Preface to the Wiley Series on Electrocatalysis and Electrochemistry vii
Foreword ix
by Masatoshi Osawa
Preface xi
Contributors xiii
Part One Nonlinear Vibrational Spectroscopy
1. Water Hydrogen Bonding Dynamics at Charged Interfaces Observed with Ultrafast Nonlinear Vibrational Spectroscopy 3
Emily E. Fenn and Michael D. Fayer
2. SFG Studies of Oxide-Water Interfaces: Protonation States, Water Polar Orientations, and Comparison with Structure Results from X-Ray Scattering 48
Y. Ron Shen and Glenn A. Waychunas
3. Vibrational Sum Frequency Generation Spectroscopy of Interfacial Dynamics 85
Christopher M. Berg and Dana D. Dlott
4. Spectroscopy of Electrifi ed Interfaces with Broadband Sum Frequency Generation: From Electrocatalysis to Protein Foams 120
Björn Braunschweig, Prabuddha Mukherjee, Robert B. Kutz, Armin Rumpel, Kathrin
Engelhardt, Wolfgang Peukert, Dana D. Dlott, and Andrzej Wieckowski
Part Two Raman Spectroscopy
5. Surface-Enhanced Resonance Raman Scattering (SERRS) Studies of Electron-Transfer Redox-Active Protein Attached to Thiol-Modified Metal: Case of Cytochrome c 153
Agata Królikowska
6. Depolarization of Surface-Enhanced Raman Scattering Photons from a Small Number of Molecules on Metal Surfaces 220
Fumika Nagasawa, Mai Takase, Hideki Nabika, and Kei Murakoshi
Part Three IRRAS Spectroscopy (Including PM-IRRAS)
7. DFT and In Situ Infrared Studies on Adsorption and Oxidation of Glycine, l-Alanine, and l-Serine on Gold Electrodes 241
Andrea P. Sandoval, José Manuel Orts, Antonio Rodes, and Juan M. Feliu
8. Composition, Structure, and Reaction Dynamics at Electrode-Electrolyte Interfaces Using Infrared Spectroscopy 266
Angel Cuesta
9. Vibrational Stark Effect at Halide Precovered Cu(100) Electrodes 307
Melanie Röefzaad, Duc Thanh Pham, and Klaus Wandelt
10. Vibrational Spectroscopy of the Ionomer-Catalyst Interface 327
Ian Kendrick, Jonathan Doan, and Eugene S. Smotkin
11. In Situ PM-IRRAS Studies of Biomimetic Membranes Supported at Gold Electrode Surfaces 345
Annia H. Kycia, ZhangFei Su, Christa L. Brosseau, and Jacek Lipkowski
Index 418