Macromolecules Containing Metal and Metal-Like Elements, Volume 2

Name: Macromolecules Containing Metal and Metal-Like Elements, Volume 2 | Organoiron Polymers
Brand: Wiley
Price: 213.99 EUR
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Organoiron Polymers

Alaa S. Abd-El-Aziz Charles E. Carraher Charles U. Pittman John E. Sheats Martel Zeldin(Herausgeber*in)

Wiley (Verlag)

Erschienen am 20. November 2003

304 Seiten

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Inhalt

Intro
Macromolecules Containing Metal and Metal-Like Elements Volume 2
Contributors
Contents
Preface
Series Preface
1. Overview of Organoiron Polymers
I. Introduction
II. Ferrocene-Based Polymers
III. Polymers Containing Cyclopentadienyliron-Complexed Arenes
IV. Polymers Containing Iron Carbonyl Complexes
V. Iron Polyynes
VI. Polymers with Iron-Iron Bonds
VII. Outlook
VIII. References
2. Synthesis and Properties of Hyperbranched Polyferrocenylenesilynes
I. Introduction
II. Polymer Synthesis
III. Structural Characterization
IV. Electronic and Thermal Transitions
V. Pyrolytic Ceramization
VI. Ceramic Composition
VII. Magnetic Susceptibility
VIII. Summary and Perspectives
IX. Experimentation
A. Materials
B. Instrumentation
C. Polymerization
D. Ceramization
X. Acknowledgments
XI. References and Notes
3. Ring-Opened Polyferrocenes: Metal-Containing Polymers for Materials Science, Self-Assembly, and Nanostructure Applications
I. Introduction
II. Properties of Polyferrocenylsilanes
III. Water-Soluble PFS Derivatives for Layer-by-Layer Self-Assembly Applications
IV. Metal-Containing Block Copolymers: Formation of Self-Assembled, Supramolecular Materials and Nanoscopic Ceramic Patterns
V. Summary
VI. Acknowledgments
VII. References
4. Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers
I. Introduction
II. Results and Discussion
A. Synthesis and Aqueous Micellization of PFS-PDMAEMA
B. Synthesis and Micellization of PFP-PFS-PDMS
III. Summary and Outlook
IV. References
5. Synthesis and Self-Assembly of Polyisoprene-block-Polyferrocenyldimethylsilane Diblock Copolymers: Fabrication of Ceramic Nanolines on Semiconducting Substrates
I. Introduction
II. Experimental
III. Results and Discussion
A. Block Copolymer Synthesis
B. PI-b-PFDMS Micelles
C. Fabrication of Ceramic Nanolines
IV. Conclusions
V. Acknowledgments
VI. References
6. Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-by-Layer Deposition
I. Introduction
II. Synthesis of Polyferrocenylsilane Polyions
III. Polymer Characterization
IV. Multilayer Characterization
V. Patterned Polyferrocenylsilane Multilayer Thin Films
VI. Summary
VII. Experimentation
VIII. Acknowledgment
IX. References
7. Metal-Containing Polymers for High-Performance Resist Applications
I. Introduction
II. Organic Resists
A. Chemical Amplification
III. Inorganic Resists
IV. Organic-Inorganic Composite Resists
V. Organometallic Polymers
A. Polyferrocenyldimethylsilane as Reactive Ion Etch Barrier
B. Printing of Organometallic Polymers by Soft Lithography
1. Directed Dewetting
VI. Organic-Organometallic Block Copolymers
A. Structure Formation via Block Copolymer Self-Assembly
1. Synthesis of Organometallic-Organic Block Copolymers
2. Periodic Nanodomain Structures
3. Thin Films of Block Copolymers
4. Self-Assembling Resists
VII. Conclusions and Outlook
VIII. Acknowledgment
IX. References
8. Proton-Coupled Intramolecular Electron Transfer in Ferrocene-Quinone Conjugated Oligomers and Polymers
I. Introduction
II. Ethynylene-Bridged Ferrocene-Anthraquinone (FcAq) Complexes
A. Transition Metal Complexes Containing Allenylidene and Cumulenylidene
B. 1-1-FcAq Complexes
C. 2-1-FcAq Complexes
D. A 1-2-FcAq Complex
E. Polymeric 1-1-FcAq Complexes
III. Vinylene-Bridged Ferrocene-Benzoquinone Complex
IV. Concluding Remarks
V. References
9. Organization of Ferrocenoyl Amino Acids
I. Introduction
II. Synthesis of Ferrocenoyl Peptides
III. Structure of Ferrocenoyl Peptides
A. General Parameters
B. Hydrogen Bonding and Ordering in the Solid State
IV. Monolayers of Ferrocene Peptide Conjugates
V. Summary
VI. Acknowledgments
VII. References
10. Polyaromatic Ethers and Thioethers Coordinated to Cyclopentadienyliron Cations
I. Introduction
II. Linear Polyaromatic Ethers, Thioethers, and Amines
A. Polyethers
B. Polythioethers
C. Copolymers with Ether-Thioether and Amine-Thioether Spacers
III. Star-Shaped Polyaromatic Ethers
IV. Polymers Containing Neutral and Cationic Cyclopentadienyliron Moieties in Their Structures
V. Polymers Containing Azobenzene Chromophores in Their Sidechains
VI. Conclusions
VII. References
11. Polymerization of Olefinic Monomers Functionalized with Cationic Cyclopentadienyliron Arene Complexes
I. Introduction
II. Methacrylates
A. Radical Polymerization of the Methacrylate Groups
B. Substitution Polymerization of Chloroarene Complexes
C. Crosslinking
III. Styrenes
A. Radical Polymerization of the Styrene Groups
B. Substitution Polymerization of Chloroarene Complexes
C. Crosslinking
IV. Norbornenes
A. Ring-Opening Metathesis Polymerization of the Norbornene Groups
B. Substitution Polymerization of Chloroarene Complexes
C. Crosslinking
V. Conclusions
VI. References
Index

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