Advances in Organometallic Chemistry

Name: Advances in Organometallic Chemistry
Brand: Academic Press
Price: 54.95 EUR
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Academic Press

Erschienen am 18. Mai 1990

318 Seiten

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978-0-08-058031-9 (ISBN)

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Front Cover
Advances in Organometallic Chemistry, Volume 30
Copyright Page
Contents
Chapter 1. Chemistry of the Cyclopentadienyl Bisphosphine Ruthenium Auxiliary
I. Introduction
II. Preparation of Cyclopentadienyl Bisphosphine Ruthenium Complexes
III. Geometry of (?5-C5H5)(PR3)2RuCl
IV. Exchange Reactions of PPh3 in (?5-C5H5)(PPh3)2RuX
V. Exchange Reactions of X in (?5-C5H5)(PR3)2RuX
VI. Ruthenium Acetylide, Vinylidene, and Carbene Complexes
VII. Decomplexation Reactions
VIII. Preparation of Ruthenium Complexes Containing ?2-Unsaturated Ligands
IX. Oligomerization Reactions
X. Orthometallation Reactions
References
Chapter 2. Thermochromic Distibines and Dibismuthines
I. Introduction
II. Historical Perspective
III. Synthesis and Chemical Properties
IV. Ultraviolet (UV) and Diffuse Reflectance Spectra
V. Structure
VI. Theory and Bonding
VII. Raman Spectra, Electron Diffraction, and Mössbauer Spectra
VIII. Comparison with Similar Compounds
IX. Concluding Remarks
References
Chapter 3. Syntheses, Structures, Bonding, and Reactivity of Main Group Heterocarboranes
I. Introduction
II. General View of Bonding and Structural Relationships
III. Stability
IV. Structural Nomeneclature
V. Heterocarboranes of Group 2 Elements
VI. Heterocarboranes of Group 13 Elements
VII. Heterocarboranes of Group 14 Elements
VIII. Heterocarboranes of Group 15 Elements
IX. Heterocarboranes of Group 16 Elements
X. Summary
References
Chapter 4. ?2 Coordination of Si-H s Bonds to Transition Metals
I. Introduction
II. The (?-C5R'5)L2Mn(H)SiR3 System
III. Dinuclear Metal Complexes with Bridging M-H-Si Interactions
IV. Other Complexes Possibly Containing M-H-Si Three-Center Bonds
V. ?2-SiH and ?2-CH Complexes: A Comparison
References
Chapter 5. Isoelectronic Organometallic Molecules
I. Introduction
II. Isoelectronic Definitions
III. Simple Ligands
IV. Polyhapto Ligands
V. Clusters
VI. Conclusions
References
Chapter 6. Dissociative Pathways in Substitution at Silicon in Solution: Silicon Cations R3Si+, R3SI+ Nu, and Silene-Type Species R2Si=X as Intermediates
I. Introduction
II. Silylenium Ion Intermediates
III. Silene-Type Species in Elimination-Addition Reactions
IV. Borderline SN1-SN2 Mechanisms
V. Tetracoordinate Silicon Cations as Intermediates in Nucleophile-Assisted Substitution at Silicon
VI. Final Remarks
References
Index
Cumulative List of Contributors

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