Begins with a historial overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and ? back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with
DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.
Reihe
Sprache
Verlagsort
Zielgruppe
Maße
Höhe: 234 mm
Breite: 157 mm
Dicke: 26 mm
Gewicht
ISBN-13
978-0-8412-3456-7 (9780841234567)
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Schweitzer Klassifikation
From Electron Transfer Reactions to the Effects of Backbonding ; Structure and Bonding in Molecular Hydrogen Complexes of Osmium(II) ; Osmium(II) Dearomatization Agents in Organic Synthesis ; A Novel, High-Yield System for the Oxidation of Methane to Methanol ; Intrinsic Ancilliary Ligand Effects in Cationic Zirconium Polymerization Catalysts ; Zeolites Offer Variety as Ligands ; Reactions Catalyzed by Methylrhenium Trioxide ; Steric Effects in Redox Reactions and Electron Transfer Rates ; Intrinsic Barriers to Atom Transfer Between Transition-Metal Centers ; Nuclear Factors in Main-Group Electron Transfer Reactions ; Calculation of Rate Constants from Spectra: Nonradiative Decay and Electron Transfer ; Ligand-Induced, Stereochemical Relaxation of Electronic Constraints in a Simple Chemical Process: Examples from Hexamm(m)ine Cr(III) Photophysics ; Time-Resolved Infrared Studies of Migratory Insertion Mechanisms in Manganese Carbonyls ; Redox Reactions of Binuclear Complexes of Ruthenium and Iron: Kinetic vs. Thermodynamic Control and Activation Effects ; Electron Delocalization Through the Disulfide Bridge ; Kinetic and Equilibrium Studies of the Reactions of Cysteine and Penicillamine with Aqueous Iron (III) ; Taube's Influence on the Design of Oscillating Reactions: ClO[2*-Driven ClO[2 ~ -I ~ Oscillator, and Turing Structures ; Hydrolysis of Coordinated Nitriles and Linkage Isomerization Reactions in Rutheniium Amine Complexes with Nitriles and Amides ; Electron Transfer in Bioinorganic Chemistry: Role of Electronic Structure and the Entatic State ; Long-Range Intramolecular Electron Transfer Reactions Across Simple Organic Bridges, Peptides, and Proteins ; Ruthenium in Biology: DNA Interactions ; Ru(II)-Polyaminopolycarboxylate Complexes for Improved DNA Probes ; The Role of Inorganic Chemistry in Cellular Mechanisms of Host Resistance to Disease ; Application of Taube Insights to Nuclear Medicine: In Vivo Inorganic Chemistry
