Preface ix
Preface to the Wiley Series on Electrocatalysis and Electrochemistry xi
Contributors xiii
1. Volcano Curves in Electrochemistry 1
Roger Parsons
2. Electrocatalysis: A Survey of Fundamental Concepts 17
Alejandro Jorge Arvia, Agustin Eduardo Bolzán, and Miguel Angel Pasquale
3. Dynamics and Stability of Surface Structures 67
Margret Giesen and Guillermo Beltramo
4. Electrocatalytic Properties of Stepped Surfaces 127
Juan M. Feliu, Enrique Herrero, and Victor Climent
5. Computational Chemistry Applied to Reactions in Electrocatalysis 165
Axel Gross and Sebastian Schnur
6. Catalysis of Electron Transfer at Metal Electrodes 197
Elizabeth Santos and Wolfgang Schmickler
7. Combining Vibrational Spectroscopy and Density Functional Theory for Probing Electrosorption and Electrocatalytic Reactions 223
Marc T. M. Koper
8. Electrochemical Catalysts: From Electrocatalysis to Bioelectrocatalysis 249
Alejandro Jorge Arvia, Agustin Eduardo Bolzan, and Miguel Angel Pasquale
9. Electrocatalysis at Bimetallic Surfaces Obtained by Surface Decoration 297
Helmut Baltruschat, Siegfried Ernst, and Nicky Bogolowski
10. CO Adsorption on Platinum Electrodes 339
Ángel Cuesta and Claudio Gutiérrez
11. Exploring Metal Oxides: A Theoretical Approach 375
Monica Calatayud and Frederik Tielens
12. Electrocatalysis at Liquid-Liquid Interfaces 427
Bin Su, Hubert H. Girault, and Zdenek Samec
13. Platinum-Based Supported Nanocatalysts for Oxidation of Methanol and Ethanol 453
Ernesto R. Gonzalez, Edson A. Ticianelli, and Ermete Antolini
14. Impact of Electrochemical Science on Energy Problems 487
Elizabeth Santos and Wolfgang Schmickler
Index 499