Electrophilic Substitution at a Saturated Carbon Atom

Name: Electrophilic Substitution at a Saturated Carbon Atom
Brand: Elsevier
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Bamford(Autor*in)

C. H. Bamford R. G. Compton C. F. H. Tipper(Herausgeber*in)

Elsevier (Verlag)

Erschienen am 14. Mai 2014

271 Seiten

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Front Cover
Comprehensive Chemical Kinetics, Volume 12
Copyright Page
Contents
Preface
Chapter 1. Introduction
REFERENCES
Chapter 2. The formation and reactions of carbanions
1. GENERAL THERMODYNAMIC CONSIDERATIONS
2. FORMATION OF CARBANIONS FROM HYDROCARBONS
3. REACTIONS AND PROPERTIES OF CARBANIONS
REFERENCES
Chapter 3. Mechanisms of electrophilic substitution at saturated carbon
1. THE FUNDAMENTAL MECHANISMS
2. SUBSTITUTION WITH REARRANGEMENT
3. MECHANISMS INVOLVING NUCLEOPHILIC OR ANIONIC CATALYSIS
REFERENCES
Chapter 4. The unimolecular mechanism. SE1
1. SUBSTITUTIONS IN ORGANOMERCURY COMPOUNDS
2. SUBSTITUTIONS IN OTHER ORGANOMETALLIC COMPOUNDS
REFERENCES
Chapter 5. Mercury-for-mercury exchanges
1. THE ONE-ALKYL MERCURY-FOR-MERCURY EXCHANGE
2. THE TWO-ALKYL (Syn-PROPORTIONATION) MERCURY-FOR-MERCURY EXCHANGE
3. THE TWO-ALKYL (SYMMETRISATION) MERCURY-FOR-MERCURY EXCHANGE
4. THE THREE-ALKYL MERCURY-FOR-MERCURY EXCHANGE
REFERENCES
Chapter 6. Other metal-for-metal exchanges
1. SUBSTITUTION OF ALKYL-METAL COMPOUNDS BY METAL SALTS
2. ALKYL EXCHANGES BETWEEN COMPOUNDS RnM AND RmM'
REFERENCES
Chapter 7. Acidolysis of organometallic compounds
1. STEREOCHEMICAL STUDIES
2. ACIDOLYSIS OF ORGANOMAGNESIUM CONPOUNDS
3. ACIDOLYSIS OF DIALKYLZINCS AND OF DIALKYLCADMIUMS
4. ACIDOLYSES OF ORGANOMERCURY COMPOUNDS
5. ACIDOLYSIS OF TRIETHYLBORON BY CARBOXYLIC ACIDS
6. ACIDOLYSIS OF THE ALKYLS OF METALS IN GROUP IVA
7. ACIDOLYSIS OF THE ALKYLS OF METALS IN GROUP VIII AND GROUP V I B
REFERENCES
Chapter 8. Halogenolysis (halogenodemetallation) of organometallic compounds
1. STEREOCHEMICAL STUDIES
2. HALOGENOLYSIS OF ORGANOMERCURY COMPOUNDS
3. HALOGENOLYSIS OF TETRAALKYLTINS
4. HALOGENOLYSIS OF TETRAALKYLLEADS
5. IODINE BROMIDE CLEAVAGE OF TETRAALKYLTINS
6. SOLVENT EFFECTS ON THE IODINOLYSIS OF TETRAALKYTINS AND TETRAALKYLLEADS
REFERENCES
Chapter 9. Other electrophilic substitutions of organometallic compounds
1. THE STEREOCHEMICAL COURSE OF CARBONATION OF ALKYLLITHIUM AND ALKYLMAGNESIUM COMPOUNDS
2. ADDITION REACTIONS OF ORGANOMAGNESIUM COMPOUNDS
3. THE REACTION BETWEEN DIALKYLZINCS AND BENZALDEHYDE
4. ALKYLATION OF TRIARYLBROMOMETHANE BY ALKYLMERCURIC HALIDES
5. CLEAVAGES OF ALKYLBORONIC ACIDS
6. ADDITION OF TRIALKYLALUMINIUMS TO NITRILES, ESTERS, AND KETONES
7. DISPROPORTIONATION OF T'ETRAALKYLSILANES CATALYSED BY ALUMINIUM BROMIDE
8. THE OXIDATION OF TETRAALKYLTINS BY CHROMIUM TRIOXIDE IN SOLVENT ACETIC ACID
9. THE DISPLACEMENT OF COBALT(III) AND CHROMIUM(III) FROM PYRIDIOMETHYLCOBALTATE IONS AND -CHROMIUM(III) IONS BY NITROSATING AGENTS
REFERENCES
Chapter 10. Electrophilic substitutions of allyl-metal compounds
1. BASE CATALYSED SE1 CLEAVAGE OF 3-PHENALLYLSILICON AND -TIN COMPOUNDS
2. METAL-FOR-METAL EXCHANGES OF ALLYL-METAL COMPOUNDS
3. ACIDOLYSIS OF ALLYL-METAL COMPOUNDS
4. HALOGENOLYSIS (HALOGENODEMETALLATION) OF ALLYL-METAL COMPOUNDS
REFERENCES
Chapter 11. Constitutional effects, salt effects, and solvent effects in electrophilic substitution at saturated
1. ENTROPIES OF ACTIVATION AS A CRITERION OF MECHANISM SUBSTITUTION BY MECHANISM SE2
2. CONSTITUTIONAL INFLUENCES IN THE ELECTROPHILIC REAGENT
3. CONSTITUTIONAL INFLUENCES IN THE SUBSTRATE
4. SALT EFFECTS AND CO-SOLVENT EFFECTS IN ELECTROPHILIC SUBSTITUTION AT SATURATED CARBON
5. SOLVENT EFFECTS AND CONSTITUTIONAL EFFECTS OF THE SUBSTRATE, IN ELECTROPHILIC SUBSTITUTION AT SATURATED CARBON
6. METAL-METAL BONDING IN SE2 TRANSITION STATES
REFERENCES
Index

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