Advances in Organometallic Chemistry

Name: Advances in Organometallic Chemistry
Brand: Academic Press
Price: 180.0 EUR
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Academic Press

Erschienen am 31. Juli 2001

296 Seiten

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Front Cover
Advances in Organometallic Chemistry
Copyright Page
Contents
Contributors
Chapter 1. The Chemical and Catalytic Reactions of Hydrido-chloro-carbonylbis (triisopropylphosphine)osmium(II) and Its Major Derivatives
I. Introduction
II. Spectroscopic Features and Coordination Polyhedron of OsHCl(CO)(Pi Pr3)2
III. Addition Reactions to OsHCl(CO)(Pi Pr3)2: Formation of Six-Coordinate Hydrido-Chloro-Carbonyl Derivatives
IV. Addition of the Os--H Bond of OsHCl(CO)(Pi Pr3)2 to Carbon-Carbon Triple Bonds: Formation of Alkenyl Derivatives
V. Formation of Hydride-Vinylidene Complexes by Addition of Terminal Alkynes to OsHCl(CO)(Pi Pr3)2
VI. Formation of Dienyl Complexes by Reaction of OsHCl(CO)(Pi Pr3)2 with Enynes
VII. Reactions of OsHCl(CO)(Pi Pr3)2 with Alkynols: Formation of a,ß-Unsaturated Carbene Complexes
VIII. Reactions of OsHCl(CO)(Pi Pr3)2 with HX Molecules: Formation of Dihydrogen Derivatives
IX. The Complex OsCl2( n2-H2)(CO)(Pi Pr3)2 as Precursor of Carbene, Alkenyl-Carbene,and u -Bis-Carbene Derivatives
IX. The Complex OsCl2(?2-H2)(CO)(Pi Pr3)2 as Precursor of Carbene, Alkenyl-Carbene,and µ-Bis-Carbene Derivatives
X. Reaction of OsHCl(CO)(Pi Pr3)2 with n-BuLi. The Chemistry of the Dihydride OsH2(CO)( 2-CH2==CHEt)(Pi Pr3)2
XI. Reactions of OsH2(?2-H2)(CO)(Pi Pr3)2 with Alkynes: Alkynyl and Related Compounds
XII. Reaction of OsHCl(CO)(Pi Pr3)2 with NaBH4: The Chemistry of OsH(?2-H2BH2)(CO)(Pi Pr3)2
XIII. Decomposition of OsH(?2-H2BH2)(CO)(Pi Pr3)2 in the Presence of Alcohols: Synthesis and Reactions of Hydride-Alkyl Compounds
XIV. Reactions of OsHCl(CO)(Pi Pr3)2 with C5H6 and Na[HBpz3]: Cyclopentadienyl and Tris(pyrazolyl)borate Compounds
XV. Reactions of OsHCl(CO)(Pi Pr3)2 with NaXR (X=O, S)
XVI. Other Metathetical Reactions on the Chloride Ligand of OsHCl(CO)(Pi Pr3)2
XVII. OsHCl(CO)(Pi Pr3)2 as a Homogeneous Catalyst
XVIII. Final Remarks
References
Chapter 2. Chemistry of o-Carboranyl Derivatives
I. Introduction
II. Group IV-B Derivatives (Si, Ge, Sn) of o-Carborane
III. Metal Compounds Containing an X,Y-Carboranyl Chelating Ligand
IV. Metal Compounds Containing a Dithiolato-o-Carborane
V. Reactivity of o-Carborane
VI. Ligand Design Derived from o-Carborane
VII. Concluding Remarks
References
Chapter 3. The Chemistry of Borabenzenes (1986-2000)
I. Introduction
II. Synthesis of Neutral Borabenzene-Ligand Adducts
III. Synthesis of Anionic Boratabenzenes
IV. Boratabenzenes: Structure and Bonding
V. Reactivity of Transition Metal Complexes of Boratabenzenes
VI. Conclusion
References
Chapter 4. Recent Advances in the Chemistry of Group 14-Group 16 Double Bond Compounds
I. Introduction
II. Theoretical Aspects
III. Synthetic Methods
IV. Structures and Physical Properties
V. Reactivities
VI. Concluding Remarks
References
Chapter 5. The M-C Bond Functionalities Bonded to an Oxo-Surface Modeled by Calix[4]arenes
I. Introductory Remarks: Scope and Limits
II. Introduction
III. Metalation of Calix[4]arenes and O-Alkylated Calix[4]arenes Using Transition Metals
IV. Low-Valent Metalla-Calix[4]arenes
V. The Organometallic Functionalization of the Metalla-Calix[4]arenes
References
Chapter 6. From AIX/GaX Monohalide Molecules to Metalloid Aluminum and Gallium Clusters
I. Introduction
II. Cocondensation Technique and Synthesis of Metastable AlX or GaX Solutions
III. Metalloid Al Clusters
IV. Metalloid Ga Clusters
V. Conclusions and Outlook
References
Chapter 7. Multiple Bonds Involving Aluminum and Gallium Atoms
I. Introduction
II. Organoaluminum Compounds Containing Multiple Bonds
III. Organogallium Compounds Containing Multiple Bonds
IV. Conclusion
References
Index
Cumulative List of Contributors for Volumes 1-36
Cumulative Index for Volumes 37-47

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