Organosilicon Chemistry

Name: Organosilicon Chemistry | From Molecules to Materials
Brand: Wiley-VCH
Price: 57.99 EUR
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From Molecules to Materials

Norbert Auner Johann Weis(Herausgeber*in)

Wiley-VCH (Verlag)

1. Auflage

Erschienen am 22. September 2011

XXII, 349 Seiten

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978-3-527-62041-8 (ISBN)

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Organosilicon Chemistry From Molecules to Materials
Contents
Tetravalent Organosilicon Compounds: Chemistry and Structure
Introduction
Structures of Small Silicon Containing Compounds - Why and How?
Sterically Overcrowded Organosilicon Compounds and their Properties
Synthesis of Functionally Substituted Oligosilanes Based on Silyltriflate Derivatives
Electroreductive Formation of Di- and Polysilanes
Linear Tetrasilanes with Internal Substituents: Oligosilanes with Optical Activity
A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes
29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H6-n and XnSi3H8-n (X = Br, I)
Calculation of the 29 Si NMR Chemical Shifts in Molecules with SIN, SiCl, and SiSi Bonds
Reactivity of Very Electron-Rich Organosilyl Amines
Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes
Fluorofunctional Silylamines and -Hydrazines Precursors for (Si-N) Ring Systems
New Approaches to (Fluoromethyl)silanes
Homo- and heterocyclic Si-O-Systems . Rings and Cages
Silaheterocycles from Intramolecular Reactions of Silicon-functionalized Diazoacetic Esters
Synthesis and Reaction Behavior of Organoalkoxysilylphenols
N-Silylation: New Possibilities for Long-known Amines
On the Acid-catalyzed Reaction of Siloxanes with Alcohols
On the Reactivity of Chlorosiloxanes
Chlorosilanols - more stable than you think - shown with 29Si NMR
Diorganosilyl-bis(O-alkylphosphonates)
Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity
Introduction
Basic Principles of the Theory of Bonding in Silicon Compounds
Expectations from an Unusual Compound: The Chemistry of Decamethylsilicocene
Cp*2Si(CO) and CP*2Si(N2): Complexes of Decamethylsilicocene
Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry
Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?
Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines
Reactions of Silaethenes in the Gas Phase and in Solution
The Reaction of Vinylsilanes with Lithium Metal
Small Silicon Ring Compounds: Formation and Reactions
Matrix Photolysis of Simple Azidosilanes
Low-coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes
Unusual Coordination in Phosphorus-Silicon Compounds
Unsaturated Silicon Compounds: Matrix IR Investigations and Quantum Chemical Calculations
Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry
Introduction
Reactivity of Penta- and Hexacoordinated Silicon Species
Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon Centers
Organosilicon Metal Compounds: Coordination Chemistry and Catalysis
Introduction
A Silane-induced CO-Activation and CC-Coupling Reaction: Modeling of Active Surface Sites
Organometal Fragment Substituted Silanols, Siloxanes and Silylamines
On the Complex Chemistry of Cyclopentadienyl Ligands with Oligoethylene Glycol Ether Tentacles
Heterometallic Complexes with a Bridging Alkoxysilyl Ligand: ?2-µ2-Si(OR)3
Silicon-containing Main Group Transition Metal Complexes
Silicon-containing Bimetallics Fe-M (M = Ni, Pd, Pt) with M-Coordinated Organic Ligands
Anionic Transition Metal Silyl Complexes: New Building Blocks in Coordination Chemistry
Synthesis and Characterization of New Transition Metal-Silicon Compounds
The Silicon Effect in Metallic Silylamides
New Chemistry for Reactive Transition-Metal Silicon Bonds
Organosilane Chemistry at Tailor-made Platinum Centers
Silicon Polymers: Formation and Application
Introduction
Regioselectivity in Hydrosilylation Reactions
Network Characterization of Photocross-linked Silicone Acrylates
Photocross-linking of a,?-Vinyl Terminated Silicones with Silicones Containing Pendant Mercapto Groups
Investigations into the Relaxation Behavior of Polymer Siloxanes
Dicyclopentadienyl Units Containing Silicone Surfactants
Applications of Transition Metal Compounds in the Preparation of Useful Silicon-containing Ceramics
New Ways to Polysilanes . Starting Compounds for New Silicon Materials
Anionic Polymerization of Masked Disilenes: Mechanism, Scope, and Applications
Ceramic Fibers from Organosilicon Polymers
Novel Multifunctional (Meth)acrylate Alkoxysilanes as Precursors for Inorganic-Organic Copolymers
Processing, Properties and Structural Development of Polymer-derived Fiber-reinforced Sic
Metal/SiO2 Nanocomposites by Sol-Gel Processing
Organically Modified SiO2 Aerogels
Spectroscopic Investigations on Silylated Inorganic Substrates
Materials for Optical Data Processing
Thick Siloxane Films from Tetraethoxysilane on Silicon Wafers
Chemical Relaxation of SiH4, Si2H6, SiH2, and H2 in Low Pressure Discharges
Kinetic and Mass Spectroscopic Investigations of Plasma Induced Deposition of Silicion Dioxide from Tetraethylorthosilicate and Oxygen
Author Index and Subject Index

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