During the past several years there has been remarkable interest and activity in two fields of the fused salt chemistry, namely Molten Salt Extractive Metallurgy and High-Temperature Fuel Cells.
The required fundamental investigations for improving industrial processes are necessarily devoted to all aspects of the reactivity in molten salts. Therefore, most of the relevant disciplines are represented here: electrochemistry, spectroscopy and computer modelling.
Reihe
Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Illustrationen
Illustrations, unspecified
Maße
Höhe: 240 mm
Breite: 170 mm
Dicke: 22 mm
Gewicht
ISBN-13
978-0-87849-669-3 (9780878496693)
DOI
10.4028/www.scientific.net/RC.24
Copyright in bibliographic data and cover images is held by Nielsen Book Services Limited or by the publishers or by their respective licensors: all rights reserved.
Schweitzer Klassifikation
Preface
I. Oxide Reaction Chemistry
Acidity Measurement
Electrochemical Behaviour of Dissolved CaO in Molten CaCl2
pO2- Sensor in Molten Chlorides: Precise Calibration and Uses
Oxoacidity Effect on Metallic Oxide Dissolution Reactions in Fused Chlorides
Separation and Selective Reactions
Three-Dimensional Reactivity Diagrams for Reaction Chemistry in Molten Chlorides
Molten Salt Separation of Baryum Sulfate from a Brazilian Baryte Ore
Separation of Tin and Indium Traces from Zinc/Lead Matrixes in Molten Chlorides
Chemical and Electrochemical Behaviour of Nickel Ion in the PbCl2-KCl Melt at 475 degreesC
II. Structural Studies of Salts and Interfaces
Raman Study on the SO3-K2S2O7 Molten System
Raman Spectroscopic Studies in the Molten System CsCl-NbCl5-NbOCl3
Structural Modelling of a Molten Salt by a Monte-Carlo Method
Ab Initio and Molecular Dynamics Studies of Molten NaCl-Graphite Interfaces
III. Refractory Metals and Alloys
Niobium
Investigations of the Complex and Redox Chemistry of K2NBF7 Dissolved in NaCl-KCl Melts with Oxide Additions
Titanium and Molybdenum
Influence of Nature of the Alkali Metal Cation on Ti(III)- e = Ti(IV)Electrochemical Process in Chloride Melts
Contribution to the Electrochemistry of Ti in Fused Salts
Electrochemical Study of Molybdenum Solutions at 500 degreesC
Electrodeposition of Molybdenum from KF-K2MoO4-SiO2 Melts
Electrochemical Study of Molybdenum in KF-K2MoO4-B2O3 Melts st 860 degreesC: Chronopotentiometry and Voltametry
IV. Light Metals Electrolysis Processes
Aluminium and Neodymium
Reactions between Molten Electrolyte - Sodium - Carbon and Air within the Cathode during Aluminium Electrolysis
Raman Spectra of Neodymium (III) Chloride-Alkali Chloride Melts and of Solid Compounds
The Kinetics and Mechanism of Al(III)/Al Electrode Reaction in Cryolite - Alumina Melts
Investigations on Cell and Electrode Materials
Oxygen-Evolving Anodes for High-Temperature Electrolysis
A Study on the Solubility of SnO2 in Cryolite-Based Melts
Chemical and Electrochemical Behaviour of Some 'New Materials' in Molten Salts to be Used for Aluminium Electrolysis
Thermodynamics of Y2O3-LiF-YF3 Melts
Electrochemical Behaviour of the Ceramical NiO-Li2O Anode in Molten CaCl2-CaO Mixture
V. Energetic Relevant Systems
Fuel Cells
Electrochemical Sensors and Fuel Cells: The Solid State Alternative
Electrochemical Corrosion Studies on Molten Carbonate Fuel Cell Components
Investigation on the Kinetics and Stability of NiO(Li) and La0.8Sr0.2CoO3 in Molten Carbonates by Means of Electrochemical Impedance Spectroscopy
Electroreduction of Oxygen under Pressurized Conditions in Molten Carbonate Media
Design of a Rotating and Hanging Meniscus Rotating Disk Electrode for Molten Carbonates
Others Prospective Investigations
Diffusion of Impurities in Liquid Metal Using Solid Electrolytes
Hydride-Containing Molten Salts and their Technology Implications
Ostwald Ripening in a Molten Salt Medium
Structure and Transport Properties of Molten NH4H2PO4 upon Addition of Solid CaHPO4
VI. Low-Temperature Molten Salts
Electrolyte-Amide Molten System: Micellar and Supercapacitive Stystems
Electrochemical Insertion of Magnesium in Vanadium Bronzes Using Room Temperature Molten Salts as an Electrolyte
Electrochemical Reduction of SO2 from Molten Amides at n-Type Semiconductor Electrodes
Electrochemical Studies in Low Temperature Amide Melts
