This new book provides comprehensive and up-to-date coverage of organotin chemistry encompassing synthetic methods, reactions, structures, spectroscopic analyses, as well as uses of organotin compounds for organic syntheses, and in various industrial products and processes. Appropriate references (over 1,000 in all) to recent articles, reviews, and books are given in each chapter. While previous books on organotin compounds have been written specifically for researchers in organotin chemistry, this book offers a more general overview of the subject which will also be of value to those in organic chemistry, pharmaceutical chemistry, environmental chemistry, and other chemical fields, as well as graduate and undergraduate students.
This new book provides comprehensive and up-to-date coverage of organotin chemistry encompassing synthetic methods, reactions, structures, spectroscopic analyses, as well as uses of organotin compounds for organic syntheses, and in various industrial products and processes. Appropriate references (over 1,000 in all) to recent articles, reviews, and books are given in each chapter. While previous books on organotin compounds have been written specifically for researchers in organotin chemistry, this book offers a more general overview of the subject which will also be of value to those in organic chemistry, pharmaceutical chemistry, environmental chemistry, and other chemical fields, as well as graduate and undergraduate students.
Reihe
Sprache
Verlagsort
Verlagsgruppe
Elsevier Science & Technology
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Maße
ISBN-13
978-0-444-87456-6 (9780444874566)
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Schweitzer Klassifikation
Chapter 1. Introduction. 2. Tin. Physical properties of tin. Chemical properties of tin. Some differences between tin and other elements in Group IVB. Analysis. Inorganic tin compounds. 3. Basic Methods of Preparation of Organotin Compounds. Grignard reaction. Wurtz reaction. Organoaluminums. Direct reaction. Organomercury and other organometallic compounds. Redistribution reaction (Kocheskov reaction). Industrial preparations and others. 4. Preparation and Properties of Organotin Compounds. Organotin hydrides. Organotin compounds with a carbon-carbon unsaturated bond. Organotin oxygen, sulfur, selenium and tellurium compounds. Organotin nitrogen, phosphorus, arsenic and antimony compounds. Compounds with Sn-Sn bonds. Compounds with Sn-other metal bonds. Organopolytins. Organotin polymers. Tin heterocycles. Organostannylenes. 5. Reactions of Organotin Compounds. Hydrostannation. Hydrostannolysis. Radical reactions. Reactions of organostannylenes. 6. Organic Syntheses with Organotin Compounds. Allyltin compounds. Vinyltin (ethenyltin) compounds. Alkynyltin and allenyltin compounds. Aryltin, benzyltin and alkyltin compounds. a-Functionally substituted organotin compounds. Organotin enolates and v-haloalkoxides. Organotin alkoxides and heterocyclic organotin compounds. Organotin hydrides. Miscellaneous compounds. 7. Structure of Organotin Compounds. Organotin(II) derivatives. Tetrahedral organotin compounds and other higher-coordination compounds. Organotin intramolecular-coordination compounds. 8. Spectroscopic Investigations. 119 Sn NMR spectroscopy. 119 Sn Mossbauer spectroscopy. 9. Applications of Organotin Compounds. PVC stabilization. Catalysts. Wood preservatives. Antifoulants. Agricultural chemicals. Pharmaceuticals. Miscellaneous uses. (All chapters begin with an Introduction and end with References). Subject Index.
