Advances in Catalysis

Name: Advances in Catalysis
Brand: Academic Press
Price: 54.95 EUR
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Academic Press

Erschienen am 1. Dezember 1983

506 Seiten

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978-0-08-056536-1 (ISBN)

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Inhalt

Cover
Copyright
Contents
Contributors
Preface
Chapter 1. Characterization and Reactivity of Molecular Oxygen Species on Oxide Surfaces
I. Introduction
II. Neutral Oxygen Species
III. Characterization of Charged Dioxygen Species
IV. Formation and Stability of Charged Diatomic Species.
V. Oxygen Ions Containing More Than Two Nuclei
VI. Reactivity of Molecular Ions
VII. The Relation of Mononuclear Surface Oxygen Species to Electron Spectroscopic and Catalysis Studies
VIII. Comparison of Oxygen Species and Their Role in Catralytic Reactions
Appendix A. Summary of gzz Values for O2- on Surfaces
Appendix B. The Experimental 17O Hyperfine Parameters (in gauss) of Diatomic Oxygen Species (O2- and ROO)
Appendix C. Characterization of Oxygen Species by Infrared Spectroscopy References
References
Note Added in Proof
Chapter 2. Catalysis by Alloys in Hydrocarbon Reactions
I. Introduction
II. Alloys
III. Particle Size Effects.
IV. Mechanism of Hydrocarbon-Hydrogen Reactions
V. Hydrocarbon Reactions on Alloys
VI. Conclusions
References
Chapter 3. Modified Raney Nickel (MRNi) Catalyst: Heterogeneous Enantio-Differentiating (Asymmetric) Catalyst
I. What Is MRNi?
II. History of Discovery and Development of MRNi
III. Profile of MRNi in Hydrogenation
IV. Profile of MRNi in Stereo-Differentation
V. Other Profiles
VI. Surface Conditions
VII. Mechanism of Enantio-Differentiation
VIII. Characterization of Catalyst by Modifying Techinque
IX. TA-NaBr-MRNi
X. Other Investigations
References
Chapter 4. Analysis of the Possible Mechanisms for a Catalytic Reaction System
I. Introduction
II. The Structure of a Chemical System
III. General Formulas for Mechanisms and Reactions
IV. A Procedure for Finding Every Direct Mechanism
V. Systems with a Simple Overall Reaction
VI. Overall Reactions with a Multiplicity Greater Than One
VII. Discussion
List of Symbols
References
Chapter 5. Homogeneous Catalytic Hydrogenation of Carbon Monoxide: Ethylene Glycol and Ethanol from Synthesis Gas
I. Introduction
II. Cobalt Catalysts
III. Rhodium Catalysts
IV. Unpromoted and Carboxylic Acid-Promoted Ruthenium Catalysts
V. Lewis Base-Promoted Ruthenium Catalysts
VI. Other Catalysts
VII. Conclusions
References
Chapter 6. Cyclodextrins and Cyclophanes as Enzyme Models
I. Introduction
II. Basic Principles of Molecular Recognition
III. Enhancement of Binding and Catalysis by Host Design
IV. Enhancement of Binding and Catalysis by Guest Design
V. Conclusion
References and Notes
Author Index
Subject Index
Contents of Previous Volumes

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