROTATORY DISPERSION: FROM ORGANIC MOLECULES TO TRANSITION METALCOMPLEXES 593
Jochen Autschbach
22 THEORETICAL ELECTRONIC CIRCULAR DICHROISM SPECTROSCOPY OFLARGE ORGANIC AND SUPRAMOLECULAR SYSTEMS 643
Lars Goerigk, Holger Kruse, and Stefan Grimme
23 HIGH-ACCURACY QUANTUM CHEMISTRY AND CHIROPTICAL PROPERTIES675
T. Daniel Crawford
24 AB INITIO METHODS FOR VIBRATIONAL CIRCULAR DICHROISMAND RAMAN OPTICAL ACTIVITY 699
Kenneth Ruud
25 MODELING OF SOLVATION EFFECTS ON CHIROPTICAL SPECTRA729
Magdalena Pecul
26 COMPLEXATION, SOLVATION, AND CHIRALITY TRANSFER INVIBRATIONAL CIRCULAR DICHROISM 747
Valentin Paul Nicu and Evert Jan Baerends
INDEX 783