This summary of modern applications of 31P NMR spectroscopy in organic and coordination chemistry brings together 20 of the world's best-known researchers in the field. The book is aimed at introducing the topic to chemists who are considering the use of 31P NMR spectroscopy and at aiding more experienced chemists in filling out their knowledge as well as supplying them with relevant references. The authors describe the significance of 31P NMR shifts as well as experimental techniques and the underlying theory. Among the topics discussed are applications of shift measurements in solving structural, conformational and mechanism problems, and the concept of stereospecificity in 31P couplings. Tabular data on representative inorganic, organic, and biochemical compounds and data on compounds associated with new frontiers in phosphorus chemistry, such as low-coordinate and hypervalent phosphorus systems, are also included.
Reihe
Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Illustrationen
Maße
Höhe: 250 mm
Breite: 160 mm
ISBN-13
978-3-527-26465-0 (9783527264650)
Schweitzer Klassifikation
General Experimental Techniques and Compilation of Chemical Shift Data; Empirical Methods for Interpreting Chemical Shifts of Phosphorus Compounds; Special Experimental Techniques in Phosphorus NMR Spectroscopy; Oriented Phases; Theoretical Considerations: Calculations of the Chemical Shift; Theoretical Considerations: Spin-Spin Coupling; NMR Studies of the Stereochemistry and Fluxionality of Five- and Six-Coordinate Phosphorus Compounds; Mechanisms of Reactions of Phosphorus Compounds; Conformation and Stereochemistry of Cyclic Compounds; Higher Order 31P NMR Spectra of Polyphosphorus Compounds; Stereospecificity in 31P-Element Couplings: Proton-Phosphorus Couplings; Stereospecificity in 31P-Element Couplings: Phosphorus-Carbon Coupling; Stereospecificity in 31P-Element Couplings: One-Bond Couplings to Other Nonmetals and to Metals; Stereochemistry of Metal Complexes: Unidentate Phosphorus Ligands; Stereochemistry of Metal Complexes: Polydentate Phosphorus Ligands; Stereochemistry of Metal Complexes: Phosphido Bridging Ligands; Unusual Ligation Modes of Phosphorus Compounds: One- and Two-Coordinate Phosphorus Compounds; Unusual Ligation Modes of Phosphorus Compounds: Phosphorus Ylides; Unusual Ligation Modes of Phosphorus Compounds: Phospholes; Unusual Ligation Modes of Phosphorus Compounds: Phosphoranides; Index.
