Ionic liquids (ILs) or melting organic salts belong to the special type of fluid thermodynamic systems in which the orthobaric (saturated) vapor phase is practically absent at low (working) temperatures located below the thermal decomposition point. The methodology of FT-(fluctuational thermodynamics) model developed by author and applied to this complicated object (considering by many theoreticians and simulators as an example of ionic fluid behavior) reveals about all typical features of usual neutral systems. In particular, such important for the construction of IL-EOS (equation of state) parameters as the location of virtual critical point, the shape of hypothetical phase diagram and the normal boiling point can be predicted, at least, in the thermodynamically-consistent manner by the proposed FT-approach. The book is recommended for the wide circle of chemists and physicists exploited in their work the remarkable quite useful and often unusual properties of ILs.
Sprache
Maße
Höhe: 220 mm
Breite: 150 mm
Dicke: 17 mm
Gewicht
ISBN-13
978-3-659-87569-4 (9783659875694)
Schweitzer Klassifikation
Vitaly B. Rogankov (69) (Dr. of Phys.-Math. Sci., Prof.). The scientific interests are ranged from the theory of phase transitions and criticality in mixtures up to the study of complex heterophase states in the finite-size systems. Author of about 200 publications and three monographs on the above items. Wife Ann Rogankova (62) and son Oleg (23).
