Part I. Electron Emission: Quantum Entrapment and Polarization.- Introduction.- Theory: Bond-Electron-Energy Correlation.- Probing Strategies: STM/S, PES, APECS/XAS, ZPS.- Solid and Liquid Skins: Quantum Entrapment and Polarization.- Adatoms, Defects, and Kink Edges.- Atomic Chain Ends, Clusters, and Nanocrystals.- Carbon Allotropes.- Hetero-Coordinated Interfaces.- Tetrahedrally-Coordinated Bond Formation.- Hetero- and Under-Coordination Coupling.- Liquid Phase.- Concluding Remarks.- Part II. Electron Diffraction: Bond-band-Barrier Forming Dynamics.- Principles: Bond-band-barrier Correlation.- Methodology: Parameterization and Justification.- VLEED Capability and Sensitivity.- Bond Geometry, Valence Band, Potential Barrier and Work Function.- Four-Stage Cu3O2 Bonding Dynamics.- Conclusion.- Part 3. Multifield Phonon Dynamics.- Wonders of Multifield Lattice Oscillation.- Theory: Multifield Oscillation Dynamics.- Phonons of the Layered Structures.- Phonons of the Sized Crystals.- Water and Aqueous Solutions.- Concluding Remarks.