Asymmetric Synthesis in Organophosphorus Chemistry

INTRODUCTION
FUNDAMENTALS OF STEREOCHEMISTRY OF ORGANOPHOSPHORUS COMPOUNDS
Determining Enantiomer Composition
Determining Absolute Configuration
Asymmetric Induction and Stereochemistry

ASYMMETRIC SYNTHESIS OF P-CHIROGENIC PHOSPHOROUS COMPOUNDS
Introduction
Low-Coordinated Organophosphorus Compounds
Compounds of Tervalent Three-Coordinated Phosphorus
Asymmetric Induction at P (IV)
Enzymatic Synthesis of P-Chiral Phosphorus Compounds
Asymmetric Synthesis of P-Chirogenic P(V) and P(VI)-Phosphorus Compounds

PHOSPHORUS COMPOUNDS WITH CHIRAL CENTRE IN SIDE CHAIN
Introduction
Asymmetric Reactions in Side Chain of Organophosphorus
Enantioselective Olefination
Stereoselective Addition of Phosphoric Nucleophiles to C=X Compounds
Asymmetric Reduction
Enantioselective Oxidation
Asymmetric Cycloaddition

ASYMMETRIC METALLOCOMPLEX CATALYSIS OF PHOSPHORUS COMPOUNDS
Introduction
Asymmetric Catalytic Hydrogenation and Reduction Reactions
Asymmetric Oxidation
Electrophilic Asymmetric Catalysis
Nucleophilic Asymmetric Catalysis of Addition Reaction to Multiple Bonds

ASYMMETRIC ORGANOCATALYSIS
Introduction
Quinine and its Derivatives
Sparteine as a Chirality Inductor
Proline, Amino Acids and their Derivatives
Various Examples

ASYMMETRIC BIOCATALYSIS IN PHOSPHOROUS CHEMISTRY
Introduction
Enzymatic Synthesis of Organophosphorus Compounds
Microbiological Syntheses of Organophosphorus Compounds

CONCLUSION